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Consider the following two-step reaction: $$ \begin{aligned} \mathrm{H}_{2} \mathrm{O}_{2}+& 2 \mathrm{Br}^{-}+2 \mathrm{H}^{+} \longrightarrow 2 \mathrm{H}_{2} \mathrm{O}+\mathrm{Br}_{2} \\ \mathrm{H}_{2} \mathrm{O}_{2}+\mathrm{Br}_{2} & \longrightarrow 2 \mathrm{H}^{+}+\mathrm{O}_{2}+2 \mathrm{Br}^{-} \end{aligned} $$ (a) Identify any catalysts or intermediates. (b) Write the net reaction.

Short Answer

Expert verified
There are no catalysts in the given reactions. The only intermediate in the reactions is \(Br_{2}\). The net reaction is \(2H_{2}O_{2} \longrightarrow 2H_{2}O + O_{2}\)

Step by step solution

01

Identification of Catalysts

A catalyst is a substance that speeds up a chemical reaction but is not consumed in the reaction. That means it appears in the reactants of the first reaction and in the products of the last reaction. Here, from the given reactions, there are no species that fulfill this criterion. Hence, there are no catalysts in the given reactions.
02

Identification of Intermediates

Intermediates are species that are produced in one reaction (forming part of the products) and consumed in a subsequent reaction (forming part of the reactants). Looking at the two reactions, it can be seen that \(Br_{2}\) is formed in the first reaction and consumed in the second reaction. Hence, \(Br_{2}\) is an intermediate.
03

Writing the Net Reaction

Addition of the two reactions and then cancellation of any species that appears on both sides of the reaction leads to the net reaction. The net reaction equation can be written by summing the two given reactions and eliminating \(Br_{2}\). This results in the final reaction: \(2H_{2}O_{2} \longrightarrow 2H_{2}O + O_{2}\)

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Chemical Reaction Mechanisms
A chemical reaction mechanism provides a detailed step-by-step description of the process by which reactants transform into products. It lays out each individual reaction stage, detailing the sequence of chemical events at the molecular level. Understanding the mechanism is crucial as it explains how a reaction proceeds, which intermediates are formed, and the speed or rate at which the products are created.

For example, consider the provided reaction involving hydrogen peroxide and bromide ions. The reaction occurs in two distinct stages. Each stage involves different species and can exhibit unique speeds. It's the sum of these stages that constitute the overall mechanism of the reaction, giving insight into the behavior and potential energy changes associated with the process.
Identification of Catalysts
Identifying catalysts in a chemical reaction involves looking for substances that reappear unchanged after the reaction has completed. A catalyst lowers the activation energy for the reaction, thus increasing its rate. However, it's crucial to note that a catalyst is not consumed in the overall reaction; it's recovered at the end.

In the given two-step reaction, no substance meets the criteria for a catalyst, as none reappears unchanged. This observation aligns with the solution provided, confirming that no catalyst is involved in transforming hydrogen peroxide into water and oxygen in the presence of bromide ions.
Identification of Intermediates
Intermediates are entities that form in the middle of a multi-step reaction process; they appear as products in one step and reactants in another but are not present in the net reaction. They are often short-lived and can be difficult to detect.

As outlined in the solution, bromine (\(Br_{2}\)) is identified as an intermediate in this reaction. It appears momentarily after the first reaction, only to be consumed in the second. Understanding intermediates is essential for unraveling the route from reactants to products and for designing experiments to probe or even manipulate the reaction pathway.
Writing Net Chemical Reactions
Constructing the net chemical reaction involves summing up all the steps in the mechanism and then canceling out any species that appear as both a product and a reactant. This provides a simplified version of the overall reaction, showing only the direct transformation of initial reactants to final products without the details of the intermediate stages.

In the problem given, once the two reactions are added, bromine, which serves as an intermediate, cancels out, leaving the net reaction to simply be the decomposition of hydrogen peroxide into water and oxygen. Writing net reactions is a concise way to understand the overall process without the complexities of the underpinning steps.

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