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What is Charles's law in mathematical terms?

Short Answer

Expert verified
Mathematically, Charles's law is expressed as \(V/T = k\), where \(V\) is the volume, \(T\) is the temperature in Kelvin, and \(k\) is a constant.

Step by step solution

01

Understanding Charles's law

Charles's Law, also known as the law of volumes, is an experimental gas law that describes how gases tend to expand when heated. It is attributed to 18th-century French chemist Jacques Charles.
02

Defining Charles's Law in words

The law states that, under constant pressure, the volume of a given mass of an ideal gas increases or decreases by the same factor as its temperature (in kelvin) increases or decreases.
03

Expressing Charles's Law mathematically

Mathematically, Charles's law is written as \(V/T = k\), where \(V\) is the volume, \(T\) is the temperature in Kelvin, and \(k\) is a constant.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Gas Laws
Gas laws are fundamental principles that describe the behavior of gases under varying conditions of temperature, pressure, and volume. Among these laws, Charles's Law plays a crucial role by detailing the relationship between temperature and volume of a gas. Understanding gas laws is essential for solving problems in both physics and chemistry fields, as these laws help predict how gases will react when subjected to changes.

Charles's Law, specifically, states that the volume of a gas is directly proportional to its temperature, as long as the pressure remains constant. This proportional relationship means that if the temperature of a gas increases, its volume will increase as well, and conversely, if the temperature decreases, the volume will also decrease. This law helps in explaining real-world phenomena, such as the inflation and deflation of hot air balloons with changes in temperature.
Ideal Gas Behavior
Ideal gas behavior is a hypothetical concept where a gas is assumed to be made of randomly moving particles that do not interact with each other except during elastic collisions. This simplified model is described by the Ideal Gas Law, a combination of Boyle's, Charles's, and Avogadro's laws. The Ideal Gas Law formula is expressed as \(PV = nRT\), where \(P\) is the pressure, \(V\) is the volume, \(n\) is the number of moles, \(R\) is the universal gas constant, and \(T\) is the temperature in Kelvin.

Charles's Law is a special case of the Ideal Gas Law, where pressure and the amount of gas are held constant. To grasp the behavior of real gases which deviate from these assumptions, scientists use various correction factors. Nevertheless, the ideal gas model remains essential in chemistry and physics, as it provides a close approximation for the behavior of real gases under many conditions.
Thermodynamics
Thermodynamics is the branch of physical science that deals with the relations between heat and other forms of energy, such as work. It lays the groundwork for understanding how energy is transformed and transferred in physical and chemical processes. Charles's Law fits within the context of thermodynamics by describing how a gas's volume changes with temperature – a form of thermal expansion.

At a microscopic level, when a gas is heated, the average kinetic energy of its molecules increases. This increase in kinetic energy causes the molecules to move faster and collide more forcefully with the walls of the container, leading to an increase in volume. Thermodynamics helps in calculating work done during the expansion or compression of a gas, which is critical in engines and refrigeration systems. Overall, the field of thermodynamics has far-reaching applications in various disciplines, including engineering, astronomy, and even biology.

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Most popular questions from this chapter

Given that \(P V=n R T\), solve for the unknown quantity. $$ \begin{array}{|l|l|l|l|l|} \hline \multicolumn{1}{|c|}{\boldsymbol{P}} & \multicolumn{1}{c|}{\boldsymbol{V}} & \multicolumn{1}{c|}{\boldsymbol{n}} & \multicolumn{1}{c|}{\boldsymbol{R}} & \multicolumn{1}{c|}{\boldsymbol{T}} \\ \hline 3.55 & 1.75 & 0.205 & 0.08206 & ? \\ \hline 1.00 & 22.5 & ? & 0.08206 & 298 \\ \hline 0.125 & ? & 3.00 & 0.08206 & 535 \\ \hline ? & 6.25 & 1.57 & 0.08206 & 343 \\ \hline \end{array} $$

Explain in molecular terms why the pressure of a gas increases with increasing temperature when the volume is held constant.

For a fixed amount of gas held at constant pressure, calculate the temperature in degrees Celsius to which the gas would have to be changed to achieve the change in volume shown in the following table. $$ \begin{array}{|c|c|c|c|} \hline \begin{array}{c} \text { Initial } \\ \text { Temperature } \end{array} & \begin{array}{c} \text { Initial } \\ \text { Volume } \end{array} & \begin{array}{c} \text { Final } \\ \text { Volume } \end{array} & \begin{array}{c} \text { Final } \\ \text { Temperature } \end{array} \\ \hline 100.0^{\circ} \mathrm{C} & 250.0 \mathrm{~mL} & 100.0 \mathrm{~mL} & ? \\\ \hline 27.5^{\circ} \mathrm{C} & 125 \mathrm{~mL} & 148 \mathrm{~mL} & ? \\ \hline 300 \mathrm{~K} & 13.7 \mathrm{~L} & 57.2 \mathrm{~L} & ? \\ \hline \end{array} $$

Consider the combustion of butene: $$ \mathrm{C}_{4} \mathrm{H}_{8}(g)+6 \mathrm{O}_{2}(g) \longrightarrow 4 \mathrm{CO}_{2}(g)+4 \mathrm{H}_{2} \mathrm{O}(g) $$ What volume of butene at \(188^{\circ} \mathrm{C}\) and \(2.50 \mathrm{~atm}\) can be burned with \(12.0 \mathrm{~L}\) of \(\mathrm{O}_{2}\) at 745 torr and \(25.0^{\circ} \mathrm{C}\) ?

Boyle used a U-tube to investigate gas properties. As shown in the figure, a gas was trapped in the closed arm of the U-tube at \(29.9 \mathrm{in} \mathrm{Hg}\), and the pressure was varied by adding mercury to the open arm. The total pressure exerted on the gas is the sum of the atmospheric pressure ( \(29.9\) in \(\mathrm{Hg}\) ) and the pressure due to the addition of mercury as measured by the difference in mercury height. Boyle recorded the following data: $$ \begin{array}{|c|c|} \hline \begin{array}{c} \text { Length of Gas Column } \\ \text { (in) } \end{array} & \begin{array}{c} \text { Difference Between } \\ \text { Mercury Levels (in), } \Delta h \end{array} \\ \hline 48 & 0.0 \\ \hline 44 & 2.8 \\ \hline 40 & 6.2 \\ \hline 36 & 10.1 \\ \hline 32 & 15.1 \\ \hline 28 & 21.2 \\ \hline 24 & 29.7 \\ \hline 22 & 35.0 \\ \hline 20 & 41.6 \\ \hline 18 & 48.8 \\ \hline 16 & 58.2 \\ \hline \end{array} $$ Graph these data. What does the graph show about the relationship between volume and pressure?

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