Chapter 9: Problem 27
What is Lewis's contribution to our understanding of the covalent bond?
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Chapter 9: Problem 27
What is Lewis's contribution to our understanding of the covalent bond?
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Draw Lewis structures of these organic molecules: (a) tetrafluoroethylene \(\left(\mathrm{C}_{2} \mathrm{~F}_{4}\right)\) (b) propane \(\left(\mathrm{C}_{3} \mathrm{H}_{8}\right)\) (c) butadiene \(\left(\mathrm{CH}_{2} \mathrm{CHCHCH}_{2}\right.\) ), (d) propyne \(\left(\mathrm{CH}_{3} \mathrm{CCH}\right),\) (e) benzoic acid \(\left(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{COOH}\right) .\) (Hint: To draw \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{COOH}\), replace an \(\mathrm{H}\) atom in benzene with a COOH group.)
Use Lewis dot symbols to show the transfer of electrons between the following atoms to form cations and anions: (a) \(\mathrm{Na}\) and \(\mathrm{F},\) (b) \(\mathrm{K}\) and \(\mathrm{S},\) (c) \(\mathrm{Ba}\) and \(\mathrm{O}\), (d) \(\mathrm{Al}\) and \(\mathrm{N}\).
Write three reasonable resonance structures of the azide ion \(\mathrm{N}_{3}^{-}\) in which the atoms are arranged as NNN. Show formal charges.
Draw three resonance structures for the chlorate ion, \(\mathrm{ClO}_{3}^{-}\). Show formal charges.
Define bond enthalpy. Bond enthalpies of polyatomic molecules are average values. Why?
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