Chapter 17: Problem 23
The amount of indicator used in an acid-base titration must be small. Why?
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Chapter 17: Problem 23
The amount of indicator used in an acid-base titration must be small. Why?
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Calculate the \(\mathrm{pH}\) of the \(0.20 \mathrm{M} \mathrm{NH}_{3} / 0.20 \mathrm{M} \mathrm{NH}_{4} \mathrm{Cl}\) buffer. What is the \(\mathrm{pH}\) of the buffer after the addition of \(10.0 \mathrm{~mL}\) of \(0.10 \mathrm{M} \mathrm{HCl}\) to \(65.0 \mathrm{~mL}\) of the buffer?
Calculate the concentration of ions in these saturated solutions: (a) \(\left[\mathrm{I}^{-}\right]\) in AgI solution with \(\left[\mathrm{Ag}^{+}\right]=9.1 \times 10^{-9} \mathrm{M}\) (b) \(\left[\mathrm{Al}^{3+}\right]\) in \(\mathrm{Al}(\mathrm{OH})_{3}\) with \(\left[\mathrm{OH}^{-}\right]=2.9 \times 10^{-9} \mathrm{M}\)
How can we predict whether a precipitate will form when two solutions are mixed?
The molar solubility of \(\mathrm{AgCl}\) in \(6.5 \times 10^{-3} \mathrm{M}\) \(\mathrm{AgNO}_{3}\) is \(2.5 \times 10^{-8} M .\) In deriving \(K_{\mathrm{sp}}\) from these data, which of these assumptions are reasonable? (a) \(K_{\mathrm{sp}}\) is the same as solubility. (b) \(K_{\mathrm{sp}}\) of \(\mathrm{AgCl}\) is the same in \(6.5 \times 10^{-3} \mathrm{M} \mathrm{AgNO}_{3}\) as in pure water. (c) Solubility of \(\mathrm{AgCl}\) is independent of the concentration of \(\mathrm{AgNO}_{3}\) (d) \(\left[\mathrm{Ag}^{+}\right]\) in solution does not change significantly on the addition of \(\mathrm{AgCl}\) to \(6.5 \times 10^{-3} \mathrm{M} \mathrm{AgNO}_{3}\). (e) \(\left[\mathrm{Ag}^{+}\right]\) in solution after the addition of \(\mathrm{AgCl}\) to \(6.5 \times 10^{-3} \mathrm{MAgNO}_{3}\) is the same as it would be in pure water.
Solid NaI is slowly added to a solution that is \(0.010 M\) in \(\mathrm{Cu}^{+}\) and \(0.010 \mathrm{M}\) in \(\mathrm{Ag}^{+}\). (a) Which compound will begin to precipitate first? (b) Calculate \(\left[\mathrm{Ag}^{+}\right]\) when CuI just begins to precipitate. (c) What percentage of \(\mathrm{Ag}^{+}\) remains in solution at this point?
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