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A vessel containing \(39.5 \mathrm{~cm}^{3}\) of helium gas at \(25^{\circ} \mathrm{C}\) and \(106 \mathrm{kPa}\) was inverted and placed in cold ethanol. As the gas contracted, ethanol was forced into the vessel to maintain the same pressure of helium. If this required \(7.7 \mathrm{~cm}^{3}\) of ethanol, what was the final temperature of the helium?

Short Answer

Expert verified
The final temperature of the helium is approximately -33.4°C.

Step by step solution

01

Understand the Problem

We need to find the final temperature of the helium gas after some ethanol is added to maintain the pressure. Initially, the gas has a volume of 39.5 cm³, and 7.7 cm³ of ethanol is added, reducing the volume of the gas to 31.8 cm³. The initial temperature is 25°C converted to Kelvin, and the pressure remains constant.
02

Convert Temperature to Kelvin

The initial temperature of the helium gas is given as 25°C. To use it in calculations, convert it to Kelvin by adding 273.15. \[ T_1 = 25 + 273.15 = 298.15 \text{ K} \]
03

Use the Combined Gas Law

Since the pressure remains constant, we can use the simplified form of the Combined Gas Law, which relates the initial and final state of the gas when pressure is constant.\[ \frac{V_1}{T_1} = \frac{V_2}{T_2} \] where \( V_1 = 39.5 \text{ cm}^3 \), \( V_2 = 31.8 \text{ cm}^3 \), \( T_1 = 298.15 \text{ K} \), and we need to find \( T_2 \).
04

Solve for Final Temperature

Rearrange the equation from Step 3 to solve for \( T_2 \):\[ T_2 = \frac{V_2 \times T_1}{V_1} \]Substitute the known values:\[ T_2 = \frac{31.8 \times 298.15}{39.5} \approx 239.75 \text{ K} \]
05

Convert Final Temperature to Celsius

Convert the final temperature in Kelvin back to Celsius by subtracting 273.15.\[ T_2 = 239.75 - 273.15 = -33.4 °\text{C} \]

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Helium Gas
Helium gas is a unique and fascinating substance often discussed in physics and chemistry due to its interesting properties. Helium is a noble gas, which means it doesn't easily form chemical compounds. This property makes it stable and inert.
Here are some key attributes of helium gas:
  • It is colorless, odorless, and tasteless, making it almost invisible in everyday settings.
  • Helium has a very low boiling point, lower than most other elements, which is why it is often found in gaseous form at room temperature.
  • It is the second lightest element, only heavier than hydrogen, which allows it to easily float in air. This is why helium is used in balloons and airships.
In gas law calculations, helium behaves ideally under a wide range of conditions. This means it follows the gas laws closely, making it a good subject for studying these laws.
Understanding helium's properties helps clarify its predictable behavior in scenarios involving pressure, volume, and temperature changes.
Gas Law Calculations
Gas law calculations help predict and understand how gases respond to changes in their environment, such as pressure, volume, and temperature. The Combined Gas Law is a fundamental equation that combines Charles's Law, Boyle's Law, and Gay-Lussac's Law.
In our exercise, the Combined Gas Law formula used is:
\[ \frac{V_1}{T_1} = \frac{V_2}{T_2} \]This form is applied when pressure remains constant. Here's what each part of the equation represents:
  • \( V_1 \) and \( V_2 \) are the initial and final volumes, respectively.
  • \( T_1 \) and \( T_2 \) are the initial and final temperatures in Kelvin.
To solve such problems, one must rearrange the equation to find the unknown. In the example, solving for final temperature \( T_2 \) involves dividing the product of final volume and initial temperature by the initial volume. Gas law calculations help us predict behaviors of gases in various conditions and make accurate measurements possible.
Temperature Conversion
Temperature conversion is pivotal in scientific calculations, especially when dealing with gas laws. Scientists often use Kelvin in their calculations because it is the SI unit for temperature and provides a direct measure from absolute zero.
To convert Celsius to Kelvin, add 273.15 to the Celsius temperature. This ensures measurements start from absolute zero, where molecular motion ceases:
\[ T(\text{K}) = T(°\text{C}) + 273.15 \]In our exercise, we converted an initial temperature of 25°C:
\[ T_1 = 25 + 273.15 = 298.15 \text{ K} \]Furthermore, when solving the problem, it was necessary to convert back from Kelvin to Celsius to provide an answer familiar in everyday contexts:
\[ T_2 = 239.75 \text{ K} - 273.15 = -33.4 °\text{C} \]Being comfortable converting between these scales is crucial for solving temperature-related questions accurately, especially in calculations involving gases.

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