Chapter 16: Problem 65
Define salt hydrolysis. Categorize salts according to how they affect the \(\mathrm{pH}\) of a solution.
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Chapter 16: Problem 65
Define salt hydrolysis. Categorize salts according to how they affect the \(\mathrm{pH}\) of a solution.
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Which would be considered a stronger Lewis acid: (a) \(\mathrm{BF}_{3}\) or \(\mathrm{BCl}_{3},\) (b) \(\mathrm{Fe}^{2+}\) or \(\mathrm{Fe}^{3+}\) ? Explain.
You are given two beakers containing separately an aqueous solution of strong acid (HA) and an aqueous solution of weak acid (HB) of the same concentration. Describe how you would compare the strengths of these two acids by (a) measuring the \(\mathrm{pH},\) (b) measuring electrical conductance, (c) studying the rate of hydrogen gas evolution when these solutions are reacted with an active metal such as \(\mathrm{Mg}\) or \(\mathrm{Zn}\).
Calculate the \(\mathrm{pH}\) of each of these solutions: (a) \(0.0010 \mathrm{MHCl},\) (b) \(0.76 \mathrm{M} \mathrm{KOH}\) (c) \(2.8 \times 10^{-4} M\) \(\mathrm{Ba}(\mathrm{OH})_{2},(\mathrm{~d}) 5.2 \times 10^{-4} \mathrm{M} \mathrm{HNO}_{3}\).
Oxalic acid \(\left(\mathrm{H}_{2} \mathrm{C}_{2} \mathrm{O}_{4}\right)\) has the following structure: An oxalic acid solution contains these species in varying concentrations: \(\mathrm{H}_{2} \mathrm{C}_{2} \mathrm{O}_{4}, \mathrm{HC}_{2} \mathrm{O}_{4}^{-}, \mathrm{C}_{2} \mathrm{O}_{4}^{2-}\), and \(\mathrm{H}^{+}\). (a) Draw Lewis structures of \(\mathrm{HC}_{2} \mathrm{O}_{4}^{-}\) and \(\mathrm{C}_{2} \mathrm{O}_{4}^{2-}\). (b) Which of the four species listed here can act only as acids, which can act only as bases, and which can act as both acids and bases?
When chlorine reacts with water, the resulting solution is weakly acidic and reacts with \(\mathrm{AgNO}_{3}\) to give a white precipitate. Write balanced equations to represent these reactions. Explain why manufacturers of household bleaches add bases such as \(\mathrm{NaOH}\) to their products to increase their effectiveness.
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