Chapter 9: Problem 45
Define bond length, resonance, and resonance structure.
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Chapter 9: Problem 45
Define bond length, resonance, and resonance structure.
These are the key concepts you need to understand to accurately answer the question.
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In 1999 an unusual cation containing only nitrogen \(\left(\mathrm{N}_{5}^{+}\right)\) was prepared. Draw three resonance structures of the ion, showing formal charges. (Hint: The \(\mathrm{N}\) atoms are joined in a linear fashion.)
Draw Lewis structures of these organic molecules: (a) methanol \(\left(\mathrm{CH}_{3} \mathrm{OH}\right) ;\) (b) ethanol \(\left(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}\right)\); (c) tetraethyllead \(\left[\mathrm{Pb}\left(\mathrm{CH}_{2} \mathrm{CH}_{3}\right)_{4}\right]\), which was used in "leaded" gasoline; (d) methylamine \(\left(\mathrm{CH}_{3} \mathrm{NH}_{2}\right)\) (e) mustard gas \(\left(\mathrm{ClCH}_{2} \mathrm{CH}_{2} \mathrm{SCH}_{2} \mathrm{CH}_{2} \mathrm{Cl}\right)\), a poison- ous gas used in World War I; (f) urea \(\left[\left(\mathrm{NH}_{2}\right)_{2} \mathrm{CO}\right]\), a fertilizer; (g) glycine \(\left(\mathrm{NH}_{2} \mathrm{CH}_{2} \mathrm{COOH}\right)\), an amino acid.
List these bonds in order of increasing ionic character: the lithium-to- fluorine bond in \(\mathrm{LiF},\) the potassium-to-oxygen bond in \(\mathrm{K}_{2} \mathrm{O},\) the nitrogen-tonitrogen bond in \(\mathrm{N}_{2}\), the sulfur-to-oxygen bond in \(\mathrm{SO}_{2}\), the chlorine-to-fluorine bond in \(\mathrm{ClF}_{3}\).
In the vapor phase, beryllium chloride consists of discrete molecular units \(\mathrm{BeCl}_{2}\). Is the octet rule satisfied for Be in this compound? If not, can you form an octet around Be by drawing another resonance structure? How plausible is this structure?
Explain what an ionic bond is.
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