Chapter 16: Problem 17
Explain what a catalyst is and how it works.
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These are the key concepts you need to understand to accurately answer the question.
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Chapter 16: Problem 17
Explain what a catalyst is and how it works.
These are the key concepts you need to understand to accurately answer the question.
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Explain why, unlike gas-phase reactions, a reaction in solution is hardly affected at all by pressure.
Would you expect the concentration of a catalyst to appear in the rate law of a catalyzed reaction? Explain.
What is the reaction order if the reaction rate triples when the concentration of a reactant is increased by a factor of 3\(?\)
The graphing calculator can run a program that can tell you the order of a chemical reaction, provided you indicate the reactant concentrations and reaction rates for two experiments involving the same reaction. Go to Appendix C. If you are using a TI-83 Plus, you can download the program RXNORDER and run the application as directed. If you are using another calculator, your teacher will provide you with key-strokes and data sets to use. At the prompts, enter the reactant concentrations and reaction rates. Run the program as needed to find the order of the following reactions. (All rates are given in M/s.) a. \(2 \mathrm{N}_{2} \mathrm{O}_{5}(g) \rightarrow 4 \mathrm{NO}_{2}(g)+\mathrm{O}_{2}(g)\) \(\mathrm{N}_{2} \mathrm{O}_{5} :\) conc. \(1=0.025 \mathrm{M} ;\) conc. \(2=0.040 \mathrm{M}\) rate \(1=8.1 \times 10^{-5} ;\) rate \(2=1.3 \times 10^{-4}\) b. \(2 \mathrm{NO}_{2}(g) \rightarrow 2 \mathrm{NO}(g)+\mathrm{O}_{2}(g)\) \(\mathrm{NO}_{2} : \mathrm{conc.} 1=0.040 \mathrm{M} ; \mathrm{conc} .2=0.080 \mathrm{M}\) rate \(1=0.0030 ;\) rate \(2=0.012\) c. \(2 \mathrm{H}_{2} \mathrm{O}_{2}(g) \rightarrow 2 \mathrm{H}_{2} \mathrm{O}(g)+\mathrm{O}_{2}(g)\) \(\mathrm{H}_{2} \mathrm{O}_{2} :\) conc. \(1=0.522 \mathrm{M} ;\) conc. \(2=0.887 \mathrm{M}\) rate \(1=1.90 \times 10^{-4} ;\) rate \(2=3.23 \times 10^{-4}\) d. \(2 \mathrm{NOBr}(g) \rightarrow 2 \mathrm{NO}(g)+\mathrm{Br}_{2}(g)\) NOBr: conc. \(1=1.27 \times 10^{-4} \mathrm{M} ;\) conc. \(2=\) \(4.04 \times 10^{-4} \mathrm{M}\) rate \(1=6.26 \times 10^{-5} ;\) rate \(2=6.33 \times 10^{-4}\) e. \(2 \mathrm{HI}(g) \rightarrow \mathrm{H}_{2}(g)+\mathrm{I}_{2}(g)\) HI: conc. \(1=4.18 \times 10^{-4} \mathrm{M} ;\) conc. \(2=\) \(8.36 \times 10^{-4} \mathrm{M}\) rate \(1=3.86 \times 10^{-5} ;\) rate \(2=1.54 \times 10^{-4}\)
What unit is most commonly used to express reaction rate?
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