Chapter 17: Problem 61
Both \(\mathrm{KCl}\) and \(\mathrm{NH}_{4} \mathrm{Cl}\) are white solids. Suggest one reagent that would enable you to distinguish between these two compounds.
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Chapter 17: Problem 61
Both \(\mathrm{KCl}\) and \(\mathrm{NH}_{4} \mathrm{Cl}\) are white solids. Suggest one reagent that would enable you to distinguish between these two compounds.
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A volume of \(75 \mathrm{~mL}\) of \(0.060 \mathrm{M} \mathrm{NaF}\) is mixed with \(25 \mathrm{~mL}\) of \(0.15 \mathrm{M} \mathrm{Sr}\left(\mathrm{NO}_{3}\right)_{2} .\) Calculate the concentra- tions in the final solution of \(\mathrm{NO}_{3}^{-}, \mathrm{Na}^{+}, \mathrm{Sr}^{2+},\) and \(\mathrm{F}^{-} \cdot\left(K_{\mathrm{sp}}\right.\) for \(\left.\mathrm{SrF}_{2}=2.0 \times 10^{-10} \mathrm{.}\right)\)
A 1.0 -L saturated silver carbonate solution at \(5^{\circ} \mathrm{C}\) is treated with enough hydrochloric acid to decompose the compound. The carbon dioxide generated is collected in a \(19-\mathrm{mL}\) vial and exerts a pressure of \(114 \mathrm{mmHg}\) at \(25^{\circ} \mathrm{C}\). What is the \(K_{\mathrm{sp}}\) of \(\mathrm{Ag}_{2} \mathrm{CO}_{3}\) at \(5^{\circ} \mathrm{C} ?\)
The molar mass of a certain metal carbonate, \(\mathrm{MCO}_{3}\), can be determined by adding an excess of \(\mathrm{HCl}\) acid to react with the carbonate and then "back-titrating" the remaining acid with \(\mathrm{NaOH}\). (a) Write an equation for these reactions. (b) In a certain experiment, \(20.00 \mathrm{~mL}\) of \(0.0800 \mathrm{M} \mathrm{HCl}\) were added to a \(0.1022-\mathrm{g}\) sample of \(\mathrm{MCO}_{3}\). The excess HCl required \(5.64 \mathrm{~mL}\) of \(0.1000 \mathrm{M} \mathrm{NaOH}\) for neutralization. Calculate the molar mass of the carbonate and identify \(\mathrm{M}\).
Calculate the \(\mathrm{pH}\) at the equivalence point for these titrations: (a) \(0.10 M \mathrm{HCl}\) versus \(0.10 \mathrm{M} \mathrm{NH}_{3}\), (b) \(0.10 \mathrm{M} \mathrm{CH}_{3} \mathrm{COOH}\) versus \(0.10 \mathrm{M} \mathrm{NaOH}\).
The maximum allowable concentration of \(\mathrm{Pb}^{2+}\) ions in drinking water is \(0.05 \mathrm{ppm}\) (that is, \(0.05 \mathrm{~g}\) of \(\mathrm{Pb}^{2+}\) in 1 million g of water). Is this guideline exceeded if an underground water supply is at equilibrium with the mineral anglesite, \(\mathrm{PbSO}_{4}\left(K_{\mathrm{sp}}=1.6 \times 10^{-8}\right) ?\)
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