Chapter 10: Problem 71
Comment on the similarities and differences in the molecular structure of the following triatomic species: \(\mathrm{CO}_{2}, \mathrm{NO}_{2}^{-}, \mathrm{O}_{3},\) and \(\mathrm{ClO}_{2}^{-}\).
Short Answer
Expert verified
CO2 has a linear shape, 180掳 bond angle, and is non-polar. NO2- and O3 have bent shapes with <120掳 bond angles and are polar. ClO2- is also bent but with a <109.5掳 bond angle, and is polar.
Step by step solution
01
Draw Lewis Structures
Begin by drawing Lewis structures. For CO2, there are two double bonds between C and each O atom. For NO2-, there is one single bond and one double bond between N and O atoms, and the remaining O atom carries a negative charge. The O3 molecule has a double bond between one pair of O atoms and a single bond with a lone pair on another O atom. Lastly, the ClO2- molecule has one double bond with an O atom, a single bond with another O atom, and three lone pairs on Cl atom, with an overall negative charge.
02
Determine Molecular Geometry using VSEPR Theory
Each molecule has a different shape based on the VSEPR theory. CO2 is linear as it has two bonded and no non-bonded electron pairs around the central C atom. NO2- is bent as it has two bonded and one non-bonded electron pairs around the N atom. O3 is bent as it also has two bonded and one non-bonded electron pairs around the central O atom. Lastly, ClO2- is bent due to three bonded and one non-bonded electron pairs around the Cl atom.
03
Comment on Bond Angles and Polarity
As per the VSEPR theory, CO2 has bond angles of 180掳 and is non-polar due to the symmetry of the molecule. NO2- and O3 have bond angles of less than 120掳 and are polar molecules. ClO2- has bond angles of less than 109.5掳 and is also polar.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Lewis Structures
Lewis structures are essential to understanding the basic structure of a molecule. They help us visualize the arrangement of atoms, bonds, and lone pairs within a molecule. A Lewis structure represents molecules using dots for electrons and lines for bonds.
For instance, in the case of CO鈧, there are two double bonds between the central carbon atom and each of the oxygen atoms. This means C shares four electrons with each O, creating a stable configuration. Next, NO鈧傗伝 has a combination of a single and a double bond, creating distinct electron distributions. Additionally, the presence of a negative charge signifies an extra electron not bonded.
Ozone, or O鈧, includes a double bond and a single bond around one O atom, with a lone pair, emphasizing its unique bonding nature. Lastly, ClO鈧傗伝 has both a single and a double bond to two different oxygen atoms, with chlorine holding lone pairs of electrons and a negative charge adding to its electron count.
Lewis structures lay the groundwork for determining further properties of a molecule, such as shape and polarity.
For instance, in the case of CO鈧, there are two double bonds between the central carbon atom and each of the oxygen atoms. This means C shares four electrons with each O, creating a stable configuration. Next, NO鈧傗伝 has a combination of a single and a double bond, creating distinct electron distributions. Additionally, the presence of a negative charge signifies an extra electron not bonded.
Ozone, or O鈧, includes a double bond and a single bond around one O atom, with a lone pair, emphasizing its unique bonding nature. Lastly, ClO鈧傗伝 has both a single and a double bond to two different oxygen atoms, with chlorine holding lone pairs of electrons and a negative charge adding to its electron count.
Lewis structures lay the groundwork for determining further properties of a molecule, such as shape and polarity.
VSEPR Theory
The VSEPR theory stands for Valence Shell Electron Pair Repulsion theory. This concept helps predict the geometric arrangement of atoms in a molecule. By understanding that electron pairs around a central atom will arrange themselves as far as possible, we can deduce the molecular shape.
In CO鈧, since there are no lone pairs on the central carbon, the electron pairs exist directly opposite each other, resulting in a linear shape. NO鈧傗伝 and O鈧 have one lone pair each around their central atom, causing the molecules to bend slightly, creating a bent shape.
ClO鈧傗伝 is especially interesting since it has one more lone pair, leading it to a bent configuration as well. The spatial arrangement dictated by VSEPR is crucial when determining the angles between atoms in a molecule and sets the stage for understanding molecular geometry.
In CO鈧, since there are no lone pairs on the central carbon, the electron pairs exist directly opposite each other, resulting in a linear shape. NO鈧傗伝 and O鈧 have one lone pair each around their central atom, causing the molecules to bend slightly, creating a bent shape.
ClO鈧傗伝 is especially interesting since it has one more lone pair, leading it to a bent configuration as well. The spatial arrangement dictated by VSEPR is crucial when determining the angles between atoms in a molecule and sets the stage for understanding molecular geometry.
Molecular Geometry
Molecular geometry refers to the three-dimensional arrangement of a molecule's atoms. This helps deduce many of its physical and chemical properties. Using VSEPR theory, the shape of a molecule can significantly influence its reactivity and interaction with other compounds.
For CO鈧, the linear arrangement leaves the molecule symmetrical, contributing to specific interactions like being a greenhouse gas. NO鈧傗伝 and O鈧, being bent, result in open structures, contributing to reactivity and absorption of both UV and visible light. This affects roles like ozone in the atmosphere.
In the case of ClO鈧傗伝, its shape contributes to its ability to act as an oxidizing agent, widely used in bleaching and water treatment processes. Understanding molecular geometry informs chemistry's practical applications in real-world scenarios.
For CO鈧, the linear arrangement leaves the molecule symmetrical, contributing to specific interactions like being a greenhouse gas. NO鈧傗伝 and O鈧, being bent, result in open structures, contributing to reactivity and absorption of both UV and visible light. This affects roles like ozone in the atmosphere.
In the case of ClO鈧傗伝, its shape contributes to its ability to act as an oxidizing agent, widely used in bleaching and water treatment processes. Understanding molecular geometry informs chemistry's practical applications in real-world scenarios.
Bond Angles
Bond angles are significant in the context of the spatial configuration of molecules. These angles are the geometric angles between two bonds originating from a single atom, directly affecting the molecule's properties.
For CO鈧, the bond angle is 180掳 due to its linear shape, allowing symmetry and non-polarity. NO鈧傗伝 and O鈧, having bent shapes, restrict bond angles to less than 120掳, contributing to the molecules鈥 reactivity and interactions with light.
The ClO鈧傗伝 molecule, due to the repulsion from its lone pairs, exhibits bond angles less than 109.5掳. Smaller bond angles can lead to increased molecule strain, influencing the molecule's stability and reactivity. Precise knowledge of bond angles aids in predicting molecular behavior.
For CO鈧, the bond angle is 180掳 due to its linear shape, allowing symmetry and non-polarity. NO鈧傗伝 and O鈧, having bent shapes, restrict bond angles to less than 120掳, contributing to the molecules鈥 reactivity and interactions with light.
The ClO鈧傗伝 molecule, due to the repulsion from its lone pairs, exhibits bond angles less than 109.5掳. Smaller bond angles can lead to increased molecule strain, influencing the molecule's stability and reactivity. Precise knowledge of bond angles aids in predicting molecular behavior.
Polarity
Polarity in molecules arises from differences in electronegativity between bonded atoms, creating partial charges. It's a pivotal factor in determining solubility, boiling points, and how substances interact with each other.
CO鈧, despite having polar bonds, is non-polar overall due to its symmetrical linear form, effectively canceling out dipole moments. NO鈧傗伝 and O鈧 have angular shapes which do not allow for dipole cancellation, resulting in polar molecules that affect their solubility and reactions with other substances.
ClO鈧傗伝 is polar as well due to its unequal sharing of electrons coupled with its asymmetrical shape. Understanding polarity is crucial in predicting and explaining a molecule鈥檚 behavior in different environments.
CO鈧, despite having polar bonds, is non-polar overall due to its symmetrical linear form, effectively canceling out dipole moments. NO鈧傗伝 and O鈧 have angular shapes which do not allow for dipole cancellation, resulting in polar molecules that affect their solubility and reactions with other substances.
ClO鈧傗伝 is polar as well due to its unequal sharing of electrons coupled with its asymmetrical shape. Understanding polarity is crucial in predicting and explaining a molecule鈥檚 behavior in different environments.