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When chlorine reacts with water, the resulting solution is weakly acidic and reacts with \(\mathrm{AgNO}_{3}\) to give a white precipitate. Write balanced equations to represent these reactions. Explain why manufacturers of household bleaches add bases such as \(\mathrm{NaOH}\) to their products to increase their effectiveness.

Short Answer

Expert verified
Chemical equations: \( \mathrm{Cl}_{2} + \mathrm{H}_{2}\mathrm{O} \to \mathrm{HOCl} + \mathrm{HCl} \), \( \mathrm{HOCl} + \mathrm{AgNO}_{3} \to \mathrm{AgCl} + \mathrm{HNO}_{3} \), and \( \mathrm{HOCl} + \mathrm{NaOH} \to \mathrm{NaOCl} + \mathrm{H}_{2}\mathrm{O} \). Bases like NaOH increase bleach effectiveness by converting weak acid into a more efficient bleaching agent.

Step by step solution

01

Writing the balanced chemical equations

First, understand that when chlorine reacts with water, hypochlorous acid and hydrochloric acid are formed. The balanced equation for this reaction is: \( \mathrm{Cl}_{2} + \mathrm{H}_{2}\mathrm{O} \to \mathrm{HOCl} + \mathrm{HCl} \). The hypochlorous acid then reacts with silver nitrate to give silver chloride (the white precipitate) and nitric acid. The balanced equation for this reaction is: \( \mathrm{HOCl} + \mathrm{AgNO}_{3} \to \mathrm{AgCl} + \mathrm{HNO}_{3} \).
02

Understanding the role of bases in enhancing bleach effectiveness

Now, the second part of the question requires understanding of a different chemical process. Bases such as sodium hydroxide (NaOH) are added to manufacturers' bleach products because they convert hypochlorous acid (weak acid) into hypochlorite ions, which is a much more effective bleaching agent due to its better stability and increased oxidizing power. This process can be represented by the balanced equation: \( \mathrm{HOCl} + \mathrm{NaOH} \to \mathrm{NaOCl} + \mathrm{H}_{2}\mathrm{O} \).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Chlorine and Water Reaction
Chlorine is a common chemical element that plays a crucial role in various chemical reactions, particularly when it interacts with water. When chlorine gas (\( \mathrm{Cl}_{2} \)) is introduced to water (\( \mathrm{H}_{2}\mathrm{O} \)), a chemical reaction occurs that results in the formation of two products: hypochlorous acid (\( \mathrm{HOCl} \)) and hydrochloric acid (\( \mathrm{HCl} \)). This reaction can be written as \( \mathrm{Cl}_{2} + \mathrm{H}_{2}\mathrm{O} \rightarrow \mathrm{HOCl} + \mathrm{HCl} \).
The reaction is significant because hypochlorous acid is a key component in bleaching and disinfection processes. Additionally, the presence of hydrochloric acid makes the resulting solution slightly acidic. This acidity plays a role in further reactions, such as those with silver nitrate, which we'll explore next.
Hypochlorous Acid
Hypochlorous acid (\( \mathrm{HOCl} \)) is a weak acid formed when chlorine reacts with water. It has important disinfectant and bleaching properties, making it valuable in various applications, including pool sanitation and household cleaners.
When hypochlorous acid is present in a solution, it can react with silver nitrate (\( \mathrm{AgNO}_{3} \)) to produce a white precipitate of silver chloride. This reaction is represented by the equation: \( \mathrm{HOCl} + \mathrm{AgNO}_{3} \rightarrow \mathrm{AgCl} + \mathrm{HNO}_{3} \).
This indicates that hypochlorous acid effectively participates in chemical reactions that produce noticeable changes, such as precipitate formation, which can be visually identified.
Bleach Effectiveness
In the context of household bleaches, effectiveness hinges largely on the chemical composition, particularly the presence of hypochlorite ions. Manufacturers often add bases, such as sodium hydroxide (\( \mathrm{NaOH} \)), to convert hypochlorous acid into hypochlorite ions (\( \mathrm{NaOCl} \)), boosting bleach performance.
The chemical reaction that illustrates this is:\( \mathrm{HOCl} + \mathrm{NaOH} \rightarrow \mathrm{NaOCl} + \mathrm{H}_{2}\mathrm{O} \).
This conversion enhances the bleach because hypochlorite ions are more stable and possess greater oxidizing power than hypochlorous acid. These properties make the bleach more effective at breaking down organic molecules, facilitating superior cleaning and disinfection results.
  • Increased stability prevents rapid degradation.
  • Enhanced oxidizing power improves stain removal.
Balanced Equations
Balanced chemical equations are vital in accurately representing chemical reactions. They ensure that the number of each type of atom is the same on both sides of the reaction, reflecting the law of conservation of mass.
When chlorine reacts with water, the balanced equation is:\( \mathrm{Cl}_{2} + \mathrm{H}_{2}\mathrm{O} \to \mathrm{HOCl} + \mathrm{HCl} \).
Afterward, the reaction of hypochlorous acid with silver nitrate is balanced as:\( \mathrm{HOCl} + \mathrm{AgNO}_{3} \to \mathrm{AgCl} + \mathrm{HNO}_{3} \).
Each of these balanced equations ensures that the molecular quantities are correctly represented, without any atoms lost or gained in the reactions. This accuracy is foundational for predicting the amounts of products formed, the reactant needs, and understanding the reaction dynamics.

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Most popular questions from this chapter

Why do we normally not quote \(K_{\mathrm{a}}\) values for strong acids such as \(\mathrm{HCl}\) and \(\mathrm{HNO}_{3}\) ? Why is it necessary to specify temperature when giving \(K_{\mathrm{a}}\) values?

About half of the hydrochloric acid produced annually in the United States \((3.0\) billion pounds \()\) is used for metal pickling. This process involves the removal of metal oxide layers from metal surfaces to prepare them for coating. (a) Write the overall and net ionic equations for the reaction between iron(III) oxide, which represents the rust layer over iron, and HCl. Identify the Bronsted acid and base. (b) Hydrochloric acid is also used to remove scale (which is mostly \(\mathrm{CaCO}_{3}\) ) from water pipes. Hydrochloric acid reacts with calcium carbonate in two stages; the first stage forms the bicarbonate ion, which then reacts further to form carbon dioxide. Write equations for these two stages and for the overall reaction. (c) Hydrochloric acid is used to recover oil from the ground. It dissolves rocks (often \(\mathrm{CaCO}_{3}\) ) so that the oil can flow more easily. In one process, a 15 percent (by mass) HCl solution is injected into an oil well to dissolve the rocks. If the density of the acid solution is \(1.073 \mathrm{~g} / \mathrm{mL}\), what is the \(\mathrm{pH}\) of the solution?

Fill in the word "acidic," "basic," or "neutral" for these solutions: (a) \(\mathrm{pOH}>7\); solution is _____. (b) \(\mathrm{pOH}=7\); solution is _____. (c) \(\mathrm{pOH}<7\); solution is _____.

Give the conjugate base of each of these acids: (a) \(\mathrm{CH}_{2} \mathrm{ClCOOH},\) (b) \(\mathrm{HIO}_{4}\) (c) \(\mathrm{H}_{3} \mathrm{PO}_{4},\) (d) \(\mathrm{H}_{2} \mathrm{PO}_{4}^{-}\) (e) \(\mathrm{HPO}_{4}^{2-},\) (f) \(\mathrm{H}_{2} \mathrm{SO}_{4},(\mathrm{~g}) \mathrm{HSO}_{4}^{-}\) (h) \(\mathrm{HCOOH}\) (i) \(\mathrm{HSO}_{3}^{-},(\mathrm{j}) \mathrm{NH}_{4}^{+},(\mathrm{k}) \mathrm{H}_{2} \mathrm{~S},\) (l) \(\mathrm{HS}^{-},(\mathrm{m}) \mathrm{HClO}\).

Hydrocyanic acid (HCN) is a weak acid and a deadly poisonous compound that, in the gaseous form (hydrogen cyanide), is used in gas chambers. Why is it dangerous to treat sodium cyanide with acids (such as HCl) without proper ventilation?

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