Chapter 4: Problem 88
A \(1.345-\mathrm{g}\) sample of a compound of barium and oxygen was dissolved in hydrochloric acid to give a solution of barium ion, which was then precipitated with an excess of potassium chromate to give \(2.012 \mathrm{~g}\) of barium chromate, \(\mathrm{BaCrO}_{4}\). What is the formula of the compound?
Short Answer
Step by step solution
Calculate moles of barium chromate
Convert moles of barium chromate to moles of barium
Calculate mass of barium in the compound
Determine mass of oxygen in the compound
Calculate moles of oxygen
Determine the mole ratio and deduce the formula
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Molar Mass Calculation
For a compound like barium chromate, \( \text{BaCrO}_4 \), you simply add up the molar masses of all the atoms in the compound.
Consider these components:
- Barium (Ba) weighs 137.33 g/mol,
- Chromium (Cr) is 51.996 g/mol,
- Oxygen (O) has a molar mass of 16.00 g/mol, and since there are four oxygen atoms, you multiply 16.00 g/mol by 4, giving 64.00 g/mol.
Mole Ratio
Here, a 1:1 mole ratio signifies that one mole of barium chromate contains exactly one mole of barium ions. This is derived from the reaction mechanism where barium ions combine with chromate ions to form barium chromate.
Therefore, the number of moles of barium in the original compound equals the moles of barium chromate calculated, ensuring accurate stoichiometric measurements. Mastery of mole ratios simplifies complex chemical equations and enhances your understanding of chemical relationships.
Precipitation Reaction
These reactions are critical in analytical chemistry for identifying ions in solution and quantifying substance amounts. When a precipitate forms, it can be isolated and weighed, allowing for the calculation of various compound-related properties, like moles and mass. This type of reaction exemplifies the practical application of concepts like molar mass and mole ratios.
Stoichiometry
In this problem, stoichiometry is employed to deduce the formula of the barium and oxygen compound. By converting grams to moles and using stoichiometric coefficients obtained from the balanced reaction, we can derive the molar relationships. Steps here included identifying the moles of barium and oxygen and determining their simplest ratio. When you performed these operations, the result was a ratio of \(1:2\) for barium to oxygen, leading to the empirical formula \( \text{BaO}_2 \). Understanding stoichiometry helps ensure calculations are logical, balanced, and consistent with chemical principles.