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When \(\mathrm{NH}_{4} \mathrm{OH}\) is added to copper sulphate solution, blue colour is obtained due to formation of: (a) \(\mathrm{Cu}\left(\mathrm{NH}_{3}\right)_{4} \mathrm{SO}_{4}\) \(\square\) (b) \(\mathrm{Cu}\left(\mathrm{NH}_{4} \mathrm{SO}_{4}\right)_{2}\) (c) \(\mathrm{Cu}(\mathrm{OH})_{2}\) \(\square\) (d) \(\mathrm{CuO}\)

Short Answer

Expert verified
The blue color is due to the formation of Cu(NH鈧)鈧劼测伜, which matches option (a).

Step by step solution

01

Analyzing the Reaction

When ammonium hydroxide ( H鈧凮H) is added to copper(II) sulfate ( CuSO鈧) solution, a complex formation occurs. Initially, a light blue precipitate of copper(II) hydroxide, Cu(OH)鈧, is formed temporarily.
02

Understanding Complex Formation

Upon adding excess ammonia (from H鈧凮H) to the solution, the precipitate dissolves, forming a deep blue-colored complex due to the formation of copper(II) tetraammine complex Cu(NH鈧)鈧劼测伜.
03

Recognizing the Formation

The deep blue color is characteristic of the Cu(NH鈧)鈧劼测伜 complex, which is often associated with copper ammine complexes. This complex highlights the coordination chemistry of copper with ammonia ligands.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Cu(NH鈧)鈧劼测伜 complex
The Cu(NH鈧)鈧劼测伜 complex is a fascinating coordination compound where copper ions form a complex ion with ammonia molecules. This complex ion is known for its intense deep blue color. When you dissolve copper sulfate in water and add ammonium hydroxide, you first see the formation of a light blue precipitate, copper(II) hydroxide \((Cu(OH)_2)\). However, as you add more ammonia, this precipitate dissolves and transforms into the Cu(NH鈧)鈧劼测伜 complex.

This transformation involves the ligands (ammonia molecules) attaching to the central copper ion. In this case, four ammonia molecules coordinate with the copper ion to form the Cu(NH鈧)鈧劼测伜 complex. This complex ion is soluble in water, which is why it doesn't precipitate out, but rather imparts a deep blue color to the solution.
Copper ammine complexes
Copper ammine complexes are a group of compounds comprising a central copper ion and ammonia molecules as ligands. These complexes are prominent examples within coordination chemistry, showcasing how metals interact with organic molecules like ammonia.

In the case of the Cu(NH鈧)鈧劼测伜 complex, copper(II) exhibits a +2 oxidation state, surrounded by four ammonia molecules. Ammonia acts as a monodentate ligand, meaning each ammonia molecule coordinates through a single atom鈥攊n this case, nitrogen. The nitrogen's lone pair of electrons are donated to the copper ion, forming coordinate covalent bonds.
  • Coordination Number: The number of ligands bound to the central metal is called the coordination number, which is four for our complex.
  • Geometry: This specific arrangement often results in a square planar or tetrahedral geometry, influencing properties such as color and magnetic behavior.
Understanding this, you can see how the properties of copper ammine complexes, including their vivid colors, are directly related to the metal-ligand interactions.
Complex Formation
Complex formation is a fundamental process in coordination chemistry and is particularly interesting in reactions involving transition metals like copper. In the discussed reaction, complex formation refers to the transformation from a simple ionic compound to a complex ion.

Initially, copper sulfate in solution contains hydrated copper ions \((Cu^{2+})\). Once ammonia is added, the initial light blue precipitate (Cu(OH)鈧) forms due to limited solubility. However, with excess ammonia, this precipitate interacts with the ammonia molecules, and through a series of complexation steps, it becomes solubilized again as Cu(NH鈧)鈧劼测伜.

This formation process involves:
  • Ligand Exchange: Ammonia molecules displace water molecules around the copper ion, leading to a stable complex.
  • Color Change: Transition from a pale blue to deep blue signifies the formation of the new complex.
  • Stability: Generally, forming such complexes stabilizes the metal ions in solution, preventing precipitates and enabling unique chemical properties.
In any complex formation, the resultant complex exhibits new chemical and physical properties unforeseen in the original components. It exemplifies the transition metal's ability to act as a hub for detailed coordination and interaction in chemical reactions.

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