Chapter 13: Problem 37
What are colligative properties? What is the meaning of the word "colligative" in this context?
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Chapter 13: Problem 37
What are colligative properties? What is the meaning of the word "colligative" in this context?
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Define boiling-point elevation and freezing-point depression. Write the equations relating boilingpoint elevation and freezing-point depression to the concentration of the solution. Define all the terms, and give their units.
Using Henry's law and the ideal gas equation to prove the statement that the volume of a gas that dissolves in a given amount of solvent is independent of the pressure of the gas. (Hint: Henry's law can be modified as \(n=k P\), where \(n\) is the number of moles of the gas dissolved in the solvent.)
Calculate the molality of each of the following aqueous solutions: (a) \(2.50 \mathrm{M} \mathrm{NaCl}\) solution (density of solution \(=1.08 \mathrm{~g} / \mathrm{mL}\) ), (b) 48.2 percent by mass KBr solution.
Which of these two aqueous solutions has (a) the higher boiling point, (b) the higher freezing point, and (c) the lower vapor pressure: \(0.35 \mathrm{~m} \mathrm{CaCl}_{2}\) or \(0.90 \mathrm{~m}\) urea? State your reasons.
Give two exceptions to Henry's law.
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