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The most acidic of the following \(0.10 \mathrm{M}\) salt solutions is (a) \(\mathrm{Na}_{2} \mathrm{S} ;\) (b) \(\mathrm{NaHSO}_{4} ;\) (c) \(\mathrm{NaHCO}_{3} ;\) (d) \(\mathrm{Na}_{2} \mathrm{HPO}_{4}\)

Short Answer

Expert verified
The most acidic 0.10 M salt solution among the given solutions is \(\mathrm{NaHSO}_{4}\) because \(\mathrm{HSO}_{4}^{-}\), the anion present in this salt, has the parent acid \(\mathrm{H}_{2}\mathrm{SO}_{4}\), which is the strongest compared to the parent acids of the anions in other salts.

Step by step solution

01

Identify the Anions and Their Parent Acids

Firstly, identify the anions in each salt and their parent acids: In (a) \(\mathrm{Na}_{2} \mathrm{S}\), the anion is \(\mathrm{S}^{^{2-}}\) and the parent acid is \(\mathrm{H}_{2} \mathrm{S}\). In (b) \(\mathrm{NaHSO}_{4}\), the anion is \(\mathrm{HSO}_{4}^-\) and the parent acid is \(\mathrm{H}_{2}\mathrm{SO}_{4}\). In (c) \(\mathrm{NaHCO}_{3}\), the anion is \(\mathrm{HCO}_{3}^-\) and the parent acid is \(\mathrm{H}_{2}\mathrm{CO}_{3}\). In (d) \(\mathrm{Na}_{2} \mathrm{HPO}_{4}\), the anion is \(\mathrm{HPO}_{4}^{^{2-}}\) and the parent acid is \(\mathrm{H}_{2}\mathrm{PO}_{4}\).
02

Determine the Strength of the Parent Acids

Now, the more acidic a solution, the lower its pH value. Therefore, the strength of the parent acid of each anion will determine how acidic the salt solution is: \(\mathrm{H}_{2}\mathrm{S}\) is a weak acid; \(\mathrm{H}_{2}\mathrm{SO}_{4}\) is a strong acid; \(\mathrm{H}_{2}\mathrm{CO}_{3}\) is a weak acid; and \(\mathrm{H}_{2}\mathrm{PO}_{4}\) is a moderate acid.
03

Find the Most Acidic Solution

Since the most acidic solution will be the one whose anion's parent acid is the strongest, and given that \(\mathrm{H}_{2}\mathrm{SO}_{4}\) is the strongest among the identified parent acids, then the solution \(\mathrm{NaHSO}_{4}\), where \(\mathrm{HSO}_{4}^{-}\) is the anion, will be the most acidic.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Anions
Anions are negatively charged ions formed when an atom gains one or more electrons. They are part of the salts that can influence the acidity or basicity of a solution. In the context of the salts given in the problem, the anion determines the property of the solution in terms of acidity. Let's examine the anions in the examples:
  • 狈补鈧係: The anion is S虏鈦. It originates from the dissociation of H鈧係.
  • 狈补贬厂翱鈧: The anion here is HSO鈧勨伝, which comes from H鈧係O鈧.
  • 狈补贬颁翱鈧: This salt contains the anion HCO鈧冣伝, derived from H鈧侰O鈧.
  • 狈补鈧侣笔翱鈧: The anion HPO鈧劼测伝 comes from H鈧侾O鈧勨伝.
Understanding the anions in each salt helps us determine which parent acid they are associated with, and this further helps predict the salt's behavior in a solution.
Parent Acids
Parent acids are the original acids that provide the anion part in the salt. Knowing the parent acid is crucial because it influences the potential acidity when the salt is dissolved in water. Generally, the stronger the parent acid, the more acidic the resulting solution can be.
Let's look at the parent acids for each salt in our example:
  • For S虏鈦 in Na鈧係, the parent acid is H鈧係, known for being a weak acid.
  • HSO鈧勨伝 in NaHSO鈧 has H鈧係O鈧 as its parent acid. H鈧係O鈧 is a strong acid, which often leads to a more acidic solution.
  • The anion HCO鈧冣伝 in NaHCO鈧 comes from H鈧侰O鈧, a weak acid.
  • HPO鈧劼测伝 in Na鈧侶PO鈧 is associated with the moderate acid H鈧侾O鈧勨伝.
Observing the strength of these parent acids helps us assess which salt solution will be most acidic.
Solution pH
The pH of a solution is a measure of its acidity or basicity. It is important as it can affect chemical reactions and the behavior of substances when they dissolve in liquid. A lower pH indicates a higher acidity, while a higher pH suggests more basic characteristics.
When salts dissolve in water, they can affect the pH by either contributing H鈦 ions (increase acidity) or OH鈦 ions (increase basicity). For the salts given in the problem, the solution's pH is influenced by how much the anion from each salt can contribute to the H鈦 concentration once dissolved.
  • 狈补贬厂翱鈧: The HSO鈧勨伝 anion can release H鈦 ions into the solution, making it very acidic.
  • 狈补鈧係: The presence of S虏鈦 doesn't contribute significantly to increasing acidity, resulting in a less acidic solution.
  • 狈补贬颁翱鈧: As a weak acid constituent, HCO鈧冣伝 generally leads to a mild acidic or even slightly basic solution.
  • 狈补鈧侣笔翱鈧: With HPO鈧劼测伝, the solution tends towards a more neutral or slightly basic pH due to it acting like a weak base.
Thus, understanding how each anion affects the solution's pH helps us identify why NaHSO鈧 is the most acidic. This insight grasps the basics of salt solutions and their intriguing influence on pH.

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Most popular questions from this chapter

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