Chapter 9: Problem 39
For each of the following, write the electron configuration and Lewis symbol: a. As b. \(\mathrm{As}^{3+}\) c. Se d. \(\mathrm{Se}^{2-}\)
Short Answer
Expert verified
As: [Ar] 3d鹿鈦 4s虏 4p鲁; Lewis dot: 5 dots
As鲁鈦: [Ar] 3d鹿鈦
Se: [Ar] 3d鹿鈦 4s虏 4p鈦; Lewis dot: 6 dots
Se虏鈦: [Ar] 3d鹿鈦 4s虏 4p鈦
Lewis dot: 8 dots
Step by step solution
01
Understanding Electron Configuration for As
Arsenic (As) is element number 33 on the periodic table. That means it has 33 electrons. To write its electron configuration, we begin filling the orbitals in order of increasing energy, using the Aufbau principle: - The first 2 electrons go into the 1s orbital: 1s虏- The next 2 electrons fill the 2s orbital: 2s虏- 6 electrons fill the 2p orbitals: 2p鈦- 2 electrons fill the 3s orbital: 3s虏- 6 electrons fill the 3p orbitals: 3p鈦- 2 electrons fill the 4s orbital: 4s虏- 10 electrons fill the 3d orbitals: 3d鹿鈦- The remaining 5 electrons go into the 4p orbitals: 4p鲁So, the complete electron configuration for As is: \[ 1s^2 \, 2s^2 \, 2p^6 \, 3s^2 \, 3p^6 \, 4s^2 \, 3d^{10} \, 4p^3 \]
02
Drawing the Lewis Symbol for As
The Lewis symbol for an element represents its valence electrons. Arsenic is in group 15, so it has 5 valence electrons:
To draw the Lewis symbol for arsenic, simply place one dot for each valence electron around the symbol 'As'. Arrange the dots as:
As with one dot on each side, and a pair on the top:
鈥
鈥 As 鈥
鈥
03
Electron Configuration for As鲁鈦 Ion
The As鲁鈦 ion has lost 3 electrons compared to the neutral atom. Starting from As鈥檚 electron configuration (\[ 1s^2 \, 2s^2 \, 2p^6 \, 3s^2 \, 3p^6 \, 4s^2 \, 3d^{10} \, 4p^3 \]), we remove the 3 outermost electrons which are in the 4p orbital:So, the electron configuration for As鲁鈦 is: \[ 1s^2 \, 2s^2 \, 2p^6 \, 3s^2 \, 3p^6 \, 4s^2 \, 3d^{10} \]
04
Understanding Lewis Symbol for As鲁鈦
Since forming
As鲁鈦 results in the loss of 3 valence electrons, the Lewis symbol for
As鲁鈦 shows no electrons around 'As', indicating it essentially adopts a full outer shell like its preceding noble gas, Argon.
05
Electron Configuration for Se
Selenium (Se) is element number 34 on the periodic table, having 34 electrons. We'll assign them to orbitals as follows:- 1s虏 - 2s虏- 2p鈦- 3s虏- 3p鈦- 4s虏- 3d鹿鈦 - 4p鈦 (the last 4 electrons fill the 4p orbital)So, the complete electron configuration for Se is:\[ 1s^2 \, 2s^2 \, 2p^6 \, 3s^2 \, 3p^6 \, 4s^2 \, 3d^{10} \, 4p^4 \]
06
Drawing the Lewis Symbol for Se
Selenium also has 6 valence electrons since it is in group 16. Arrange the dots as follows around 'Se':
Se with two pairs of dots and two single dots, one on each side:
鈥 鈥
鈥 Se 鈥
鈥 鈥
07
Electron Configuration for Se虏鈦 Ion
The Se虏鈦 ion gains 2 additional electrons compared to the neutral Se atom. These electrons fill the 4p orbital fully, giving us:The electron configuration for Se虏鈦 becomes: \[ 1s^2 \, 2s^2 \, 2p^6 \, 3s^2 \, 3p^6 \, 4s^2 \, 3d^{10} \, 4p^6 \]
08
Understanding Lewis Symbol for Se虏鈦
With the additional 2 electrons,
Se虏鈦 has a full valence shell like krypton. Thus, the Lewis symbol for
Se虏鈦 shows eight dots around 'Se', representing a complete octet and a stable electron configuration:
鈥
鈥 Se 鈥
鈥 鈥
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Lewis symbol
The Lewis symbol is a simplistic representation of an element and its valence electrons - those electrons which take part in chemical bonding. For a given element, the Lewis symbol uses dots placed around the chemical symbol to symbolize the number of valence electrons. The chemical behavior of an element is largely determined by its number of valence electrons, which is why the Lewis symbol is a useful tool in predicting how an element might interact with others during a chemical reaction.
To draw a Lewis symbol:
To draw a Lewis symbol:
- Identify its valence electrons based on its group number in the periodic table.
- Represent each of these electrons with a dot placed around the element's chemical symbol.
- Spread the dots evenly around the four sides of the symbol just like arranging dots on dice.
valence electrons
Valence electrons are the electrons that reside in the outermost shell of an atom. They play a crucial role in bonding because they can be lost, gained, or shared with other atoms to achieve a complete outer shell, known as achieving a noble gas configuration.
Valence electrons are critical in determining:
Understanding the number of valence electrons helps to predict the common charges that elements form as ions during chemical reactions. This forms the basis of many chemical bonding theories.
Valence electrons are critical in determining:
- How atoms bond with each other.
- The chemical properties of elements.
- Most notably, the formation of ions.
Understanding the number of valence electrons helps to predict the common charges that elements form as ions during chemical reactions. This forms the basis of many chemical bonding theories.
As鲁鈦 ion
The
As鲁鈦 ion is formed when a neutral arsenic atom loses three of its valence electrons. In its neutral state, arsenic has five valence electrons, so losing three leaves it with only two remaining. This loss of electrons results in a positive charge of +3.
The electron configuration changes because the ion loses electrons primarily from the highest energy level:
The electron configuration changes because the ion loses electrons primarily from the highest energy level:
- Atoms will lose electrons starting with their outermost electrons, typically from the highest occupied subshell, to form cations.
- For As, electrons are removed from the 4p subshell, reducing electron configuration stability.
Se虏鈦 ion
The
Se虏鈦 ion occurs when a selenium atom gains two additional electrons to complete its outer shell, forming a full valence shell similar to that of a noble gas. Selenium normally has six valence electrons. By acquiring two more,
Se虏鈦 reaches a more stable electron configuration.
With the gain of these electrons:
With the gain of these electrons:
- The electron configuration becomes 1s虏 2s虏 2p鈦 3s虏 3p鈦 4s虏 3d鹿鈦 4p鈦.
- This configuration fills the 4p subshell, exhibiting a highly stable arrangement corresponding to krypton's configuration.