Chapter 14: Problem 54
The concentrations of enzymes in cells are usually quite small. What is the biological significance of this fact?
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Chapter 14: Problem 54
The concentrations of enzymes in cells are usually quite small. What is the biological significance of this fact?
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Use the Arrhenius equation to show why the rate constant of a reaction (a) decreases with increasing activation energy and (b) increases with increasing temperature.
For the reaction $$ \mathrm{NO}(g)+\mathrm{O}_{3}(g) \longrightarrow \mathrm{NO}_{2}(g)+\mathrm{O}_{2}(g) $$ the frequency factor \(A\) is \(8.7 \times 10^{12} \mathrm{~s}^{-1}\) and the activation energy is \(63 \mathrm{~kJ} / \mathrm{mol}\). What is the rate constant for the reaction at \(75^{\circ} \mathrm{C} ?\)
The reaction of \(\mathrm{G}_{2}\) with \(\mathrm{E}_{2}\) to form \(2 \mathrm{EG}\) is exothermic, and the reaction of \(\mathrm{G}_{2}\) with \(\mathrm{X}_{2}\) to form \(2 \mathrm{XG}\) is endothermic. The activation energy of the exothermic reaction is greater than that of the endothermic reaction. Sketch the potential energy profile diagrams for these two reactions on the same graph.
“The rate constant for the reaction $$ \mathrm{NO}_{2}(g)+\mathrm{CO}(g) \longrightarrow \mathrm{NO}(g)+\mathrm{CO}_{2}(g) $$ is \(1.64 \times 10^{-6} / M \cdot \mathrm{s} .\)." What is incomplete about this statement?
The decomposition of \(\mathrm{N}_{2} \mathrm{O}\) to \(\mathrm{N}_{2}\) and \(\mathrm{O}_{2}\) is a first-order reaction. At \(730^{\circ} \mathrm{C}\) the half-life of the reaction is \(3.58 \times\) \(10^{3} \mathrm{~min}\). If the initial pressure of \(\mathrm{N}_{2} \mathrm{O}\) is \(2.10 \mathrm{~atm}\) at \(730^{\circ} \mathrm{C},\) calculate the total gas pressure after one halflife. Assume that the volume remains constant.
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