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Draw a Lewis structure of a covalent compound in which nitrogen has: (a) Three single bonds and one unshared pair of electrons (b) One single bond, one double bond, and one unshared pair of electrons (c) One triple bond and one unshared pair of electrons

Short Answer

Expert verified
Nitrogen forms these structures in NH鈧, NO鈧傗伝, and HCN.

Step by step solution

01

Understanding the components of a Lewis structure

Lewis structures are diagrams that represent the bonding between atoms of a molecule and the lone pairs of electrons in the molecule. In this task, we need to draw specific configurations for nitrogen, considering its common valency and electron pair arrangements.
02

Drawing structure for part (a) - Three single bonds and one unshared pair

For part (a), the nitrogen must form three single bonds with other atoms and retain one lone pair of electrons. A common example would be the structure of ammonia (NH鈧). In NH鈧, the nitrogen atom forms single covalent bonds with each of the three hydrogen atoms, and it retains one lone pair of electrons. The structure can be depicted as: H | N - H | H The bonds between N and each H are single, and there is a lone pair on nitrogen.
03

Drawing structure for part (b) - One single bond, one double bond, and one unshared pair

For part (b), a suitable compound is nitrogen dioxide (NO鈧傗伝). In NO鈧傗伝, one of the oxygens forms a double bond with nitrogen, the other oxygen forms a single bond, and there's one lone pair on nitrogen. The structure can be represented as: O || N--O | lone pair Here, the 'O' with a double line is double bonded, the other 'O' is single bonded, and a lone pair is on nitrogen.
04

Drawing structure for part (c) - One triple bond and one unshared pair

For part (c), a suitable compound is hydrogen cyanide (HCN). In HCN, the carbon atom is triple-bonded to the nitrogen atom, and nitrogen has one lone pair. The structure can be depicted as: H-C鈮: Here, the triple bond is between carbon and nitrogen, and there's a lone pair on nitrogen.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Understanding Covalent Bonding
Covalent bonding involves the sharing of electron pairs between atoms, allowing them to attain a full outer shell of electrons. This is a common type of chemical bond formed between non-metal atoms. When atoms share electrons, they create a bond that holds them together in a molecule. For example, in a molecule like ammonia (NH鈧), nitrogen shares its electrons with hydrogen atoms to achieve a stable electron configuration. Atoms typically form covalent bonds to fulfill the octet rule, which means having eight electrons in their valence shell. However, there are exceptions to this rule, especially with smaller atoms like hydrogen, which is satisfied with two electrons.
The Role of Nitrogen in Compounds
Nitrogen is a versatile element that can form various types of covalent bonds depending on its bonding partners. - **Three Single Bonds**: In ammonia (NH鈧), nitrogen forms three single bonds with hydrogen and has one lone electron pair, resulting in a pyramidal shape. This is a typical configuration for nitrogen when it needs to satisfy its valency without forming multiple bonds with the same atom. - **One Single Bond and One Double Bond**: In nitrogen dioxide ( O鈧傗伝), nitrogen forms a compound by sharing one pair of electrons with one oxygen (single bond) and two pairs with another oxygen (double bond). This gives NO鈧傗伝 its bent shape due to the repulsion of the lone pair, following the VSEPR (Valence Shell Electron Pair Repulsion) theory. - **One Triple Bond**: In compounds like hydrogen cyanide (HCN), nitrogen forms a triple bond with carbon, which is a highly stable and strong bond, allowing for a linear molecular geometry. It also retains an unshared pair of electrons.
Exploring Electron Pair Arrangements
In covalent compounds, the arrangement of electron pairs around an atom is crucial in determining the molecule's shape and properties. - **Lone Pairs**: Electrons that are not involved in bonding are known as lone pairs. These lone pairs still exert force on the molecule, influencing its shape. For instance, in NH鈧, the lone pair on nitrogen slightly pushes the hydrogen atoms closer together, creating a trigonal pyramidal shape. - **Bonding Pairs**: These are pairs of electrons that join two atoms in a molecule. Their arrangement can be single, double, or triple bonds, affecting the geometry of the molecule. For example, in NO鈧傗伝, the presence of both single and double bonds causes a bent shape, while in HCN, the linear geometry is due to the triple bond. - **VSEPR Theory**: This theory is used to predict the geometry of the molecules based on the repulsion between electron pairs. Contrary to what one might think, these shapes are not flat, two-dimensional structures but have three-dimensional geometry, offering stability to the molecules by minimizing repulsions between electrons.

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Most popular questions from this chapter

On packaged table salt, it is common to see a label stating that the salt "supplies iodide, a necessary nutrient." Name and write the formula of the iodinecontaining nutrient compound found in iodized salt.

Answer true or false. (a) To predict whether a covalent molecule is polar or nonpolar, you must know both the polarity of each bond and the geometry (shape) of the molecule. (b) A molecule may have two or more polar bonds and still be nonpolar. (c) All molecules with polar bonds are polar. (d) If water were a linear molecule with an \(\mathrm{H}-\mathrm{O}-\mathrm{H}\) bond angle of \(180^{\circ},\) water would be a nonpolar molecule. (e) \(\mathrm{H}_{2} \mathrm{O}\) and \(\mathrm{NH}_{3}\) are polar molecules, but \(\mathrm{CH}_{4}\) is nonpolar. (f) In methanol, \(\mathrm{CH}_{3} \mathrm{OH}\), the \(\mathrm{O}-\mathrm{H}\) bond is more polar than the \(\mathrm{C}-\mathrm{O}\) bond. (g) Dichloromethane, \(\mathrm{CH}_{2} \mathrm{Cl}_{2}\), is polar, but tetrachloromethane, \(\mathrm{CCl}_{4},\) is nonpolar. (h) Ethanol, \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}\), the alcohol of alcoholic beverages, has polar bonds, has a net dipole, and is a polar molecule.

Answer true or false. (a) According to the Lewis model of bonding, atoms bond together in such a way that each atom participating in the bond acquires an outer-shell electron configuration matching that of the noble gas nearest to it in atomic number. (b) Atoms that lose electrons to achieve a filled valence shell become cations and form ionic bonds with anions. (c) Atoms that gain electrons to achieve filled valence shells become anions and form ionic bonds with cations. (d) Atoms that share electrons to achieve filled valence shells form covalent bonds. (e) Ionic bonds tend to form between elements on the left side of the Periodic Table, and covalent bonds tend to form between elements on the right side of the Periodic Table. (f) Ionic bonds tend to form between a metal and a nonmetal. (g) When two nonmetals combine, the bond between them is usually covalent. (h) Electronegativity is a measure of an atom's attraction for the electrons it shares in a chemical bond with another atom. (i) Electronegativity generally increases with atomic number. (j) Electronegativity generally increases with atomic weight. (k) Electronegativity is a periodic property. (l) Fluorine, in the upper-right corner of the Periodic Table, is the most electronegative element; hydrogen, in the upper-left corner, is the least electronegative element. (m) Electronegativity depends on both the nuclear charge and the distance of the valence electrons from the nucleus. (n) Electronegativity generally increases from left to right across a period of the Periodic Table. (o) Electronegativity generally increases from top to bottom in a column of the Periodic Table.

We are constantly warned about the dangers of "leadbased" paints. Name and write the formula for a leadcontaining compound found in lead-based paints.

Why can't second-row elements have more than eight electrons in their valence shells? That is, why does the octet rule work for second-row elements?

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