Chapter 11: Problem 78
Which compound acts as an oxidising as well as a reducing agent? (a) \(\mathrm{SO}_{2}\) (b) \(\mathrm{MnO}_{2}\) (c) \(\mathrm{Al}_{2} \mathrm{O}_{3}\) (d) \(\mathrm{CrO}_{3}\)
Short Answer
Expert verified
SO_{2} acts as both an oxidizing and reducing agent.
Step by step solution
01
Understanding Redox Behavior
A compound that acts as both an oxidizing and reducing agent can undergo both reduction (gaining electrons) and oxidation (losing electrons). To identify such a compound among the options, we need to determine which compounds can change oxidation states in both directions.
02
Analyze \\(\mathrm{SO}_{2}\\)
\(\mathrm{SO}_{2}\) often acts as a reducing agent. However, in some reactions, it can be oxidized to \(\mathrm{SO}_{3}\) or reduced to sulfur. Thus, it can act as both reducing and oxidizing agent.
03
Analyze \\(\mathrm{MnO}_{2}\\)
\(\mathrm{MnO}_{2}\) primarily acts as an oxidizing agent, particularly reducing to \(\mathrm{Mn}^{2+}\). It rarely acts as a reducing agent.
04
Analyze \\(\mathrm{Al}_{2}\mathrm{O}_{3}\\)
\(\mathrm{Al}_{2}\mathrm{O}_{3}\) is a stable compound and doesn't change oxidation states easily. It generally does not act as either an oxidizing or reducing agent.
05
Analyze \\(\mathrm{CrO}_{3}\\)
\(\mathrm{CrO}_{3}\) acts as a strong oxidizing agent, converting into \(\mathrm{Cr}^{3+}\) when reduced. Under some conditions, it can be reduced further, but it's not known for acting as a reducing agent.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Oxidizing Agent
An oxidizing agent is a substance that gains electrons in a chemical reaction. This means it **oxidizes** another species, while itself getting reduced. It's like the "electron grabber" in a reaction. Oxidizing agents are essential because they drive many chemical processes by accepting electrons.
An easy way to remember what an oxidizing agent does is to think about its function:
For example, \(\mathrm{MnO}_{2}\), in reactions, reduces to form \(\mathrm{Mn}^{2+}\). This shows it acting as an oxidizing agent by accepting electrons from another compound.
An easy way to remember what an oxidizing agent does is to think about its function:
- It gets reduced (gains electrons).
- It causes the oxidation of another agent.
For example, \(\mathrm{MnO}_{2}\), in reactions, reduces to form \(\mathrm{Mn}^{2+}\). This shows it acting as an oxidizing agent by accepting electrons from another compound.
Reducing Agent
A reducing agent is the opposite of an oxidizing agent. It loses electrons and in doing so, it reduces another substance. Think of it as the "electron donor" in a chemical reaction. Reducing agents play a crucial role in many processes by supplying electrons.
Here's what you should know:
Here's what you should know:
- It gets oxidized (loses electrons).
- It causes the reduction of another agent.
Oxidation States
Understanding oxidation states is critical to identifying oxidizing and reducing agents. The oxidation state is a hypothetical charge that an atom would have if all bonds to atoms of different elements were completely ionic.
Here's a quick rundown on oxidation states:
Overall, being able to track oxidation states lets you understand who gains or loses electrons during a reaction, revealing the roles of different agents.
Here's a quick rundown on oxidation states:
- Elements in their natural state have an oxidation state of zero.
- Oxygen commonly has an oxidation state of -2.
- The sum of oxidation states in a molecule must equal the overall charge of the molecule.
Overall, being able to track oxidation states lets you understand who gains or loses electrons during a reaction, revealing the roles of different agents.