/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 43 Sodium metal reacts explosively ... [FREE SOLUTION] | 91Ó°ÊÓ

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Sodium metal reacts explosively with hydrochloric acid, \(\mathrm{HCl}(a q)\), as shown in the following chemical equation: \\[2 \mathrm{Na}(s)+2 \mathrm{HCl}(a q) \longrightarrow 2 \mathrm{NaCl}(a q)+\mathrm{H}_{2}(g)\\] What volume of \(\mathrm{H}_{2}(g)\) is produced when \(3.50 \mathrm{g}\) of \(\mathrm{Na}(s)\) is treated with an excess of hydrochloric acid at a temperature of \(18^{\circ} \mathrm{C}\) and a pressure of 0.995 atm?

Short Answer

Expert verified
The volume of hydrogen gas produced is approximately 1.81 liters.

Step by step solution

01

Calculate Moles of Sodium

First, we need to find the moles of sodium (\(\mathrm{Na}\)) we have. The molar mass of sodium is approximately 23.0 g/mol. We use the formula: \[ \text{Moles of Na} = \frac{\text{Mass of Na}}{\text{Molar Mass of Na}} \] Substituting in the given values: \[ \text{Moles of Na} = \frac{3.50 \, \text{g}}{23.0 \, \text{g/mol}} \approx 0.152 \, \text{mol} \]
02

Determine Moles of Hydrogen Gas Produced

Using the balanced equation \[2 \mathrm{Na}(s) + 2 \mathrm{HCl}(aq) \rightarrow 2 \mathrm{NaCl}(aq) + \mathrm{H}_{2}(g)\], we see that 2 moles of \(\mathrm{Na}\) produce 1 mole of \(\mathrm{H}_2\). Therefore, the moles of hydrogen gas are half of the moles of sodium: \[ \text{Moles of } \mathrm{H}_2 = \frac{0.152 \, \text{mol}}{2} \approx 0.076 \, \text{mol} \]
03

Use Ideal Gas Law to Find Volume of Hydrogen

We now use the ideal gas law \( PV = nRT \) to find the volume \( V \) of the produced \( \mathrm{H}_2 \). - \( P = 0.995 \, \text{atm} \) (given pressure) - \( n = 0.076 \, \text{mol} \) (moles of \( \mathrm{H}_2 \)) - \( R = 0.0821 \, \text{L atm/mol K} \) (ideal gas constant) - \( T = 18^{\circ} \mathrm{C} + 273 = 291 \, \text{K} \) (temperature in Kelvin)Substituting into the ideal gas equation: \[ V = \frac{nRT}{P} = \frac{0.076 \, \text{mol} \times 0.0821 \, \text{L atm/mol K} \times 291 \, \text{K}}{0.995 \, \text{atm}} \approx 1.81 \, \text{L} \]
04

Conclusion

Therefore, the volume of hydrogen gas produced is approximately 1.81 liters.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Ideal Gas Law
When dealing with gases, one of the most fundamental tools in chemistry is the ideal gas law. It provides a way to relate the pressure, volume, temperature, and moles of a gas, specifically in an idealized context. The equation for the ideal gas law is \( PV = nRT \), where:
  • \( P \) represents the pressure of the gas (in atmospheres, atm).
  • \( V \) is the volume the gas occupies (in liters, L).
  • \( n \) denotes the number of moles of the gas.
  • \( R \) is the ideal gas constant (0.0821 L atm/mol K).
  • \( T \) is the temperature of the gas, measured in Kelvin (K).
Applying this equation, you can solve for any variable if the others are known. In the example, we use the ideal gas law to find the volume of hydrogen gas produced from a chemical reaction. We substitute the known values: the pressure (0.995 atm), the number of moles (0.076 mol), and the temperature converted to Kelvin (291 K) into the formula to solve for \( V \), yielding a volume of approximately 1.81 liters.
Chemical Reactions
Chemical reactions involve the transformation of reactants into products. For a reaction to occur, bonds in reactants must break, and new bonds must form to create the products. Written reactions provide chemists with a concise way to describe these changes.To understand chemical reactions, look at balanced equations where reactants and products have equal numbers of each type of atom. In the reaction \(2 \text{Na}(s) + 2 \text{HCl}(aq) \rightarrow 2 \text{NaCl}(aq) + \text{H}_2(g)\), sodium reacts with hydrochloric acid to form sodium chloride and hydrogen gas.Balanced equations are vital:
  • They maintain the law of conservation of mass, ensuring mass is neither created nor destroyed.
  • They provide mole ratios that are essential for stoichiometry calculations.
By analyzing the equation above, we can determine, for instance, that 2 moles of sodium will yield 1 mole of hydrogen gas when they react, guiding our stoichiometry.
Mole Calculations
Moles provide a bridge between the atomic world and the macroscopic world we observe. Moles allow chemists to count atoms/molecules by weighing them.In stoichiometry, mole calculations are essential for converting mass of a substance to its number of moles. The formula for determining moles is \( \text{Moles} = \frac{\text{Mass}}{\text{Molar Mass}} \).Let’s use sodium (Na) as an example:
  • We start with a mass of 3.50 grams of sodium.
  • The molar mass of sodium is approximately 23.0 g/mol.
  • Thus, the number of moles of sodium is \( \frac{3.50 \, \text{g}}{23.0 \, \text{g/mol}} \approx 0.152 \, \text{mol} \).
These calculations are crucial for understanding how much of each reactant you need, and how much product you’ll get, as they connect the quantities in a balanced chemical equation with real-world measurements.

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Most popular questions from this chapter

The unit of pressure most commonly used for checking the inflation of automobile and bicycle tires is pounds per square inch (lb/in^), abbreviated psi. The conversion factor between atm and psi is \(1.00 \mathrm{atm}=14.7 \mathrm{psi}\) Suppose an automobile tire is filled to a pressure of 34 psi. What is the pressure in atm in the tire?

Answer true or false. (a) The ideal gas law assumes that there are no attractive forces between molecules and therefore no liquids. (b) Unlike a gas, whose molecules move freely in any direction, molecules in a liquid are locked into fixed positions, giving the liquid a constant shape. (c) Surface tension is the force that prevents a liquid from being stretched. (d) Surface tension creates an elastic-like layer on the surface of a liquid. (e) Water has a high surface tension because \(\mathrm{H}_{2} \mathrm{O}\) is a small molecule. (f) Vapor pressure is proportional to temperature-as the temperature of a liquid sample increases, its vapor pressure also increases. (g) When molecules evaporate from a liquid, the temperature of the liquid drops. (h) Evaporation is a cooling process because it leaves fewer molecules with high kinetic energy in the liquid state. (i) The boiling point of a liquid is the temperature at which its vapor pressure equals the atmospheric pressure. (j) \(\quad\) As the atmospheric pressure increases, the boiling point of a liquid increases. (k) The temperature of boiling water is related to how vigorously it is boiling- -the more vigorous the boiling, the higher the temperature of the water. (l) The most important factor determining the relative boiling points of liquids is molecular weight the greater the molecular weight, the higher the boiling point. \((\mathrm{m})\) Ethanol \(\left(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}, \mathrm{bp} 78.5^{\circ} \mathrm{C}\right)\) has a greater vapor pressure at \(25^{\circ} \mathrm{C}\) than water \(\left(\mathrm{H}_{2} \mathrm{O}, \mathrm{bp} 100^{\circ} \mathrm{C}\right)\) (n) Hexane \(\left(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{CH}_{3}, \mathrm{bp} 69^{\circ} \mathrm{C}\right)\) has a higher boiling point than methane \(\left(\mathrm{CH}_{4}\right.\) bp \(-164^{\circ} \mathrm{C}\) ) because hexane has more sites for hydrogen bonding between its molecules than does methane. (o) A water molecule can participate in hydrogen bonding through each of its hydrogen atoms and through its oxygen atom. (p) For nonpolar molecules of comparable molecular weight, the more compact the shape of the molecule, the higher its boiling point.

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On the basis of what you have learned about intermolecular forces, predict which liquid has the highest boiling point: (a) Pentane, \(C_{5} H_{12}\) (b) Chloroform, \(\mathrm{CHCl}_{3}\) (c) Water, \(\mathrm{H}_{2} \mathrm{O}\)

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