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A \text { square planar complex is formed by hybridization of } which atomic orbitals? (a) \(s, p_{x}, p_{y}, p_{z}, d_{y z}\) (b) \(s, p_{x}, p_{y}, d_{x}{ }^{2}-y^{2}\) (c) \(s, p_{x}, p_{y}, d_{z}{ }^{2}\) \quad\( (d) \)s, p_{x}, p_{z}, d_{x y}$

Short Answer

Expert verified
Option (b): s, p_x, p_y, d_虫虏-测虏.

Step by step solution

01

Understand the Concept of Hybridization

Hybridization is the process of combining atomic orbitals to form new hybrid orbitals suitable for the pairing of electrons to form chemical bonds. For square planar complexes, the central metal atom typically undergoes dsp虏 hybridization.
02

Identify the Orbitals Involved in dsp虏 Hybridization

In dsp虏 hybridization, one s, two p, and one d orbital are mixed. Specifically, the involved orbitals are the s, two equatorial p orbitals (usually p_x and p_y), and the d_虫虏-测虏 orbital.
03

Evaluate Each Given Choice

Compare each option against dsp虏 hybridization. - Option (a): includes d_yz, which is not involved in dsp虏. - Option (b): includes s, p_x, p_y, and d_虫虏-测虏 which exactly matches dsp虏. - Option (c): includes d_z虏 which is associated with dsp鲁 hybridization, not dsp虏. - Option (d): includes d_xy, which does not match dsp虏.
04

Select the Correct Answer

Based on the evaluation, option (b) s, p_x, p_y, d_虫虏-测虏 aligns with dsp虏 hybridization, making it the correct choice.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Square Planar Complex
A square planar complex is a type of coordination compound where the central metal atom is surrounded by atoms or groups of atoms lying at the four corners of a square. This arrangement is a result of the specific hybridization called dsp虏 hybridization.

In square planar complexes, the geometry is crucial for understanding how atoms are organized around the central atom. This geometric arrangement helps to minimize repulsions between the electron pairs in chemical bonds, thus making the complex more stable.

Frequently, square planar complexes are observed in transition metals. Metals like platinum, palladium, and gold often form square planar complexes due to their electronic configurations. These metals have the right number of d electrons to allow the dsp虏 hybridization process to take place without issues.

  • The central atom typically has a coordination number of four.
  • Common amongst d鈦 metal ions where low spin configurations are favored.
  • Utilizes dsp虏 hybrid orbitals, which lead to a flat, symmetric shape.
Atomic Orbitals
Atomic orbitals are the regions around an atom's nucleus where the probability of finding electrons is highest. These regions have specific shapes and energy levels. They are fundamental in understanding how atoms combine and bond in molecules.

Each atomic orbital is characterized by a set of quantum numbers:
  • Principal Quantum Number (n): Determines the size and energy of the orbital.
  • Azimuthal Quantum Number (l): Defines the shape of the orbital.
  • Magnetic Quantum Number (m): Indicates the orientation of the orbital in space.
  • Spin Quantum Number (s): Describes the two possible orientations (spin) of the electron within an orbital.

Atomic orbitals such as s, p, and d play a crucial role in hybridization. For dsp虏 hybridization, the orbitals involved are specifically the s, two p orbitals (typically px and py), and the d虫虏-测虏. This unique combination is what allows the formation of square planar complexes, providing a very specific and stable electronic arrangement around the central atom.
Hybridization
Hybridization is the concept of mixing atomic orbitals to form new hybrid orbitals, which are used to describe the electronic structure of molecules, particularly the bonds they form. The number and types of orbitals involved in hybridization determine the geometry of the resulting complex or molecule.

In dsp虏 hybridization, which is crucial for forming square planar complexes, the mixing involves:
  • One s orbital: Contributes to the spherical symmetry of the orbital arrangement.
  • Two p orbitals: Typically the px and py orbitals, contributing directional properties.
  • One d orbital: Specifically d虫虏-测虏, which is directional and fits into the planar structure.
This hybridization creates four equivalent orbitals, perfectly suitable for organizing the ligands symmetrically around the central metal atom in a square planar fashion.

Hybridization helps explain not only the geometry but also the bonding properties and angles in complex molecules. Understanding this concept is vital in the field of chemistry, as it provides insights into molecular structure and reactivity.

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