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Predict whether the following metals will react with the acid indicated. If a reaction does occur, write the net ionic equation for the reaction. Assume that reactants and products are in their standard states. (a) \(\mathrm{Ag}\) in \(\mathrm{HNO}_{3}(\mathrm{aq}) ;\) (b) \(\mathrm{Zn}\) in \(\mathrm{HI}(\mathrm{aq}) ;\) (c) \(\mathrm{Au}\) in \(\mathrm{HNO}_{3}\) (for the couple \(\left.\mathrm{Au}^{3+} / \mathrm{Au}, E^{\circ}=1.52 \mathrm{V}\right)\).

Short Answer

Expert verified
a) No reaction occurs between Ag and HNO3. b) The net ionic reaction between Zn and HI is: \[ Zn_{(s)} + 2H^{+}_{(aq)} \rightarrow Zn^{2+}_{(aq)} + H2_{(g)} \] c) The net ionic reaction between Au and HNO3 is : \[ 4Au_{(s)} + 24H^{+}_{(aq)} + 8NO3^-_{(aq)} \rightarrow 4Au^{3+}_{(aq)} + 2NO_{(g)} + 12H2O_{(l)} \]

Step by step solution

01

Silver (Ag) in Nitric acid (HNO3)

Silver is a low reactivity metal and does not react with nitric acid. Thus, no reaction occurs.
02

Zinc (Zn) in Hydroiodic acid (HI)

Zinc is a reactive metal and reacts with hydroiodic acid (HI) as follows: \[ Zn_{(s)} + 2HI_{(aq)} \rightarrow ZnI2_{(aq)} + H2_{(g)} \]. The net ionic equation simplifies to: \[ Zn_{(s)} + 2H^{+}_{(aq)} \rightarrow Zn^{2+}_{(aq)} + H2_{(g)} \]
03

Gold (Au) in Nitric acid (HNO3)

In nitric acid, Au does not react under normal conditions. However, with the standard potential given as \(E^{\circ}=1.52 V\), Au can react with concentrated nitric acid as follows: \[ 4Au_{(s)} + 8HNO3_{(aq)} \rightarrow 4Au(NO3)3_{(aq)} + 2NO_{(g)} + 4H2O_{(l)}\]. The net ionic equation simplifies to: \[ 4Au_{(s)} + 24H^{+}_{(aq)} + 8NO3^-_{(aq)} \rightarrow 4Au^{3+}_{(aq)} + 2NO_{(g)} + 12H2O_{(l)} \]

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Net Ionic Equations
Understanding net ionic equations is crucial when studying chemical reactions. These equations show only the chemical species that are involved in a reaction, omitting the spectator ions that do not participate. This simplifies the equation and focuses on the essence of the chemical change. For instance, when zinc reacts with hydroiodic acid, the overall chemical equation is
\[ Zn_{(s)} + 2HI_{(aq)} \rightarrow ZnI2_{(aq)} + H2_{(g)} \].
However, the net ionic equation strips it down to the reactive species only:
\[ Zn_{(s)} + 2H^{+}_{(aq)} \rightarrow Zn^{2+}_{(aq)} + H2_{(g)} \].
By writing net ionic equations, students can better visualize and understand the actual chemical reaction taking place.
Reactivity Series
The reactivity series is a list of metals arranged in order of their ability to displace other metals in a reaction, basically, it showcases a hierarchy of metal reactivity. Metals at the top, such as potassium and lithium, are more reactive and will easily engage in chemical reactions. Conversely, metals like gold and platinum are found at the bottom, indicating low reactivity. This series is key in predicting whether a metal will react with a given acid. For example, silver (Ag) is quite low on this series, which means it won't react with dilute acids like nitric acid (HNO3). On the other hand, zinc (Zn), which is higher on the reactivity series, readily reacts with acids, as seen with hydroiodic acid (HI).
Chemical Reactions in Standard States
A standard state refers to the most stable physical state of an element or compound under standard conditions (usually 1 bar pressure and a specified temperature, typically 25°C). When we consider chemical reactions in these standard states, we can accurately measure and compare the tendencies of different substances to react. For instance, gold (Au) does not react with nitric acid under normal conditions, but based on the provided standard electrode potential (\(E^{\circ}=1.52 V\)), we can infer that under certain conditions, such as high concentration, a reaction is feasible. It's important to remember that reactivity can vary significantly with temperature, pressure, and concentration.
Redox Reactions
Redox reactions are chemical processes involving the transfer of electrons between two substances. One substance gets oxidized (loses electrons) while the other gets reduced (gains electrons). In the context of metals reacting with acids, the metal is oxidized, and the hydrogen ions from the acid are reduced. As a practical example, when zinc reacts with hydroiodic acid, zinc loses electrons to form \(Zn^{2+}\) ions, thus getting oxidized, while hydrogen ions gain electrons to form hydrogen gas (\(H2\)), getting reduced. Recognizing redox reactions is essential for understanding various chemical phenomena, including corrosion, energy storage in batteries, and metabolic processes in living organisms.

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Most popular questions from this chapter

Of the following statements concerning electrochemical cells, the correct ones are: (a) The cathode is the negative electrode in both voltaic and electrolytic cells. (b) The function of a salt bridge is to permit the migration of electrons between the half-cell compartments of an electrochemical cell. (c) The anode is the negative electrode in a voltaic cell. (d) Electrons leave the cell from either the cathode or the anode, depending on what electrodes are used. (e) Reduction occurs at the cathode in both voltaic and electrolytic cells. (f) If electric current is drawn from a voltaic cell long enough, the cell becomes an electrolytic cell. (g) The cell reaction is an oxidationreduction reaction.

Use the data in Appendix D to calculate the standard cell potential for each of the following reactions. Which reactions will occur spontaneously? (a) \(\mathrm{H}_{2}(\mathrm{g})+\mathrm{F}_{2}(\mathrm{g}) \longrightarrow 2 \mathrm{H}^{+}(\mathrm{aq})+2 \mathrm{F}^{-}(\mathrm{aq})\) (b) \(\mathrm{Cu}(\mathrm{s})+\mathrm{Ba}^{2+}(\mathrm{aq}) \longrightarrow \mathrm{Cu}^{2+}(\mathrm{aq})+\mathrm{Ba}(\mathrm{s})\) (c) \(3 \mathrm{Fe}^{2+}(\mathrm{aq}) \longrightarrow \mathrm{Fe}(\mathrm{s})+2 \mathrm{Fe}^{3+}(\mathrm{aq})\) (d) \(\mathrm{Hg}(1)+\mathrm{HgCl}_{2}(\mathrm{aq}) \longrightarrow \mathrm{Hg}_{2} \mathrm{Cl}_{2}(\mathrm{s})\)

An aqueous solution of \(\mathrm{K}_{2} \mathrm{SO}_{4}\) is electrolyzed by means of Pt electrodes. (a) Which of the following gases should form at the anode: \(\mathrm{O}_{2}, \mathrm{H}_{2}, \mathrm{SO}_{2}, \mathrm{SO}_{3} ?\) Explain. (b) What product should form at the cathode? Explain. (c) What is the minimum voltage required? Why is the actual voltage needed likely to be higher than this value?

The theoretical \(E_{\text {cell }}^{\circ}\) for the methane-oxygen fuel cell is \(1.06 \mathrm{V} .\) What is \(E^{\circ}\) for the reduction half-reaction \(\mathrm{CO}_{2}(\mathrm{g})+8 \mathrm{H}^{+}(\mathrm{aq})+8 \mathrm{e}^{-} \longrightarrow \mathrm{CH}_{4}(\mathrm{g})+2 \mathrm{H}_{2} \mathrm{O}(1) ?\)

A solution containing both \(\mathrm{Ag}^{+}\) and \(\mathrm{Cu}^{2+}\) ions is subjected to electrolysis. (a) Which metal should plate out first? (b) Plating out is finished after a current of \(0.75 \mathrm{A}\) is passed through the solution for 2.50 hours. If the total mass of metal is \(3.50 \mathrm{g},\) what is the mass percent of silver in the product?

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