Chapter 6: Problem 9
Describe two exothermic processes and two endothermic processes.
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Chapter 6: Problem 9
Describe two exothermic processes and two endothermic processes.
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Define these terms: enthalpy, enthalpy of reaction. Under what condition is the heat of a reaction equal to the enthalpy change of the same reaction?
Determine the standard enthalpy of formation of ethanol \(\left(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}\right)\) from its standard enthalpy of combustion \((-1367.4 \mathrm{~kJ} / \mathrm{mol})\)
The first step in the industrial recovery of zinc from the zinc sulfide ore is roasting, that is, the conversion of \(\mathrm{ZnS}\) to \(\mathrm{ZnO}\) by heating: $$ \begin{aligned} 2 \mathrm{ZnS}(s)+3 \mathrm{O}_{2}(g) \longrightarrow & 2 \mathrm{ZnO}(s)+2 \mathrm{SO}_{2}(g) \\ & \Delta H_{\mathrm{rxn}}^{\circ}=-879 \mathrm{~kJ} / \mathrm{mol} \end{aligned} $$ Calculate the heat evolved (in kJ) per gram of \(\mathrm{ZnS}\) roasted.
From these data, $$ \begin{aligned} \mathrm{S}(\text { rhombic })+\mathrm{O}_{2}(g) \longrightarrow \mathrm{SO}_{2}(g) \\ \Delta H_{\mathrm{rxn}}^{\circ} &=-296.06 \mathrm{~kJ} / \mathrm{mol} \\ \mathrm{S}(\text { monoclinic })+\mathrm{O}_{2}(g) & \longrightarrow \mathrm{SO}_{2}(g) \\ \Delta H_{\mathrm{rxn}}^{\circ} &=-296.36 \mathrm{~kJ} / \mathrm{mol} \end{aligned} $$ calculate the enthalpy change for the transformation $$ S \text { (rhombic) } \longrightarrow \mathrm{S} \text { (monoclinic) } $$ (Monoclinic and rhombic are different allotropic forms of elemental sulfur.)
Methanol \(\left(\mathrm{CH}_{3} \mathrm{OH}\right)\) is an organic solvent and is also used as a fuel in some automobile engines. From the following data, calculate the standard enthalpy of formation of methanol: $$ \begin{aligned} 2 \mathrm{CH}_{3} \mathrm{OH}(l)+3 \mathrm{O}_{2}(g) \longrightarrow 2 \mathrm{CO}_{2}(g)+4 \mathrm{H}_{2} \mathrm{O}(l) \\ \Delta H_{\mathrm{rxn}}^{\circ}=-1452.8 \mathrm{~kJ} / \mathrm{mol} \end{aligned} $$
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