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Silver nitrate is a very expensive chemical. For a particular experiment, you need \(100.0 \mathrm{mL}\) of \(0.0750 \mathrm{M}\) \(\mathrm{AgNO}_{3},\) but only \(60 \mathrm{mL}\) of \(0.0500 \mathrm{M} \mathrm{AgNO}_{3}\) is available. You decide to pipet exactly \(50.00 \mathrm{mL}\) of the solution into a \(100.0 \mathrm{mL}\) flask, add an appropriate mass of \(\mathrm{AgNO}_{3},\) and then dilute the resulting solution to exactly \(100.0 \mathrm{mL}\). What mass of \(\mathrm{AgNO}_{3}\) must you use?

Short Answer

Expert verified
You must use 0.849 g of \(AgNO_{3}\)

Step by step solution

01

Calculate moles needed for final solution

First, calculate the number of moles needed for the final solution using the equation \(M = n/v\), where \(M\) is the molarity, \(n\) is the number of moles, and \(v\) is the volume (in litres). The final solution has a volume of 0.100 litres (or 100.0 mL) and a molarity of 0.075 mol/L, so you need \(n = M*v = 0.075 \times 0.100 = 0.0075\) mol of \(AgNO_{3}\)
02

Calculate moles in initial solution

Next, calculate the number of moles in the initial solution (again using \(M = n/v\)), which has a volume of 0.050 L and a molarity of 0.050 mol/L. This gives \(n = M*v = 0.050 \times 0.050 = 0.0025\) mol of \(AgNO_{3}\)
03

Calculate moles of \(AgNO_{3}\) to be added

Now, subtract the number of moles in the initial solution from the number of moles needed for the final solution. This gives \(0.0075 - 0.0025 = 0.0050\) mol.
04

Calculate mass of \(AgNO_{3}\) to be added

Finally, convert the number of moles to be added into mass using the molar mass of \(AgNO_{3}\), which is 169.87 g/mol. This gives the mass as \(m = n \times mw = 0.0050 \times 169.87 = 0.849 g\).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Molarity calculations
Molarity is a concept used to describe how concentrated a solution is. Specifically, it is expressed as the number of moles of solute (the substance being dissolved) per liter of solution. In mathematical terms, it's represented by the formula: \( M = \frac{n}{V} \). Here, \( M \) stands for molarity, \( n \) is the number of moles of the solute, and \( V \) is the volume of the solution in liters.
To determine how many moles of silver nitrate (\( \text{AgNO}_3 \)) you need for your experiment, you first need to find the desired molarity and volume of your final solution. In this exercise, you’re aiming for a solution that is 0.075 M in a total volume of 0.1 L. Simply plug these values into the equation to find out how many moles you need: \( n = M \times V = 0.075 \times 0.100 = 0.0075 \) moles.
Molarity calculations are crucial when preparing solutions with precise concentrations, especially in chemistry experiments where the concentration of reactants affects reaction rates and outcomes.
Mass calculation
Once the number of moles required for the final solution is determined, you need to figure out how much extra silver nitrate you need to add. In this particular exercise, you start with a certain amount already in a 0.050 L solution at 0.050 M. Calculating the initial moles using \( M = \frac{n}{V} \), you get: \( n = 0.050 \times 0.050 = 0.0025 \) moles of \( \text{AgNO}_3 \).
The difference between the moles needed (0.0075 moles) and what you already have (0.0025 moles) tells you exactly how much more is required: 0.0075 - 0.0025 = 0.005 moles.
To convert this mole requirement into mass, multiply by the molar mass of \( \text{AgNO}_3 \), which is 169.87 g/mol. Thus, 0.005 moles \( \times 169.87 \text{ g/mol} = 0.849 \text{ g} \).
Performing mass calculations accurately ensures that the correct amount of a substance is used, which is essential for the reliability of experimental results.
Solution preparation
Preparing a solution accurately involves a series of calculated steps to ensure that the final outcome meets the required specifications. Here’s how to approach this task from the exercise:
  • Start by measuring out 50.00 mL of the existing 0.050 M \( \text{AgNO}_3 \) solution. This will provide an initial amount of 0.0025 moles of \( \text{AgNO}_3 \).
  • Next, calculate and weigh out 0.849 g of additional \( \text{AgNO}_3 \), to achieve the desired moles for your final concentration.
  • Add this mass to the measured 50.00 mL of solution.
  • Finally, dilute the entire mixture to reach the total volume of 100.0 mL, ensuring uniform concentration throughout the solution.
Each step helps to create the precise conditions needed for the experiment. Solution preparation involves attention to detail, accuracy, and understanding each component's role in achieving the overall desired concentration.

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Most popular questions from this chapter

Iron metal reacts with chlorine gas. How many grams of \(\mathrm{FeCl}_{3}\) are obtained when \(515 \mathrm{g} \mathrm{Cl}_{2}\) reacts with excess Fe? $$ 2 \mathrm{Fe}(\mathrm{s})+3 \mathrm{Cl}_{2}(\mathrm{g}) \longrightarrow 2 \mathrm{FeCl}_{3}(\mathrm{s}) $$

Write chemical equations to represent the following reactions. (a) Calcium phosphate is heated with silicon dioxide and carbon, producing calcium silicate \(\left(\mathrm{CaSiO}_{3}\right)\) phosphorus ( \(\mathrm{P}_{4}\) ), and carbon monoxide. The phosphorus and chlorine react to form phosphorus trichloride, and the phosphorus trichloride and water react to form phosphorous acid. (b) Copper metal reacts with gaseous oxygen, carbon dioxide, and water to form green basic copper carbonate, \(\mathrm{Cu}_{2}(\mathrm{OH})_{2} \mathrm{CO}_{3}\) (a reaction responsible for the formation of the green patina, or coating, often seen on outdoor bronze statues). (c) White phosphorus and oxygen gas react to form tetraphosphorus decoxide. The tetraphosphorus decoxide reacts with water to form an aqueous solution of phosphoric acid. (d) Calcium dihydrogen phosphate reacts with sodium hydrogen carbonate (bicarbonate), producing calcium phosphate, sodium hydrogen phosphate, carbon dioxide, and water (the principal reaction occurring when ordinary baking powder is added to cakes, bread, and biscuits).

The rocket boosters of the space shuttle Discovery, launched on July \(26,2005,\) used a fuel mixture containing primarily solid ammonium perchlorate, \(\mathrm{NH}_{4} \mathrm{ClO}_{4}(\mathrm{s}),\) and aluminum metal. The unbalanced chemical equation for the reaction is given below. \(\mathrm{Al}(\mathrm{s})+\mathrm{NH}_{4} \mathrm{ClO}_{4}(\mathrm{s}) \longrightarrow\) $$ \mathrm{Al}_{2} \mathrm{O}_{3}(\mathrm{s})+\mathrm{AlCl}_{3}(\mathrm{s})+\mathrm{H}_{2} \mathrm{O}(\mathrm{l})+\mathrm{N}_{2}(\mathrm{g}) $$ What is the minimum mass of \(\mathrm{NH}_{4} \mathrm{ClO}_{4}\) consumed, per kilogram of \(\mathrm{Al}\), by the reaction of \(\mathrm{NH}_{4} \mathrm{ClO}_{4}\) and Al?[Hint: Balance the elements in the order \(\mathrm{Cl}, \mathrm{H},\) \(\mathrm{O}, \mathrm{Al}, \mathrm{N} .\)]

Water and ethanol, \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}(\mathrm{l}),\) are miscible, that is, they can be mixed in all proportions. However, when these liquids are mixed, the total volume of the resulting solution is not equal to the sum of the pure liquid volumes, and we say that the volumes are not additive. For example, when \(50.0 \mathrm{mL}\) of water and \(50.0 \mathrm{mL}\) of \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}(\mathrm{l}),\) are mixed at \(20^{\circ} \mathrm{C},\) the total volume of the solution is \(96.5 \mathrm{mL}\), not \(100.0 \mathrm{mL}\). (The volumes are not additive because the interactions and packing of water molecules are slightly different from the interactions and packing of \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}\) molecules.) Calculate the molarity of \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}\) in a solution prepared by mixing \(50.0 \mathrm{mL}\) of water and \(50.0 \mathrm{mL}\) of \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}(\mathrm{l})\) at \(20^{\circ} \mathrm{C} .\) At this temperature, the densities of water and ethanol are 0.99821 \(\mathrm{g} / \mathrm{mL}\) and \(0.7893 \mathrm{g} / \mathrm{mL},\) respectively.

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