Chapter 19: Problem 109
In recent years there has been much interest in electric cars. List some advantages and disadvantages of electric cars compared to automobiles with internal combustion engines.
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Chapter 19: Problem 109
In recent years there has been much interest in electric cars. List some advantages and disadvantages of electric cars compared to automobiles with internal combustion engines.
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A \(9.00 \times 10^{2}-\mathrm{mL} 0.200 \mathrm{M} \mathrm{MgI}_{2}\) was electrolyzed. As a result, hydrogen gas was generated at the cathode and iodine was formed at the anode. The volume of hydrogen collected at \(26^{\circ} \mathrm{C}\) and \(779 \mathrm{mmHg}\) was \(1.22 \times 10^{3} \mathrm{~mL}\). (a) Calculate the charge in coulombs consumed in the process. (b) How long (in min) did the electrolysis last if a current of 7.55 A was used? (c) A white precipitate was formed in the process. What was it and what was its mass in grams? Assume the volume of the solution was constant.
Consider the following half-reactions: \(\mathrm{MnO}_{4}^{-}(a q)+8 \mathrm{H}^{+}(a q)+5 e^{-} \longrightarrow$$\mathrm{Mn}^{2+}(a q)+4 \mathrm{H}_{2} \mathrm{O}(l)\) \(\mathrm{NO}_{3}^{-}(a q)+4 \mathrm{H}^{+}(a q)+3 e^{-} \longrightarrow \mathrm{NO}(g)+2 \mathrm{H}_{2} \mathrm{O}(l)\) Predict whether \(\mathrm{NO}_{3}^{-}\) ions will oxidize \(\mathrm{Mn}^{2+}\) to \(\mathrm{MnO}_{4}^{-}\) under standard-state conditions.
Write the equations relating \(\Delta G^{\circ}\) and \(K\) to the standard emf of a cell. Define all the terms.
The cathode reaction in the Leclanché cell is given by $$ 2 \mathrm{MnO}_{2}(s)+\mathrm{Zn}^{2+}(a q)+2 e^{-} \longrightarrow \mathrm{ZnMn}_{2} \mathrm{O}_{4}(s) $$ If a Leclanché cell produces a current of \(0.0050 \mathrm{~A}\) calculate how many hours this current supply will last if there are initially \(4.0 \mathrm{~g}\) of \(\mathrm{MnO}_{2}\) present in the cell. Assume that there is an excess of \(\mathrm{Zn}^{2+}\) ions.
Explain why chlorine gas can be prepared by electrolyzing an aqueous solution of \(\mathrm{NaCl}\) but fluorine gas cannot be prepared by electrolyzing an aqueous solution of NaF.
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