Chapter 10: Problem 10
(a) Write equations for the reactions of KH with \(\mathrm{NH}_{3}\) and with ethanol. (b) Identify the conjugate acid-base pairs in each reaction.
Short Answer
Expert verified
(a) KH reacts with NH鈧 to form KNH鈧 and H鈧; with ethanol to form C鈧侶鈧匫K and H鈧. (b) Conjugate pairs: KH/H鈧 and NH鈧/NH鈧傗伝; KH/H鈧 and C鈧侶鈧匫H/C鈧侶鈧匫鈦.
Step by step solution
01
Write the Reaction of KH with NH3
The first reaction involves the interaction of potassium hydride (KH) with ammonia (NH鈧). Potassium hydride is a strong base and will react with ammonia, which acts as an acid in this scenario (donating a hydrogen ion). The balanced chemical equation for this reaction is: \[ \text{KH} + \text{NH}_3 \rightarrow \text{KNH}_2 + \text{H}_2 \] Here, potassium hydride donates a hydride ion (\(H^-\)) to ammonia, resulting in the formation of potassium amide (KNH鈧) and hydrogen gas (H鈧).
02
Identify the Conjugate Acid-Base Pairs in First Reaction
In the reaction of KH with NH鈧, identify the acid-base pairs. The base is KH, which forms the conjugate acid, H鈧, after donating a hydride ion. NH鈧, acting as an acid, forms its conjugate base, \(NH_2^-\) (as part of KNH鈧) after accepting a hydride ion. Thus, the acid-base pairs are: \( \text{KH (base)} \rightarrow \text{H}_2 (conjugate acid)} \) and \( \text{NH}_3 (acid)} \rightarrow \text{NH}_2^- \text{(conjugate base)} \).
03
Write the Reaction of KH with Ethanol
Next, consider the reaction between potassium hydride (KH) and ethanol (C鈧侶鈧匫H). In this reaction, KH again acts as a base and ethanol as an acid (donating a hydrogen ion from the hydroxyl group). The chemical equation for this reaction is: \[ \text{KH} + \text{C}_2\text{H}_5\text{OH} \rightarrow \text{C}_2\text{H}_5\text{OK} + \text{H}_2 \] Potassium ethoxide (C鈧侶鈧匫K) and hydrogen gas (H鈧) are the products, with KH donating a hydride ion to ethanol which releases hydrogen gas.
04
Identify the Conjugate Acid-Base Pairs in Second Reaction
In the reaction with ethanol, KH again donates a hydride ion and forms hydrogen gas, making it the base. Its conjugate acid is H鈧. Ethanol (C鈧侶鈧匫H) donates a proton, becoming potassium ethoxide (C鈧侶鈧匫鈦), acting as the acid. Thus, the conjugate acid-base pairs are: \( \text{KH (base)} \rightarrow \text{H}_2 \text{(conjugate acid)} \) and \( \text{C}_2\text{H}_5\text{OH (acid)} \rightarrow \text{C}_2\text{H}_5\text{O}^- \text{(conjugate base)} \).
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Conjugate Acid-Base Pairs
In chemistry, an acid-base reaction involves the transfer of protons (H鈦 ions) from acids to bases. This interaction forms what are called conjugate acid-base pairs.
A conjugate acid-base pair is a pair of compounds that transform into each other by gain or loss of a proton:
- An acid releases a proton and, as a result, becomes a conjugate base.
- A base accepts a proton and becomes a conjugate acid.
- KH acts as a base, forming hydrogen gas (H鈧) as its conjugate acid.
- Ethanol donates a proton, becoming potassium ethoxide (C鈧侶鈧匫鈦), its conjugate base.
Potassium Hydride Reactions
Potassium hydride (KH) is a potent chemical compound widely known for its strong basic properties. In reactions, it serves as a source of hydride ions (H鈦), which can induce various transformations:
- When KH reacts with ammonia (NH鈧), it forms potassium amide (KNH鈧) and releases hydrogen gas (H鈧), a very common product in such reactions. The hydride ion from KH bonds with NH鈧, showcasing its base functionality.
- In its reaction with ethanol (C鈧侶鈧匫H), KH once again demonstrates its basicity. Ethanol loses a proton (H鈦) to form potassium ethoxide (C鈧侶鈧匫K) while hydrogen gas (H鈧) is liberated.
Chemical Equations
Chemical equations are symbolic representations that describe chemical reactions. They contain reactants, products, and often the states of the substances involved (such as solid, liquid, or gas).A balanced chemical equation has equal numbers of each type of atom on both sides of the equation. This is important because it reflects the law of conservation of mass:
- The reaction of KH with NH鈧: \[ \text{KH} + \text{NH}_3 \rightarrow \text{KNH}_2 + \text{H}_2 \]
- The reaction of KH with ethanol: \[ \text{KH} + \text{C}_2\text{H}_5\text{OH} \rightarrow \text{C}_2\text{H}_5\text{OK} + \text{H}_2 \]