Chapter 2: Problem 35
What does a chemical formula represent? What is the ratio of the atoms in the following molecular formulas? (a) NO, (b) \(\mathrm{NCl}_{3}\) (c) \(\mathrm{N}_{2} \mathrm{O}_{4},\) (d) \(\mathrm{P}_{4} \mathrm{O}_{6}\)
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Chapter 2: Problem 35
What does a chemical formula represent? What is the ratio of the atoms in the following molecular formulas? (a) NO, (b) \(\mathrm{NCl}_{3}\) (c) \(\mathrm{N}_{2} \mathrm{O}_{4},\) (d) \(\mathrm{P}_{4} \mathrm{O}_{6}\)
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Fluorine reacts with hydrogen \((\mathrm{H})\) and with deuterium (D) to form hydrogen fluoride (HF) and deuterium fluoride (DF) [deuterium \(\left({ }_{1}^{2} \mathrm{H}\right.\) ) is an isotope of hydrogen]. Would a given amount of fluorine react with different masses of the two hydrogen isotopes? Does this violate the law of definite proportions? Explain.
(a) Describe Rutherford's experiment and how it led to the structure of the atom. How was he able to estimate the number of protons in a nucleus from the scattering of the \(\alpha\) particles? (b) Consider the \({ }^{23} \mathrm{Na}\) atom. Given that the radius and mass of the nucleus are \(3.04 \times 10^{-15} \mathrm{~m}\) and \(3.82 \times 10^{-23} \mathrm{~g},\) respectively, calculate the density of the nucleus in \(\mathrm{g} / \mathrm{cm}^{3}\). The radius of a \({ }^{23}\) Na atom is \(186 \mathrm{pm}\). Calculate the density of the space occupied by the electrons in the sodium atom. Do your results support Rutherford's model of an atom? [The volume of a sphere is \((4 / 3) \pi r^{3},\) where \(r\) is the radius. \(]\)
Which of these are elements, which are molecules but not compounds, which are compounds but not molecules, and which are both compounds and molecules? (a) \(\mathrm{SO}_{2},\) (b) \(\mathrm{S}_{8},\) (c) \(\mathrm{Cs},\) (d) \(\mathrm{N}_{2} \mathrm{O}_{5},\) (e) O, (f) \(\mathrm{O}_{2},(\mathrm{~g}) \mathrm{O}_{3},(\mathrm{~h}) \mathrm{CH}_{4},\) (i) \(\mathrm{KBr},(\mathrm{j}) \mathrm{S},(\mathrm{k}) \mathrm{P}_{4},(\mathrm{l}) \mathrm{LiF}\)
Explain why the chemical formulas of ionic compounds are usually the same as their empirical formulas.
Identify the following as elements or compounds: \(\mathrm{NH}_{3}, \mathrm{~N}_{2}, \mathrm{~S}_{8}, \mathrm{NO}, \mathrm{CO}, \mathrm{CO}_{2}, \mathrm{H}_{2}, \mathrm{SO}_{2}\)
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