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Which solution, \(1.0 m \mathrm{NaCl}\) or \(1.0 m\) glucose, \(\mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6}\), should have the highest boiling point? Explain.

Short Answer

Expert verified
The solution of \(1.0 m \mathrm{NaCl}\) should have the highest boiling point because \(\mathrm{NaCl}\) dissociates into two ions in water thereby raising the boiling point more than glucose, which doesn't dissociate.

Step by step solution

01

Analyzing the solute in the solutions

First, it is important to analyze the nature of the solute in both solutions. We have \(1.0 m \mathrm{NaCl}\) and \(1.0 m\) glucose, \(\mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6}\). Sodium chloride is an ionic compound and it tends to dissociate into its ions when mixed with water. On the other hand, glucose is a molecular compound and it does not dissociate in water.
02

Counting the number of particles in each solution

In the \(1.0 m \mathrm{NaCl}\) solution when \(\mathrm{NaCl}\) dissolves in water, it dissociates into two ions: \(\mathrm{Na^{+}}\) and \(\mathrm{Cl^{-}}\). So there are two particles. On the other hand, glucose \(\mathrm{C_{6}H_{12}O_{6}}\) does not dissociate, hence there is only one particle.
03

Comparing the boiling points

The boiling point of a solution is higher if there are more particles in the solution. Since \(\mathrm{NaCl}\) dissociates into two particles in water whereas glucose does not dissociate, the \(\mathrm{NaCl}\) solution should have a higher boiling point compared to the glucose solution.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Ionic Compounds
Ionic compounds are made up of positive and negative ions held together by ionic bonds. These compounds typically form when metals react with non-metals. When ionic compounds dissolve in water, they tend to dissociate into their constituent ions. For example, sodium chloride (NaCl) dissociates into sodium ions
  • \( \text{Na}^+ \)
  • \( \text{Cl}^- \)
This dissociation is significant because it increases the number of particles in a solution.
When the number of particles in the solution increases, properties such as the boiling point are affected. Boiling point elevation occurs because more energy is needed to enable the solvent's molecules to escape as vapor.
This effect is directly related to the number of solute particles present in the solution.
Molecular Compounds
Molecular compounds consist of molecules formed by covalent bonds between atoms. Typically, these compounds are non-metals. Unlike ionic compounds, molecular compounds do not dissociate into ions when dissolved in water.
For instance, glucose (\( \text{C}_6\text{H}_{12}\text{O}_6 \)) remains intact as entire molecules in a solution. This integrity means the number of particles in the solution is less compared to ionic solutions with the same concentration.
  • Since glucose does not separate into smaller particles, the boiling point elevation of its solution is lower.
Understanding the behavior of these compounds helps in predicting how a solution will behave in terms of boiling point and other colligative properties.
Solute Dissociation
Solute dissociation is the process where a compound breaks into smaller particles, such as ions, when dissolving in a solvent like water. This is common in ionic compounds but not in molecular compounds.
When a solute dissociates, it produces more particles in the solution, amplifying colligative effects such as boiling point elevation and freezing point depression.
In the case of sodium chloride \( \text{(NaCl)} \), the dissociation increases the particle count from one to two, thereby resulting in a higher boiling point increase compared to a non-dissociating solute like glucose.
  • This effect is especially relevant in various scientific and industrial applications, emphasizing the importance of understanding whether a compound will dissociate in a given liquid.
  • This understanding is critical for solutions where the boiling point is a factor of interest.
Thus, the behavior of solutes upon dissolution plays a critical role in determining the physical properties of solutions.

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