Chapter 8: Problem 3
Describe the general layout of a modern periodic table.
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Chapter 8: Problem 3
Describe the general layout of a modern periodic table.
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Write ground-state electron configurations for these transition metal ions: (a) \(\mathrm{Sc}^{3+}\) (b) \(\mathrm{Ti}^{4+}\) (c) \(\mathrm{V}^{5+}\) (d) \(\mathrm{Cr}^{3+}\) , (e) \(\mathrm{Mn}^{2+},\) (f) \(\mathrm{Fe}^{2+}\) (h) \(\mathrm{Co}^{2+}\) (g) \(\mathrm{Fe}^{3+}\) (i) \(\mathrm{Ni}^{2+}\) (i) \(\mathrm{Cu}^{+}\) (k) \(\mathrm{Cu}^{2+}\) (1) \(\mathrm{Ag}^{+}\) \((\mathrm{m}) \mathrm{Au}^{+}\) (n) \(\mathrm{Au}^{3+},\) (o) \(\mathrm{Pt}^{2+}\)
Explain why the first electron affinity of sulfur is \(200 \mathrm{~kJ} / \mathrm{mol}\) but the second electron affinity is \(-649 \mathrm{~kJ} / \mathrm{mol}\),
The ionization energies of sodium (in \(\mathrm{kJ} / \mathrm{mol}\) ), starting with the first and ending with the eleventh, are 495.9,4560,6900,9540,13,400,16,600,20,120 \(25,490,28,930,141,360,170,000 .\) Plot the log of ionization energy \((y\) axis \()\) versus the number of ionization \((x\) axis \() ;\) for example, \(\log 495.9\) is plotted versus 1 (labeled \(I_{1}\), the first ionization energy), log 4560 is plotted versus 2 (labeled \(I_{2}\), the second ionization energy), and so on. (a) Label \(I_{1}\) through \(I_{11}\) with the electrons in orbitals such as \(1 s, 2 s, 2 p,\) and \(3 s .\) (b) What can you deduce about electron shells from the breaks in the curve?
What factors account for the unique nature of hydrogen?
In each of the following pairs, indicate which one of the two species is smaller: (a) \(\mathrm{Cl}\) or \(\mathrm{Cl}^{-},\) (b) Na or \(\mathrm{Na}^{+}\), (c) \(\mathrm{O}^{2-}\) or \(\mathrm{S}^{2-},\) (d) \(\mathrm{Mg}^{2+}\) or \(\mathrm{Al}^{3+},\) (e) \(\mathrm{Au}^{+}\) or \(\mathrm{Au}^{3+}\).
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