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How many grams of \(\mathrm{NaCl}\) are required to precipitate most of the \(\mathrm{Ag}^{+}\) ions from \(2.50 \times 10^{2} \mathrm{~mL}\) of \(0.0113 \mathrm{MAgNO}_{3}\) solution? Write the net ionic equation for the reaction.

Short Answer

Expert verified
To precipitate most of the Ag+ ions from the solution, we would require approximately 0.165 grams of NaCl. The net ionic equation for the reaction is Ag+(aq) + Cl- (aq) -> AgCl(s).

Step by step solution

01

Calculate the number of moles of AgNO3

Firstly, we need to determine the number of moles of AgNO3 in the solution. We can do this using the formula for molarity which is M = moles/volume. Since Molarity (M) is given as 0.0113 M, and the volume is 2.50 x 10^2 mL (which is equal to 0.25 L when converted), we can rearrange the formula to find moles = Molarity x Volume = 0.0113 x 0.25 = 0.002825 moles.
02

Find the amount of NaCl

From the stoichiometry of the reaction, we know that 1 mole of AgNO3 reacts with 1 mole of NaCl. Hence, the number of moles of NaCl required will be the same as the number of moles of AgNO3.So, moles of NaCl needed = 0.002825 moles. To convert this into grams, use the molar mass of NaCl (58.44 g/mol). Therefore, grams of NaCl = moles x molar mass = 0.002825 moles x 58.44 g/mol = 0.165 grams.
03

Write the net ionic equation

The net ionic equation for the reaction between AgNO3 and NaCl is Ag+(aq) + Cl- (aq) -> AgCl(s). The net ionic equation represents the actual reaction taking place and disregards the spectator ions. In this case, Sodium (Na) and Nitrate (NO3) are the spectator ions.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Mole Concept
The mole concept is a fundamental pillar of chemistry that represents a specific number of particles, typically atoms, ions, or molecules. It's defined as the amount of substance that contains as many particles as there are atoms in 12 grams of carbon-12.The number is called Avogadro's number, and it approximately equals to \( 6.022 \times 10^{23} \) entities per mole. Understanding the mole concept allows chemists to count particles by weighing them. This becomes especially handy in reactions where counting individual particles is infeasible due to their microscopic size.To apply the mole concept to a real-world example, let's examine the exercise given. The first step involves calculating the number of moles of \( \text{AgNO}_3 \) using the solution's molarity and volume. By applying the formula \( \text{moles} = \text{Molarity} \times \text{Volume} \), one can easily transition from the macroscopic world of liters and molarity to the microscopic world of moles and individual \( \text{Ag}^{+} \) ions.
Molar Mass Calculation
Molar mass is the mass in grams of one mole of a substance. It's a bridge between the atomic scale and the real-world scale. For any substance, the molar mass is numerically equal to its atomic or molecular mass in atomic mass units (amu) but is expressed in units of grams per mole (g/mol).Calculating molar mass is crucial for converting between grams and moles, as seen in the textbook solution. After determining the number of moles of \( \text{NaCl} \), they're converted into grams using \( \text{NaCl} \'s \) molar mass of \( 58.44 \text{ g/mol} \). The calculation is straightforward: multiply the number of moles by the molar mass. In the exercise, \( 0.002825 \text{ moles} \times 58.44 \text{ g/mol} \) results in approximately 0.165 grams of \( \text{NaCl} \) required for the reaction.
Net Ionic Equations
Net ionic equations are a simplified way to show only the chemical species that actually change during the reaction. They omit the spectator ions, which do not participate in the actual chemical change but are present to balance the charge. These equations provide a clearer picture of the chemical change occurring in a solution.To write a net ionic equation, one must first write the balanced full ionic equation and then remove the ions that appear unchanged on both sides of the equation. The resulting net ionic equation for the textbook exercise would include the silver ion \( \text{Ag}^{+} (aq) \) and the chloride ion \( \text{Cl}^{-} (aq) \) combining to form solid silver chloride \( \text{AgCl} (s) \), succinctly represented as \( \text{Ag}^{+}(aq) + \text{Cl}^{-}(aq) \rightarrow \text{AgCl}(s) \). This equation highlights the essential chemical change, aiding students' understanding of the reaction's dynamics.

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Most popular questions from this chapter

This "cycle of copper" experiment is performed in some general chemistry laboratories. The series of reactions starts with copper and ends with metallic copper. The steps are: (1) A piece of copper wire of known mass is allowed to react with concentrated nitric acid [the products are copper(II) nitrate, nitrogen dioxide, and water]. (2) The copper(II) nitrate is treated with a sodium hydroxide solution to form copper(II) hydroxide precipitate. (3) On heating, copper(II) hydroxide decomposes to yield copper(II) oxide. (4) The copper(II) oxide is reacted with concentrated sulfuric acid to yield copper(II) sulfate. (5) Copper(II) sulfate is treated with an excess of zinc metal to form metallic copper. (6) The remaining zinc metal is removed by treatment with hydrochloric acid, and metallic copper is filtered, dried, and weighed. (a) Write a balanced equation for each step and classify the reactions. (b) Assuming that a student started with \(65.6 \mathrm{~g}\) of copper, calculate the theoretical yield at each step. (c) Considering the nature of the steps, comment on why it is possible to recover most of the copper used at the start.

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