Chapter 13: Problem 83
A cucumber placed in concentrated brine (saltwater) shrivels into a pickle. Explain.
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Chapter 13: Problem 83
A cucumber placed in concentrated brine (saltwater) shrivels into a pickle. Explain.
These are the key concepts you need to understand to accurately answer the question.
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Calculate the molality of each of the following aqueous solutions: (a) \(2.50 \mathrm{M} \mathrm{NaCl}\) solution (density of solution \(=1.08 \mathrm{~g} / \mathrm{mL}\) ), (b) 48.2 percent by mass KBr solution.
For dilute aqueous solutions in which the density of the solution is roughly equal to that of the pure solvent, the molarity of the solution is equal to its molality. Show that this statement is correct for a \(0.010 \mathrm{M}\) urea \(\left.\left[\mathrm{(NH}_{2}\right)_{2} \mathrm{CO}\right]\) solution.
Both \(\mathrm{NaCl}\) and \(\mathrm{CaCl}_{2}\) are used to melt ice on roads in winter. What advantages do these substances have over sucrose or urea in lowering the freezing point of water?
Calculate the amount of water (in grams) that must be added to (a) \(5.00 \mathrm{~g}\) of urea \(\left[\left(\mathrm{NH}_{2}\right)_{2} \mathrm{CO}\right]\) in the preparation of a 16.2 percent by mass solution and (b) \(26.2 \mathrm{~g}\) of \(\mathrm{MgCl}_{2}\) in the preparation of a 1.5 percent by mass solution.
Define ion pairs. What effect does ion-pair formation have on the colligative properties of a solution? How does the ease of ion-pair formation depend on (a) charges on the ions, (b) size of the ions, (c) nature of the solvent (polar versus nonpolar), (d) concentration?
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