Chapter 5: Problem 162
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Chapter 5: Problem 162
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The products of oxidation of 2 -pentanone with concentrated nitric acid are (a) propanoic acid and ethanoic acid (b) butanoic acid and methanoic acid (c) propanoic acid and methanoic acid (d) 2 -methyl propanoic acid and methanoic acid
2 -phenyl ethanol on oxidation with alkaline \(\mathrm{KMnO}_{4}\) gives (a) benzaldehyde (b) 2 -phenyl ethanoic acid (c) benzoic acid (d) 2 -phenyl ethanol
The IUPAC name of product (B) is (a) Heptane-2, 6 -dione (b) 6 -oxoheptanoic acid (c) 5 -oxohexanal (d) 6 -oxoheptanal
Identify the correct statements among the following. (a) Formaldehyde can react with both \(-\mathrm{NH}_{2}\) groups in semicarbazide. (b) In mixed Cannizzaro reaction involving HCHO, it is always the intermediate formed from HCHO which transfers its hydride to the other aldehyde. (c) Benzaldehyde reduces both Tollens' reagent and Fehling's solution. (d) In Fehling's solution, Cu(II) ions are kept in soluble form of a complex in alkaline medium.
Bromobenzene can be converted to benzoic acid by (a) treating with \(\mathrm{Mg}\) and then carboxylating. (b) treating with \(\mathrm{NaOH}\) and then carboxylating. (c) treating with KCN and then hydrolysing. (d) oxidation with \(\mathrm{KMnO}_{4}\).
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