Chapter 7: Problem 144
Construct a concept map encompassing the ideas behind the first law of thermodynamics.
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Chapter 7: Problem 144
Construct a concept map encompassing the ideas behind the first law of thermodynamics.
These are the key concepts you need to understand to accurately answer the question.
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In each of the following processes, is any work done when the reaction is carried out at constant pressure in a vessel open to the atmosphere? If so, is work done by the reacting system or on it? (a) Reaction of nitrogen monoxide and oxygen gases to form gaseous nitrogen dioxide; (b) precipitation of magnesium hydroxide by the reaction of aqueous solutions of \(\mathrm{NaOH}\) and \(\mathrm{MgCl}_{2} ;\) (c) reaction of copper(II) sulfate and water vapor to form copper(II) sulfate pentahydrate.
Compressed air in aerosol cans is used to free electronic equipment of dust. Does the air do any work as it escapes from the can?
Determine \(\Delta H^{\circ}\) for this reaction from the data below. \(\mathrm{N}_{2} \mathrm{H}_{4}(1)+2 \mathrm{H}_{2} \mathrm{O}_{2}(1) \longrightarrow \mathrm{N}_{2}(\mathrm{g})+4 \mathrm{H}_{2} \mathrm{O}(1)\) $$\begin{array}{r} \mathrm{N}_{2} \mathrm{H}_{4}(\mathrm{l})+\mathrm{O}_{2}(\mathrm{g}) \longrightarrow \mathrm{N}_{2}(\mathrm{g})+2 \mathrm{H}_{2} \mathrm{O}(\mathrm{l}) \\ \Delta H^{\circ}=-622.2 \mathrm{kJ} \end{array}$$ $$\mathrm{H}_{2}(\mathrm{g})+\frac{1}{2} \mathrm{O}_{2}(\mathrm{g}) \longrightarrow \mathrm{H}_{2} \mathrm{O}(\mathrm{l}) \quad \Delta H^{\circ}=-285.8 \mathrm{kJ}$$ $$\mathrm{H}_{2}(\mathrm{g})+\mathrm{O}_{2}(\mathrm{g}) \longrightarrow \mathrm{H}_{2} \mathrm{O}_{2}(1) \quad \Delta H^{\circ}=-187.8 \mathrm{kJ}$$
Use Hess's law to determine \(\Delta H^{\circ}\) for the reaction $$\mathrm{CO}(\mathrm{g})+\frac{1}{2} \mathrm{O}_{2}(\mathrm{g}) \longrightarrow \mathrm{CO}_{2}(\mathrm{g}), \text { given that }$$ $$\begin{array}{l} \text { C(graphite) }+\frac{1}{2} \mathrm{O}_{2}(\mathrm{g}) \longrightarrow \mathrm{CO}(\mathrm{g}) \\ &\left.\qquad \Delta H^{\circ}=-110.54 \mathrm{k} \mathrm{J}\right] \end{array}$$ $$\begin{aligned} &\text { C(graphite) }+\mathrm{O}_{2}(\mathrm{g}) \longrightarrow \mathrm{CO}_{2}(\mathrm{g})\\\ &&\Delta H^{\circ}=-393.51 \mathrm{kJ} \end{aligned}$$
A 1.22 kg piece of iron at \(126.5^{\circ} \mathrm{C}\) is dropped into \(981 \mathrm{g}\) water at \(22.1^{\circ} \mathrm{C} .\) The temperature rises to \(34.4^{\circ} \mathrm{C} .\) What will be the final temperature if this same piece of iron at \(99.8^{\circ} \mathrm{C}\) is dropped into \(325 \mathrm{mL}\) of glycerol, \(\mathrm{HOCH}_{2} \mathrm{CH}(\mathrm{OH}) \mathrm{CH}_{2} \mathrm{OH}(1)\) at \(26.2^{\circ} \mathrm{C} ?\) For glycerol, \(d=1.26 \mathrm{g} / \mathrm{mL} ; C_{n}=219 \mathrm{JK}^{-1} \mathrm{mol}^{-1}\).
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