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Ammonium sulfate is used as a nitrogen and sulfur fertilizer. It is produced by reacting ammonia with sulfuric acid. Write the balanced equation for the reaction of gaseous ammonia with sulfuric acid solution. What volume (in liters) of ammonia at \(15^{\circ} \mathrm{C}\) and \(1.15\) atm is required to produce \(150.0 \mathrm{~g}\) of ammonium sulfate?

Short Answer

Expert verified
46.39 liters of ammonia are needed.

Step by step solution

01

Write the Unbalanced Reaction

Start by identifying the reactants and products. The reactants are ammonia \((\text{NH}_3)\) and sulfuric acid \((\text{H}_2\text{SO}_4)\). The product formed is ammonium sulfate \((\text{(NH}_4)_2\text{SO}_4)\). The unbalanced chemical equation is: \[ \text{NH}_3 + \text{H}_2\text{SO}_4 \rightarrow \text{(NH}_4)_2\text{SO}_4 \]
02

Balance the Chemical Equation

To balance the equation, ensure that the number of each type of atom is equal on both sides of the equation. The balanced equation is: \[ 2 \text{NH}_3 + \text{H}_2\text{SO}_4 \rightarrow \text{(NH}_4)_2\text{SO}_4 \]
03

Calculate Moles of Ammonium Sulfate

Calculate the molar mass of ammonium sulfate \((\text{(NH}_4)_2\text{SO}_4)\) which is the sum of the atomic masses: \(2(14.01 + 4 \times 1.01) + 32.07 + 4 \times 16.00 = 132.14 \, \text{g/mol}\).To find the moles of \(\text{(NH}_4)_2\text{SO}_4\), use the given mass: \( \frac{150.0 \, \text{g}}{132.14 \, \text{g/mol}} = 1.135 \, \text{mol}\).
04

Determine Moles of Ammonia Required

According to the balanced equation, \(2\) moles of \(\text{NH}_3\) are required to produce \(1\) mole of \(\text{(NH}_4)_2\text{SO}_4\). Therefore, for \(1.135\) moles of \(\text{(NH}_4)_2\text{SO}_4\), the moles of \(\text{NH}_3\) needed are \(2 \times 1.135 = 2.270 \, \text{mol}\).
05

Use Ideal Gas Law to Find Volume of Ammonia

Use the Ideal Gas Law equation: \(PV = nRT\). Use \(P = 1.15 \, \text{atm}\), \(n = 2.270\), \(R = 0.0821 \, \text{L atm/mol K}\), and \(T = 15^{\circ}\text{C} = 288.15\, \text{K}\).Substitute these values into the equation to solve for \(V\):\[ V = \frac{nRT}{P} = \frac{2.270 \times 0.0821 \times 288.15}{1.15} \approx 46.39 \, \text{L} \]
06

Conclusion

The volume of ammonia gas required at \(15^{\circ} \text{C}\) and \(1.15 \text{atm}\) to produce \(150.0\, \text{g}\) of ammonium sulfate is approximately \(46.39\) liters.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Balancing Chemical Equations
Balancing chemical equations is a crucial step in solving stoichiometry problems. The goal is to ensure that the number of atoms for each element is the same on both sides of the equation. This is because matter cannot be created or destroyed in a chemical reaction. In our reaction, the unbalanced equation was:
  • \( \text{NH}_3 + \text{H}_2\text{SO}_4 \rightarrow \text{(NH}_4)_2\text{SO}_4 \)
Initially, this equation is not balanced because the number of nitrogen and hydrogen atoms aren't the same on both sides. To balance it, we need 2 molecules of \(\text{NH}_3\) reacting with one molecule of \(\text{H}_2\text{SO}_4\). This makes the balanced equation:
  • \(2 \text{NH}_3 + \text{H}_2\text{SO}_4 \rightarrow \text{(NH}_4)_2\text{SO}_4 \)
Now, the count for each type of atom matches on both sides of the equation, confirming it is balanced.
Ideal Gas Law
The Ideal Gas Law is an essential equation in chemistry that relates the pressure, volume, temperature, and amount of gas. It is given by:
  • \( PV = nRT \)
Where:
  • \(P\) = Pressure in atmospheres (atm)
  • \(V\) = Volume in liters (L)
  • \(n\) = Moles of gas
  • \(R\) = Ideal gas constant (0.0821 L atm/mol K)
  • \(T\) = Temperature in Kelvin (K)
In the problem, we used the Ideal Gas Law to find the volume of \(\text{NH}_3\) needed. We have:
  • \(P = 1.15\) atm
  • \(n = 2.270\) mol
  • \(T = 15^{\circ}\text{C} = 288.15 \text{ K}\)
Solving for \(V\), we substituted these values into the equation:\[ V = \frac{nRT}{P} = \frac{2.270 \times 0.0821 \times 288.15}{1.15} \approx 46.39 \, \text{L} \]So, the volume of \(\text{NH}_3\) required is approximately \(46.39\) liters.
Molar Mass Calculation
Calculating the molar mass of a compound allows us to understand how many grams one mole of that compound weighs. This is essential when determining moles from a given mass in stoichiometry. For ammonium sulfate, the molar mass is calculated as follows:
  • Ammonium ion \((\text{NH}_4^+)\): \(14.01 + 4 \times 1.01 = 18.05\)
  • There are two ammonium ions, so: \(2 \times 18.05\)
  • Sulfur atom \((\text{S})\): \(32.07\)
  • Four oxygen atoms \((4 \times 16.00)\)
Adding these together gives the molar mass of ammonium sulfate \(\text{(NH}_4)_2\text{SO}_4\):
  • \(2(18.05) + 32.07 + 64.00 = 132.14 \, \text{g/mol}\)
This molar mass is used to convert the given mass of ammonium sulfate in the problem to moles.
Ammonium Sulfate
Ammonium sulfate \((\text{(NH}_4)_2\text{SO}_4)\) is a chemical compound widely used in fertilizers as a source of nitrogen and sulfur for plants. It is a crystalline salt that dissolves easily in water, making it useful not only in agriculture but also in various industrial applications.To produce ammonium sulfate, ammonia \((\text{NH}_3)\) reacts with sulfuric acid \((\text{H}_2\text{SO}_4)\), forming the fertilizer in a balanced chemical reaction. The resulting compound helps in soil enrichment by providing key nutrients. Moreover, its relatively low cost and ease of production contribute to its widespread use in farming.Understanding the reaction and applications of ammonium sulfate is crucial in fields like agriculture and chemistry where improving crop yield and fertilization efficiency are prioritized.

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Most popular questions from this chapter

Three \(25.0-\mathrm{L}\) flasks are placed next to each other on a shelf in a chemistry stockroom. The first flask contains He at a pressure of \(1.0 \mathrm{~atm}\), the second contains Xe at \(1.50 \mathrm{~atm}\), and the third contains \(\mathrm{F}_{2}\) and has a label that says \(2.0 \mathrm{~mol} \mathrm{~F}_{2}\). Consider the following questions about these flasks. a. Which flask has the greatest number of moles of gas? b. If you wanted each of the flasks to be at the same pressure as the He flask, what general things could you do to the other two containers to make this happen?

What is the ratio of rates of effusion of \(\mathrm{N}_{2}\) and \(\mathrm{O}_{2}\) under the same conditions?

Consider the following setup, which shows identical containers connected by a tube with a valve that is presently closed. The container on the left has \(1.0 \mathrm{~mol}\) of \(\mathrm{H}_{2}\) gas; the container on the right has \(1.0 \mathrm{~mol}\) of \(\mathrm{O}_{2}\). Note: Acceptable answers to some of these questions might be "both" or "neither one." a. Which container has the greatest density of gas? b. Which container has molecules that are moving at a faster average molecular speed? C. Which container has more molecules? d. If the valve is opened, will the pressure in each of the containers change? If it does, how will it change (increase, decrease, or no change)? e. \(2.0 \mathrm{~mol}\) of \(\mathrm{Ar}\) is added to the system with the valve open. What fraction of the total pressure will be due to the \(\mathrm{H}_{2}\) ?

Starting from the ideal gas law, prove that the volume of mole of gas is inversely proportional to the pressure at constant temperature (Boyle's law)

Ammonium chloride, \(\mathrm{NH}_{4} \mathrm{Cl}\), is a white solid. When heated to \(325^{\circ} \mathrm{C}\), it gives a vapor that is a mixture of ammonia and hydrogen chloride \(\mathrm{NH}_{4} \mathrm{Cl}(s) \longrightarrow \mathrm{NH}_{3}(g)+\mathrm{HCl}(g)\) Suppose someone contends that the vapor consists of \(\mathrm{NH}_{4} \mathrm{Cl}\) molecules rather than a mixture of \(\mathrm{NH}_{3}\) and \(\mathrm{HCl}\). Could you decide between these alternative views on the basis of gas-density measurements? Explain.

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