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Name and give the symbol of the element with the given characteristic. (a) Largest atomic radius in Group \(2 \mathrm{A}\) (b) Smallest atomic radius in Group 2 A. (c) Largest atomic radius in the second period. (d) Smallest atomic radius in the second period. (e) Largest ionization energy in Group 7 A. (f) Lowest ionization energy in Group 7A.

Short Answer

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(a) Ba, (b) Be, (c) Li, (d) Ne, (e) F, (f) I

Step by step solution

01

Understanding Atomic Radius Trends in Group 2A

The atomic radius tends to increase as you move down a group in the periodic table. For Group 2A, which consists of alkaline earth metals, starting from Beryllium (Be) at the top to Barium (Ba) at the bottom, the atomic radius increases. Therefore, the element with the largest atomic radius in Group 2A is Barium (Ba), and the one with the smallest atomic radius is Beryllium (Be).
02

Checking Periodic Trends for the Second Period

In the second period of the periodic table, atomic radii decrease from left to right across a period as the nucleus attracts the electrons more strongly, pulling them closer. Thus, the element with the largest atomic radius in the second period is Lithium (Li), which is on the far left, and the element with the smallest atomic radius is Neon (Ne), located at the far right.
03

Understanding Ionization Energy in Group 7A

Ionization energy increases across a period and decreases down a group. Group 7A (halogens) includes Fluorine (F), Chlorine (Cl), Bromine (Br), and Iodine (I). Fluorine, at the top of Group 7A, has the highest ionization energy due to its smaller size and greater effective nuclear charge, while Iodine, at the bottom, has the lowest ionization energy due to its larger size and increased electron shielding.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Periodic Table Trends
Understanding periodic table trends is fundamental to grasping how elements behave. The periodic table is organized into periods (rows) and groups (columns), which reveal patterns in element properties.
One crucial trend is that atomic radius increases as you move down a group because new electron shells are added. This makes the atoms larger. For example, in the alkaline earth metals of Group 2A, you'll notice that Beryllium (Be) at the top is smaller than Barium (Ba) at the bottom.
In periods, the atomic radius decreases from left to right. This happens because electrons are added to the same shell and the nucleus attracts them more strongly, making the atomic radius smaller.
  • Within Group 2A, Barium has the largest atomic radius, while Beryllium has the smallest.
  • Within the second period, Lithium boasts the largest atomic radius, and Neon has the smallest.
These predictable trends help chemists to quickly identify how an element might interact with others.
Ionization Energy
Ionization energy refers to the amount of energy required to remove an electron from an isolated atom. This is a key aspect of understanding an element's reactivity and bonding behavior.
As you move across a period from left to right, ionization energy tends to increase. This is because elements grow more nuclear charge, yet the electron shielding doesn't increase, requiring more energy to remove an electron. Conversely, as you descend a group, ionization energy decreases due to the addition of electron shells, which increases electron shielding and makes it easier to remove an electron.
  • In Group 7A (halogens), Fluorine has the highest ionization energy due to a strong effective nuclear charge and less electron shielding.
  • Iodine, on the other hand, boasts the lowest ionization energy in this group, attributed to its larger size and increased electron shielding.
Understanding ionization energy helps us predict which elements are more likely to lose an electron and become positively charged ions.
Alkaline Earth Metals
The alkaline earth metals, found in Group 2A of the periodic table, are known for their reactivity and vital presence in various natural and industrial applications. This group includes Beryllium (Be), Magnesium (Mg), Calcium (Ca), Strontium (Sr), Barium (Ba), and Radium (Ra).
These metals have two electrons in their outermost shell, which they tend to lose, forming ions with a +2 charge. Their reactivity increases as you move down the group. For example, Beryllium has a higher ionization energy than Barium, making it less reactive.
Alkaline earth metals are essential in numerous applications, such as:
  • Construction, where Calcium compounds are critical for making cement and drywall.
  • Fireworks, typically involving Magnesium, which burns brightly.
  • Health, with Magnesium playing roles in bodily functions and supplements.
These metals are characterized by their metallic nature, lustrous appearance, and relatively high melting points.
Halogens
Halogens, residing in Group 7A of the periodic table, include elements like Fluorine (F), Chlorine (Cl), Bromine (Br), Iodine (I), and Astatine (At).
They are unique for their high reactivity, seeking to gain an additional electron to achieve a noble gas electron configuration. This reactivity decreases down the group as the atomic radius increases and electron shielding weakens their effective nuclear charge.
Some key uses and properties of halogens include:
  • Disinfectants: Chlorine is commonly used in water purification.
  • Pharmaceuticals: Iodine is essential in medical applications and diagnostics.
  • Industrial applications: Fluorine compounds are vital in creating Teflon and refrigerants.
Additionally, these elements exist in various physical states at room temperature, with Fluorine and Chlorine as gases, Bromine as a liquid, and Iodine and Astatine as solids.

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Most popular questions from this chapter

The natural abundance of boron isotopes is as follows: \(19.9 \%\) boron \(-10(10.013 \mathrm{amu})\) and \(80.1 \%\) boron- 11 \((11.009 \mathrm{amu})\). Calculate the atomic weight of boron (watch the significant figures) and compare your calculated value with that given in the Periodic Table.

Answer true or false. (a) Ionization energy is the energy required to remove the most loosely held electron from an atom in the gas phase. (b) When an atom loses an electron, it becomes a positively charged ion. (c) Ionization energy is a periodic property because ground-state electron configuration is a periodic property. (d) Ionization energy generally increases going from left to right across a period of the Periodic Table. (e) Ionization energy generally increases in going from top to bottom within a column in the Periodic Table. (f) The sign of an ionization energy is always positive.

The average atomic weight of lithium is 6.941 amu. The two naturally occurring isotopes of lithium have the following masses: \(^{6} \mathrm{Li}, 6.01512 \mathrm{amu} ;^{7} \mathrm{Li}, 7.01600\) amu. Calculate the percent abundance of \(^{6} \mathrm{Li}\) and \(^{7} \mathrm{Li}\) in naturally occurring lithium.

Answer true or false. (a) Matter is divided into elements and pure substances. (b) Matter is anything that has mass and volume (occupies space). (c) A mixture is composed of two or more pure substances. (d) An element is a pure substance. (e) A heterogeneous mixture can be separated into pure substances, but a homogeneous mixture cannot. (f) \(\quad\) A compound consists of elements combined in a fixed ratio. (g) A compound is a pure substance. (h) All matter has mass. (i) All of the 118 known elements occur naturally on Earth. (j) The first six elements in the Periodic Table are the most important for human life. (k) The combining ratio of a compound tells you how many atoms of each element are combined in the compound. (1) The combining ratio of 1: 2 in the compound \(\mathrm{CO}_{2}\) tells you that this compound is formed by the combination of one gram of carbon with two prams of oxygen.

The elements game, Part I. Name and give the symbol of the element that is named for each person. (a) Niels Bohr \((1885-1962),\) Nobel Prize for Physics in 1922 (b) Pierre and Marie Curie, Nobel Prize for Chemistry in 1903 (c) Albert Einstein \((1879-1955),\) Nobel Prize for Physics in 1921 (d) Enrico Fermi \((1901-1954),\) Nobel Prize for Physics in 1938 (e) Ernest Lawrence \((1901-1958),\) Nobel Prize for Physics in 1939 (f) Lise Meitner \((1868-1968),\) codiscoverer of nuclear fission (g) Dmitri Mendeleyev \((1834-1907),\) first person to formulate a workable Periodic Table (h) Alfred Nobel \((1833-1896),\) discoverer of dynamite (i) Ernest Rutherford \((1871-1937),\) Nobel Prize for Chemistry in 1908. (j) Glenn Seaborg (1912-1999), Nobel Prize for Chemistry in 1951.

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