Chapter 9: Problem 46
What is Charles's law in mathematical terms?
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Chapter 9: Problem 46
What is Charles's law in mathematical terms?
These are the key concepts you need to understand to accurately answer the question.
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Given that \(P V=n R T\), solve for the unknown quantity. $$ \begin{array}{|l|l|l|l|l|} \hline \multicolumn{1}{|c|}{\boldsymbol{P}} & \multicolumn{1}{c|}{\boldsymbol{V}} & \multicolumn{1}{c|}{\boldsymbol{n}} & \multicolumn{1}{c|}{\boldsymbol{R}} & \multicolumn{1}{c|}{\boldsymbol{T}} \\ \hline 3.55 & 1.75 & 0.205 & 0.08206 & ? \\ \hline 1.00 & 22.5 & ? & 0.08206 & 298 \\ \hline 0.125 & ? & 3.00 & 0.08206 & 535 \\ \hline ? & 6.25 & 1.57 & 0.08206 & 343 \\ \hline \end{array} $$
Explain in molecular terms why the pressure of a gas increases with increasing temperature when the volume is held constant.
For a fixed amount of gas held at constant pressure, calculate the temperature in degrees Celsius to which the gas would have to be changed to achieve the change in volume shown in the following table. $$ \begin{array}{|c|c|c|c|} \hline \begin{array}{c} \text { Initial } \\ \text { Temperature } \end{array} & \begin{array}{c} \text { Initial } \\ \text { Volume } \end{array} & \begin{array}{c} \text { Final } \\ \text { Volume } \end{array} & \begin{array}{c} \text { Final } \\ \text { Temperature } \end{array} \\ \hline 100.0^{\circ} \mathrm{C} & 250.0 \mathrm{~mL} & 100.0 \mathrm{~mL} & ? \\\ \hline 27.5^{\circ} \mathrm{C} & 125 \mathrm{~mL} & 148 \mathrm{~mL} & ? \\ \hline 300 \mathrm{~K} & 13.7 \mathrm{~L} & 57.2 \mathrm{~L} & ? \\ \hline \end{array} $$
Consider the combustion of butene: $$ \mathrm{C}_{4} \mathrm{H}_{8}(g)+6 \mathrm{O}_{2}(g) \longrightarrow 4 \mathrm{CO}_{2}(g)+4 \mathrm{H}_{2} \mathrm{O}(g) $$ What volume of butene at \(188^{\circ} \mathrm{C}\) and \(2.50 \mathrm{~atm}\) can be burned with \(12.0 \mathrm{~L}\) of \(\mathrm{O}_{2}\) at 745 torr and \(25.0^{\circ} \mathrm{C}\) ?
Boyle used a U-tube to investigate gas properties. As shown in the figure, a gas was trapped in the closed arm of the U-tube at \(29.9 \mathrm{in} \mathrm{Hg}\), and the pressure was varied by adding mercury to the open arm. The total pressure exerted on the gas is the sum of the atmospheric pressure ( \(29.9\) in \(\mathrm{Hg}\) ) and the pressure due to the addition of mercury as measured by the difference in mercury height. Boyle recorded the following data: $$ \begin{array}{|c|c|} \hline \begin{array}{c} \text { Length of Gas Column } \\ \text { (in) } \end{array} & \begin{array}{c} \text { Difference Between } \\ \text { Mercury Levels (in), } \Delta h \end{array} \\ \hline 48 & 0.0 \\ \hline 44 & 2.8 \\ \hline 40 & 6.2 \\ \hline 36 & 10.1 \\ \hline 32 & 15.1 \\ \hline 28 & 21.2 \\ \hline 24 & 29.7 \\ \hline 22 & 35.0 \\ \hline 20 & 41.6 \\ \hline 18 & 48.8 \\ \hline 16 & 58.2 \\ \hline \end{array} $$ Graph these data. What does the graph show about the relationship between volume and pressure?
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