/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 22 The half-life of the radioactive... [FREE SOLUTION] | 91Ó°ÊÓ

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The half-life of the radioactive isotope phosphorus- 32 is 14.3 days. How long does it take for a sample of phosphorus-32 to lose \(99 \%\) of its radioactivity?

Short Answer

Expert verified
It will take approximately 67.1 days for a sample of phosphorus-32 to lose 99% of its radioactivity.

Step by step solution

01

Understand the Problem

The problem has provided the half-life of phosphorus-32 as 14.3 days. The task is to calculate how long it will take for a sample of this isotope to lose 99% of its radioactivity. This will involve understanding the concept of half-life and calculating the number of half-lives that would result in a 99% decrease.
02

Calculate the number of half-lives

The formula for exponential decay can be used to calculate the number of half-lives needed for a 99% decrease. It is given by \(N = N0(1/2)^n\), where \(N\) is the final amount, \(N0\) is the initial amount, and \(n\) is the number of half-lives. Since we are looking for a 99% decrease, \(N\) would be 1% of \(N0\), which can be written as \(N = 0.01 N0\). Now, substituting into the equation we get: \(0.01 = (1/2)^n\). Then, take the natural logarithm of both sides to solve for \(n\). By doing this you isolate \(n\) on one side of the equation.
03

Solve for the time

Now that we have the number of half-lives, multiplying this by the half-life of phosphorus-32 will give the total time required. We can substitute the known value for the half-life of phosphorus-32 as 14.3 days into our solution to find out the total time it takes for phosphorus-32 to lose 99% of its radioactivity.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Half-life
The concept of half-life is fundamental in understanding radioactive decay. It represents the time required for half of the radioactive isotope in a sample to decay. Hence, if you start with a certain amount of radioactive material, after one half-life, you will have half of that original amount remaining. This process continues halving the quantity every half-life period.

For example, if the half-life of phosphorus-32 is 14.3 days, after 14.3 days only 50% of the original phosphorus-32 will remain. After another 14.3 days, or 28.6 days total, only 25% of it will remain, and so on. This consistent halving is key to understanding how long it takes for large percentages of the substance to decay. The calculation involves determining how many half-lives are needed for the substance to reduce to any specific percentage, like in the case of losing 99% of radioactivity.
Phosphorus-32
Phosphorus-32 is a radioactive isotope of phosphorus that is commonly used in scientific research, particularly in molecular biology and genetics. The isotope has a relatively short half-life of 14.3 days, which makes it suitable for many experimental applications where a shorter-term decay product is desirable.

Due to its radioactive properties, phosphorus-32 emits beta particles, which are helpful in various labeling applications. It allows scientists to track and understand processes such as DNA synthesis. Despite its benefits in research, handling phosphorus-32 requires caution due to its radioactivity. Proper safety protocols must always be followed to minimize exposure and ensure safe usage in laboratories.
Exponential Decay
Exponential decay refers to the process by which a quantity decreases at a rate proportional to its current value. In the context of radioactive decay, the amount of a radioactive isotope decreases over time following an exponential decay model.

The formula used to describe exponential decay in radioactive materials is:
  • \( N = N_0 (1/2)^n \)
where:
  • \( N \) is the remaining amount of isotope
  • \( N_0 \) is the initial amount of isotope
  • \( n \) is the number of half-lives that have passed
This means that the remaining quantity decreases by half every half-life. For a 99% decrease, you solve for \( n \) where \( 0.01 = (1/2)^n \), using logarithms to find \( n \). This solution helps you determine how long it takes for the radioactive substance to significantly decay.
Natural Logarithm
The natural logarithm is a mathematical function that is often used in calculating exponential growth and decay. It is denoted as \( \ln(x) \) and is particularly useful in solving equations where the variable is in the exponent, like those describing exponential decay.

In the provided exercise, when deriving the exact number of half-lives \( n \) needed for phosphorus-32 to reduce to just 1% of its starting amount, you take the natural logarithm of both sides of the decay equation. Specifically, \( \ln(0.01) = \ln((1/2)^n) \). Utilizing properties of logarithms, this can be simplified to \( n \cdot \ln(1/2) = \ln(0.01) \), solving for \( n \).

This is a crucial step as it allows you to isolate \( n \) and find the exact number of half-life periods required. Understanding how to use the natural logarithm in this way is vital in many fields, particularly in scenarios dealing with decay, population growth, and financial calculations.

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Most popular questions from this chapter

If even a tiny spark is introduced into a mixture of \(\mathrm{H}_{2}(\mathrm{g})\) and \(\mathrm{O}_{2}(\mathrm{g}),\) a highly exothermic explosive reaction occurs. Without the spark, the mixture remains unreacted indefinitely. (a) Explain this difference in behavior. (b) Why is the nature of the reaction independent of the size of the spark?

The object is to study the kinetics of the reaction between peroxodisulfate and iodide ions. $$\begin{aligned} &\text { (a) } \mathrm{S}_{2} \mathrm{O}_{8}^{2-}(\mathrm{aq})+3 \mathrm{I}^{-}(\mathrm{aq}) \longrightarrow 2 \mathrm{SO}_{4}^{2-}(\mathrm{aq})+\mathrm{I}_{3}^{-}(\mathrm{aq}) \end{aligned}$$ The \(I_{3}^{-}\) formed in reaction (a) is actually a complex of iodine, \(\mathrm{I}_{2},\) and iodide ion, \(\mathrm{I}^{-}\). Thiosulfate ion, \(\mathrm{S}_{2} \mathrm{O}_{3}^{2-}\) also present in the reaction mixture, reacts with \(\mathrm{I}_{3}^{-}\) just as fast as it is formed. $$\text { (b) } 2 \mathrm{S}_{2} \mathrm{O}_{3}^{2-}(\mathrm{aq})+\mathrm{I}_{3}^{-}(\mathrm{aq}) \longrightarrow \mathrm{S}_{4} \mathrm{O}_{6}^{2-}+3 \mathrm{I}^{-}(\mathrm{aq})$$ When all of the thiosulfate ion present initially has been consumed by reaction (b), a third reaction occurs between \(\mathrm{I}_{3}^{-}(\mathrm{aq})\) and starch, which is also present in the reaction mixture. $$\text { (c) } \mathrm{I}_{3}^{-}(\mathrm{aq})+\operatorname{starch} \longrightarrow \text { blue complex }$$ The rate of reaction (a) is inversely related to the time required for the blue color of the starch-iodine complex to appear. That is, the faster reaction (a) proceeds, the more quickly the thiosulfate ion is consumed in reaction (b), and the sooner the blue color appears in reaction (c). One of the photographs shows the initial colorless solution and an electronic timer set at \(t=0 ;\) the other photograph shows the very first appearance of the blue complex (after 49.89 s). Tables I and II list some actual student data obtained in this study. $$\begin{array}{l} \hline\text { TABLE I } \\ \text { Reaction conditions at } 24^{\circ} \mathrm{C}: 25.0 \mathrm{mL} \text { of the } \\ \left(\mathrm{NH}_{4}\right)_{2} \mathrm{S}_{2} \mathrm{O}_{8}(\text { aq) listed, } 25.0 \mathrm{mL} \text { of the } \mathrm{KI}(\mathrm{aq}) \\ \text { listed, } 10.0 \mathrm{mL} \text { of } 0.010 \mathrm{M} \mathrm{Na}_{2} \mathrm{S}_{2} \mathrm{O}_{3}(\mathrm{aq}), \text { and } 5.0 \mathrm{mL} \\ \text { starch solution are mixed. The time is that of the } \\ \text { first appearance of the starch-iodine complex. } \\ \hline & \text { Initial Concentrations, } \mathrm{M} \\ \hline \text { Experiment } & \left(\mathrm{NH}_{4}\right)_{2} \mathrm{S}_{2} \mathrm{O}_{8} & \mathrm{KI} & \text { Time, s } \\ \hline 1 & 0.20 & 0.20 & 21 \\ 2 & 0.10 & 0.20 & 42 \\ 3 & 0.050 & 0.20 & 81 \\ 4 & 0.20 & 0.10 & 42 \\ 5 & 0.20 & 0.050 & 79 \\ \hline \end{array}$$ $$\begin{array}{l} \hline \text { TABLE II } \\ \text { Reaction conditions: those listed in Table I for } \\ \text { Experiment } 4, \text { but at the temperatures listed. } \\ \hline \text { Experiment } & \text { Temperature, }^{\circ} \mathrm{C} & \text { Time, } \mathrm{s} \\ \hline 6 & 3 & 189 \\ 7 & 13 & 88 \\ 8 & 24 & 42 \\ 9 & 33 & 21 \\ \hline \end{array}$$ (a) Use the data in Table I to establish the order of reaction (a) with respect to \(\mathrm{S}_{2} \mathrm{O}_{8}^{2-}\) and to I \(^{-}\). What is the overall reaction order? [Hint: How are the times required for the blue complex to appear related to the actual rates of reaction? (b) Calculate the initial rate of reaction in Experiment 1 expressed in \(\mathrm{M} \mathrm{s}^{-1} .\) [Hint: You must take into account the dilution that occurs when the various solutions are mixed, as well as the reaction stoichiometry indicated by equations \((a),(b), \text { and }(c) .]\) (c) Calculate the value of the rate constant, \(k,\) based on experiments 1 and 2 (d) Calculate the rate constant, \(k\), for the four different temperatures in Table II. (e) Determine the activation energy, \(E_{\mathrm{a}}\), of the peroxodisulfate- iodide ion reaction. (f) The following mechanism has been proposed for reaction (a). The first step is slow, and the others are fast. $$\begin{array}{c} \mathrm{I}^{-}+\mathrm{S}_{2} \mathrm{O}_{8}^{2-} \longrightarrow \mathrm{IS}_{2} \mathrm{O}_{8}^{3-} \\ \mathrm{IS}_{2} \mathrm{O}_{8}^{3-} \longrightarrow 2 \mathrm{SO}_{4}^{2-}+\mathrm{I}^{+} \\ \mathrm{I}^{+}+\mathrm{I}^{-} \longrightarrow \mathrm{I}_{2} \\ \mathrm{I}_{2}+\mathrm{I}^{-} \longrightarrow \mathrm{I}_{3}^{-} \end{array}$$ Show that this mechanism is consistent with both the stoichiometry and the rate law of reaction (a). Explain why it is reasonable to expect the first step in the mechanism to be slower than the others.

For the reversible reaction \(\mathrm{A}+\mathrm{B} \rightleftharpoons \mathrm{C}+\mathrm{D},\) the enthalpy change of the forward reaction is \(+21 \mathrm{kJ} / \mathrm{mol}\) The activation energy of the forward reaction is \(84 \mathrm{kJ} / \mathrm{mol}.\) (a) What is the activation energy of the reverse reaction? (b) In the manner of Figure 14-10, sketch the reaction profile of this reaction.

One example of a zero-order reaction is the decomposition of ammonia on a hot platinum wire, \(2 \mathrm{NH}_{3}(\mathrm{g}) \longrightarrow \mathrm{N}_{2}(\mathrm{g})+3 \mathrm{H}_{2}(\mathrm{g}) .\) If the concentration of ammonia is doubled, the rate of the reaction will (a) be zero; (b) double; (c) remain the same; (d) exponentially increase.

The reaction \(A \longrightarrow\) products is second order. The initial rate of decomposition of \(A\) when \([\mathrm{A}]_{0}=0.50 \mathrm{M}\) is \((\mathrm{a})\) the same as the initial rate for any other value of \([\mathrm{A}]_{0} ;\) (b) half as great as when \([\mathrm{A}]_{0}=1.00 \mathrm{M} ;(\mathrm{c})\) five times as great as when \([\mathrm{A}]_{0}=[\mathrm{A}]_{0}=0.25 \mathrm{M}.\)

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