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Problem 5

What are the predominant interactions when oppositely charged ions are a. far apart? b. at internuclear distances close to \(r_{0} ?\) c. very close together (at a distance that is less than the sum of the ionic radii)?

Problem 5

Bond energies are typically reported as average values for a range of bonds in a molecule rather than as specific values for a single bond? Why?

Problem 6

If the bonds in the products are weaker than those in the reactants, is a reaction exothermic or endothermic? Explain your answer.

Problem 6

Several factors contribute to the stability of ionic compounds. Describe one type of interaction that destabilizes ionic compounds. Describe the interactions that stabilizeionic compounds.

Problem 6

Calculate the percent ionic character of HF (dipole moment \(=1.826 \mathrm{D}\) ) if the \(\mathrm{H}-\mathrm{F}\) bond distance is \(92 \mathrm{pm}\).

Problem 6

Although formal charges do not represent actual charges on atoms in molecules or ions, they are still useful. Why?

Problem 6

How would the lattice energy of an ionic compound consisting of a monovalent cation and a divalent anion compare with the lattice energy of an ionic compound containing a monovalent cation and a monovalent anion, if the internuclear distance was the same in both compounds? Explain your answer.

Problem 7

Calculate the percent ionic character of CO (dipole moment \(=0.110 \mathrm{D}\) ) if the \(\mathrm{C}\) - \(\mathrm{O}\) distance is \(113 \mathrm{pm} .\)

Problem 7

Why are resonance structures important?

Problem 7

What is the relationship between the electrostatic attractive energy between charged particles and the distance between the particles?

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