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How many electrons must each atom gain or lose to acquire an electron configuration identical to the noble gas nearest to it in atomic number? (a) Li (b) \(\mathrm{Cl}\) (c) \(P\) (d) \(A l\) \((\mathrm{e}) \mathrm{Sr}\) (f) \(\mathrm{S}\) \((g) \quad\) Si (h) \(\mathrm{O}\)

Short Answer

Expert verified
(a) Lose 1; (b) Gain 1; (c) Gain 3; (d) Lose 3; (e) Lose 2; (f) Gain 2; (g) Lose 4; (h) Gain 2.

Step by step solution

01

Analyze Li

Lithium (Li) has 3 electrons. The noble gas closest to Li is helium (He), which has 2 electrons. Therefore, Li must lose 1 electron to achieve the electron configuration of He.
02

Analyze Cl

Chlorine (Cl) has 17 electrons. The next noble gas is argon (Ar), which has 18 electrons. Hence, Cl needs to gain 1 electron to match Ar's electron configuration.
03

Analyze P

Phosphorus (P) has 15 electrons. The next noble gas is argon (Ar) with 18 electrons. Thus, P must gain 3 electrons to achieve the electron configuration of Ar.
04

Analyze Al

Aluminum (Al) has 13 electrons. The preceding noble gas is neon (Ne) with 10 electrons. Therefore, Al must lose 3 electrons to reach Ne's electron configuration.
05

Analyze Sr

Strontium (Sr) has 38 electrons. The noble gas prior to Sr is krypton (Kr) having 36 electrons. So, Sr must lose 2 electrons to obtain Kr's electron configuration.
06

Analyze S

Sulfur (S) has 16 electrons. The subsequent noble gas is argon (Ar), which has 18 electrons. Thus, S must gain 2 electrons to achieve Ar's electron configuration.
07

Analyze Si

Silicon (Si) has 14 electrons. The preceding noble gas is neon (Ne) with 10 electrons. Si needs to lose 4 electrons to reach Ne's electron configuration.
08

Analyze O

Oxygen (O) has 8 electrons. The following noble gas is neon (Ne) with 10 electrons. Therefore, O must gain 2 electrons to match the electron configuration of Ne.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Noble Gases
Noble gases are a group of elements found in the far right column of the periodic table. They include helium (He), neon (Ne), argon (Ar), krypton (Kr), xenon (Xe), and radon (Rn). These gases are unique because they have a full valence shell, making them stable and unreactive. This stability arises from having a complete outer electron shell, which other elements aspire to achieve through gaining or losing electrons.
Typically, elements become more stable by obtaining the same electron configuration as the nearest noble gas. For example, lithium (Li), with 3 electrons, will lose one electron to resemble helium's configuration, while chlorine (Cl), possessing 17 electrons, will gain one electron to mimic argon's configuration.
Knowing which noble gas is nearest to a given element helps predict whether an atom will tend to gain or lose electrons, thus influencing its chemical behavior and the types of bonds it forms.
Gaining Electrons
Some elements are naturally inclined to gain electrons in order to attain a noble gas configuration. This occurs when an atom has fewer electrons than its nearest noble gas and a higher atomic number than it. Gaining electrons increases stability by filling up the outer electron shell.
For example:
  • Chlorine (Cl) has 17 electrons and needs one additional electron to reach the electron configuration of argon (Ar) with 18 electrons.
  • Phosphorus (P) has 15 electrons and requires three more electrons to match argon's configuration.
  • Oxygen (O) with 8 electrons needs two additional electrons to achieve the neon (Ne) configuration, which has 10 electrons.
Gaining electrons typically leads to negatively charged ions, known as anions. These ions are essential in forming ionic bonds, commonly seen in compounds like sodium chloride (NaCl) where chlorine gains an electron.
Losing Electrons
Elements that lose electrons usually have more electrons than their nearest noble gas and need to shed a few to simplify their electron cloud. Losing electrons helps them achieve the arrangement of the preceding noble gas, stabilizing the atom. This process often results in positively charged ions, called cations.
Consider the following examples:
  • Lithium (Li), with 3 electrons, will lose 1 electron to mirror helium's configuration, which has 2 electrons.
  • Aluminum (Al), consisting of 13 electrons, needs to lose 3 electrons to emulate neon’s configuration, which has 10 electrons.
  • Strontium (Sr) needs to lose 2 electrons from its 38 to match krypton (Kr) with 36 electrons.
  • Silicon (Si), having 14 electrons, must shed 4 electrons to resemble neon’s configuration.
These cations play a crucial role in the formation of ionic bonds where, for example, lithium pairs with fluorine (F) to form lithium fluoride (LiF) through electron transfer.
Periodic Table
The periodic table is a comprehensive chart that organizes all the chemical elements based on their atomic number, electron configurations, and recurring chemical properties. The table allows students and chemists to identify patterns and predict the behavior of elements, such as their tendency to gain or lose electrons.
Each column on the table is known as a group and typically contains elements with similar properties and the same number of valence electrons. Noble gases are located in Group 18, and elements often strive to attain their stable electron configuration.
The arrangement of elements into periods (rows) helps in recognizing the type of electron transitions they are likely to undergo. Transitioning across a period from left to right usually means an addition of electrons, moving closer to filling the valence shell and becoming similar to the noble gases, while moving vertically within a group indicates similar behavior in electron loss or gain.
  • For instance, elements like Li and Al in the same group will lose electrons to reach a previous noble gas configuration.
  • In contrast, elements such as Cl and P gain electrons to attain the configuration of their noble gas neighbor.
Thus, the periodic table is essential for understanding chemical reactions and electron behavior across different elements.

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Most popular questions from this chapter

Complete the chart by writing formulas for the compounds formed: \(\mathrm{Br}^{-} \quad \mathrm{MnO}_{4}^{-} \quad \mathrm{O}^{2-} \quad \mathrm{NO}_{3}^{-} \quad \mathrm{SO}_{4}^{2-} \quad \mathrm{PO}_{4}^{3-} \quad \mathrm{OH}^{-}\) \(\mathbf{L i}^{+}\) \(\mathrm{Ca}^{2+}\) \(\mathrm{Co}^{3+}\) \(\mathrm{K}^{+}\) \(\mathrm{Cu}^{2}\)

Predict which ions are stable: (a) \(\mathrm{Br}^{2-}\) (b) \(\mathrm{C}^{4-}\) (c) \(\mathrm{Ca}^{+}\) (d) \(A r^{+}\) (e) \(\mathrm{Na}^{+}\) (f) \(\quad \mathrm{Cs}^{+}\)

Potassium chloride and potassium bicarbonate are used as potassium dietary supplements. Write the formula of each compound.

Answer true or false. (a) According to the Lewis model of bonding, atoms bond together in such a way that each atom participating in the bond acquires an outer-shell electron configuration matching that of the noble gas nearest to it in atomic number. (b) Atoms that lose electrons to achieve a filled valence shell become cations and form ionic bonds with anions. (c) Atoms that gain electrons to achieve filled valence shells become anions and form ionic bonds with cations. (d) Atoms that share electrons to achieve filled valence shells form covalent bonds. (e) Ionic bonds tend to form between elements on the left side of the Periodic Table, and covalent bonds tend to form between elements on the right side of the Periodic Table. (f) Ionic bonds tend to form between a metal and a nonmetal. (g) When two nonmetals combine, the bond between them is usually covalent. (h) Electronegativity is a measure of an atom's attraction for the electrons it shares in a chemical bond with another atom. (i) Electronegativity generally increases with atomic number. (j) Electronegativity generally increases with atomic weight. (k) Electronegativity is a periodic property. (l) Fluorine, in the upper-right corner of the Periodic Table, is the most electronegative element; hydrogen, in the upper-left corner, is the least electronegative element. (m) Electronegativity depends on both the nuclear charge and the distance of the valence electrons from the nucleus. (n) Electronegativity generally increases from left to right across a period of the Periodic Table. (o) Electronegativity generally increases from top to bottom in a column of the Periodic Table.

Write formulas for these compounds. (a) Calcium sulfite, which is used in preserving cider and other fruit juices (b) Calcium hydrogen sulfite, which is used in dilute aqueous solutions for washing casks in brewing to prevent souring and cloudiness of beer and to prevent secondary fermentation (c) Calcium hydroxide, which is used in mortar, plaster, cement, and other building and paving materials (d) Calcium hydrogen phosphate, which is used in animal feeds and as a mineral supplement in cereals and other foods

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