Chapter 14: Problem 3
What are the advantages of measuring the initial rate of a reaction?
/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none}
Learning Materials
Features
Discover
Chapter 14: Problem 3
What are the advantages of measuring the initial rate of a reaction?
All the tools & learning materials you need for study success - in one app.
Get started for free
The rate law for the reaction $$ \mathrm{NH}_{4}^{+}(a q)+\mathrm{NO}_{2}^{-}(a q) \longrightarrow \mathrm{N}_{2}(g)+2 \mathrm{H}_{2} \mathrm{O}(l) $$ is given by rate \(=k\left[\mathrm{NH}_{4}^{+}\right]\left[\mathrm{NO}_{2}^{-}\right]\). At \(25^{\circ} \mathrm{C},\) the rate constant is \(3.0 \times 10^{-4} / M \cdot\) s. Calculate the rate of the reaction at this temperature if \(\left[\mathrm{NH}_{4}^{+}\right]=0.26 \mathrm{M}\) and \(\left[\mathrm{NO}_{2}^{-}\right]=0.080 \mathrm{M}\)
Explain what is meant by the rate law of a reaction.
The thermal decomposition of phosphine \(\left(\mathrm{PH}_{3}\right)\) into phosphorus and molecular hydrogen is a first-order reaction: $$ 4 \mathrm{PH}_{3}(g) \longrightarrow \mathrm{P}_{4}(g)+6 \mathrm{H}_{2}(g) $$ The half-life of the reaction is 35.0 s at \(680^{\circ} \mathrm{C}\). Calculate (a) the first-order rates constant for the reaction and (b) the time required for 95 percent of the phosphine to decompose.
The reaction \(\mathrm{H}+\mathrm{H}_{2} \longrightarrow \mathrm{H}_{2}+\mathrm{H}\) has been studied for many years. Sketch a potential-energy-versusreaction-progress diagram for this reaction.
Consider the reaction $$ \mathrm{A} \longrightarrow \mathrm{B} $$ The rate of the reaction is \(1.6 \times 10^{-2} M / \mathrm{s}\) when the concentration of A is \(0.35 M\). Calculate the rate constant if the reaction is (a) first order in \(\mathrm{A},\) (b) second order in A.
What do you think about this solution?
We value your feedback to improve our textbook solutions.