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(Chemical Connections \(11 \mathrm{C}\) ) What are Freons? Why were they considered ideal compounds to use as heat-transfer agents in refrigeration systems? Give structural formulas of two Freons used for this purpose.

Short Answer

Expert verified
Freons are halogenated hydrocarbons used as refrigerants; they were ideal due to their stability, low boiling points, and non-toxicity. Examples: Freon-12 (CFâ‚‚Clâ‚‚) and Freon-22 (CHClFâ‚‚).

Step by step solution

01

Understanding Freons

Freons are a group of halogenated hydrocarbons, mostly chlorofluorocarbons (CFCs), commonly used as refrigerants, propellants, and solvents. They are non-flammable, non-toxic, and very stable, which made them a popular choice in refrigeration systems.
02

Characteristics of Freons

Freons have properties that were ideal for use in refrigeration systems: they have low boiling points, are capable of being easily vaporized and condensed, and are chemically inert, preventing them from reacting with other substances in the system.
03

Structural Formulas of Common Freons

Two examples of Freons used in refrigeration systems are Freon-12 and Freon-22. Freon-12 has the chemical formula CFâ‚‚Clâ‚‚ (Dichlorodifluoromethane), and Freon-22 has the chemical formula CHClFâ‚‚ (Chlorodifluoromethane). These compounds consist of carbon atoms bonded to chlorine and fluorine atoms.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Halogenated Hydrocarbons
Halogenated hydrocarbons are chemical compounds where one or more hydrogen atoms in a hydrocarbon molecule have been replaced by halogen atoms like fluorine, chlorine, bromine, or iodine. This group of compounds includes a variety of chemicals, but the ones most relevant to refrigeration are chlorofluorocarbons (CFCs). These are derived from methane or ethane and contain carbon, chlorine, and fluorine.

The substitution of halogens for hydrogen in these compounds significantly alters their chemical and physical properties. For instance, it contributes to greater stability and resistance to combustion. Such stability is advantageous for refrigerants as it ensures that the compounds won’t break down easily or explode.

  • Non-flammable: Making them safer for use in environments where high pressures and temperatures occur.
  • Chemically inert: They do not react easily with other materials, preventing equipment corrosion.
  • Stable: Can resist breakdown, which is critical in systems designed for long-term use.
Chlorofluorocarbons
Chlorofluorocarbons, often referred to as CFCs, are a class of compounds that include carbon, chlorine, and fluorine atoms. These compounds emerged as revolutionary solutions for industrial needs in the 20th century due to their unique properties. One of their salient attributes is their suitability as refrigerants, propellants, and cleaning solvents.

The advantages of CFCs in refrigeration systems stem from their low boiling points, ensuring efficient heat absorption and release during vaporization and condensation cycles. This property enables them to maintain stable temperatures, which is crucial in preserving perishable goods.

Despite their efficacy, CFCs gained notoriety due to environmental concerns. Their release into the atmosphere leads to ozone layer depletion, posing challenges that have since led to the development of alternatives like hydrochlorofluorocarbons (HCFCs) and hydrofluorocarbons (HFCs), both designed to be less harmful to the environment.
Refrigeration Systems
Refrigeration systems are an essential part of modern life, playing a crucial role in preserving food, cooling environments, and supporting industrial processes. These systems utilize a cycle of evaporation and condensation, where a refrigerant absorbs heat from one location and releases it in another, thus cooling the designated space.

Freons, primarily CFCs like Freon-12 (CFâ‚‚Clâ‚‚) and Freon-22 (CHClFâ‚‚), were pivotal in the development of these systems. Their low boiling points and chemical inertness made them efficient at circulating within the refrigeration unit without reacting with the components. As the refrigerant vaporizes, it absorbs heat, which is critical for the cooling process. Once it condenses, it releases the absorbed heat, thus completing the cycle.

The historical use of Freons has shifted with the rise of environmental awareness. The refrigeration industry now seeks safer alternatives that do not contribute to ozone layer depletion while maintaining the efficiency needed for effective cooling. This shift has brought new challenges and innovations to the field.

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Most popular questions from this chapter

Answer true or false. (a) The two major sources of alkanes the world over are petroleum and natural gas. (b) The octane number of a particular gasoline is the number of grams of octane per liter of the fuel. (c) Octane and 2,2,4 -trimethylpentane are constitutional isomers and have the same octane number.

The reaction of chlorine with pentane gives a mixture of three chloroalkanes, each with the molecular formula \(\mathrm{C}_{5} \mathrm{H}_{11} \mathrm{Cl}\). Write a line-angle formula and the IUPAC name for each chloroalkane.

Answer true or false. (a) Freons are members of a class of organic compounds called chlorofluorocarbons (CFCs). (b) An advantage of Freons as heat-transfer agents in refrigeration systems, propellants in aerosol sprays, and solvents for industrial cleaning is that they are nontoxic, nonflammable, odorless, and noncorrosive. (c) Freons in the stratosphere interact with ultraviolet radiation and thereby set up chemical reactions that lead to the destruction of the stratospheric ozone layer. (d) Alternative names for the important laboratory and industrial solvent \(\mathrm{CH}_{2} \mathrm{Cl}_{2}\) are dichloromethane, methylene chloride, and chloroform.

(Chemical Connections \(11 \mathrm{C}\) ) In what way do Freons negatively affect the environment?

As stated in Section 11.9 , the wax found in apple skins is an unbranched alkane with the molecular formula \(\mathrm{C}_{27} \mathrm{H}_{56}\). Explain how the presence of this alkane in apple skins prevents the loss of moisture from within the apple.

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