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Ethylene oxide, \(\mathrm{C}_{2} \mathrm{H}_{4} \mathrm{O}\), is made by the oxidation of ethylene, \(\mathrm{C}_{2} \mathrm{H}_{4}\) $$ 2 \mathrm{C}_{2} \mathrm{H}_{4}(g)+\mathrm{O}_{2}(g) \longrightarrow 2 \mathrm{C}_{2} \mathrm{H}_{4} \mathrm{O}(g) $$ Ethylene oxide is used to make ethylene glycol for automobile antifreeze. In a pilot study, \(10.6 \mathrm{~g}\) of ethylene gave \(9.91 \mathrm{~g}\) of ethylene oxide. What is the percentage yield of ethylene oxide?

Short Answer

Expert verified
The percentage yield of ethylene oxide is 59.47%.

Step by step solution

01

Calculate Molar Mass of Ethylene

First, we need to determine the molar mass of ethylene (\( \mathrm{C}_2 \mathrm{H}_4 \)). The atomic masses are: C = 12, H = 1.\[\text{Molar mass of } \mathrm{C}_2 \mathrm{H}_4 = 2 \times 12 + 4 \times 1 = 28 \text{ g/mol}\]
02

Calculate Molar Mass of Ethylene Oxide

Next, we calculate the molar mass of ethylene oxide (\( \mathrm{C}_2 \mathrm{H}_4 \mathrm{O} \)). Atomic masses are: C = 12, H = 1, O = 16.\[\text{Molar mass of } \mathrm{C}_2 \mathrm{H}_4 \mathrm{O} = 2 \times 12 + 4 \times 1 + 16 = 44 \text{ g/mol}\]
03

Calculate Moles of Ethylene

Now, calculate the number of moles of ethylene used:\[\text{Moles of } \mathrm{C}_2 \mathrm{H}_4 = \frac{10.6 \text{ g}}{28 \text{ g/mol}} = 0.3786 \text{ moles}\]
04

Determine Theoretical Yield of Ethylene Oxide

Since the reaction ratio is 1:1, the moles of \( \mathrm{C}_2 \mathrm{H}_4 \) directly convert to moles of \( \mathrm{C}_2 \mathrm{H}_4 \mathrm{O} \). Therefore, theoretical moles of \( \mathrm{C}_2 \mathrm{H}_4 \mathrm{O} = 0.3786 \text{ moles}\). Then, calculate the theoretical mass:\[\text{Theoretical mass of } \mathrm{C}_2 \mathrm{H}_4 \mathrm{O} = 0.3786 \times 44 = 16.66 \text{ g}\]
05

Calculate Percentage Yield

Finally, calculate the percentage yield using the actual yield (9.91 g) and theoretical yield (16.66 g):\[\text{Percentage yield} = \left(\frac{9.91}{16.66}\right) \times 100\% = 59.47\%\]

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Molar Mass
Understanding molar mass is crucial when performing calculations in chemistry, especially in stoichiometry and percentage yield calculations. Molar mass refers to the mass of one mole of a given substance and is generally expressed in grams per mole (g/mol). To compute the molar mass of a compound, one must sum the atomic masses of all the elements present in its chemical formula. For instance, the molar mass of ethylene
  • Ethylene ( \(\mathrm{C}_2 \mathrm{H}_4\) ): Add the atomic mass of two carbon atoms (\(2 \times 12\)) plus the atomic mass of four hydrogen atoms (\(4 \times 1\)), giving us 28 g/mol.
  • Ethylene Oxide ( \(\mathrm{C}_2 \mathrm{H}_4 \mathrm{O}\) ): Adding the atomic masses of two carbon atoms (\(2 \times 12\)), four hydrogen (\(4 \times 1\)), and one oxygen atom (\(16\)) results in a molar mass of 44 g/mol.
Knowing the molar mass allows you to convert between grams and moles, a critical step in calculating how much product you can theoretically obtain in a reaction.
Theoretical Yield
Theoretical yield is the maximum amount of product that can be generated from a given quantity of reactants under perfect conditions, based on the balanced chemical equation. When calculating theoretical yield, no consideration is given to possible side reactions or practical losses, making it an ideal scenario. In the case of producing ethylene oxide from ethylene, both chemicals react in a 1:1 molar ratio as per the equation provided. Therefore, the amount of product (ethylene oxide) is directly related to the amount of the reactant (ethylene) used. By first calculating the moles of the reactant (given by dividing the mass of ethylene by its molar mass), you can then determine the moles of the product expected under perfect conditions. The next step involves converting these moles into grams using the molar mass of the product. This gives you the theoretical yield in grams. Understanding the theoretical yield helps to provide a benchmark for evaluating the efficiency of a real-world chemical reaction, where actual yields are often lower.
Stoichiometry
Stoichiometry is the backbone of calculating quantities in chemical reactions. It involves understanding and applying balanced chemical equations to determine the proportions of reactants and products involved. By using stoichiometry, you can predict the amount of product formed or require the amount of reactant necessary for a complete reaction.Key aspects of stoichiometry in the context of the ethylene oxide problem include:
  • The reaction ratio of \(2 \mathrm{C}_2 \mathrm{H}_4 + \mathrm{O}_2 \to 2 \mathrm{C}_2 \mathrm{H}_4 \mathrm{O}\) tells us that two moles of ethylene react with one mole of oxygen to produce two moles of ethylene oxide.
  • Since the ratio is 1:1 for ethylene to ethylene oxide, the number of moles of ethylene determines the number of moles of ethylene oxide produced.
  • This linkage allows the conversion between moles of reactants and products using their stoichiometric coefficients, which in turn helps in determining theoretical yields or in analyzing percentage yields.
Mastering stoichiometry is essential for performing calculations that involve chemical equations, as it ensures both clarity and accuracy in translating between theoretical predictions and practical outcomes.

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Most popular questions from this chapter

Thiophene is a liquid compound of the elements C, H, and \(S .\) A sample of thiophene weighing \(7.96 \mathrm{mg}\) was burned in oxygen, giving \(16.65 \mathrm{mg} \mathrm{CO}_{2} .\) Another sample was subjected to a series of reactions that transformed all of the sulfur in the compound to barium sulfate. If \(4.31 \mathrm{mg}\) of thiophene gave \(11.96 \mathrm{mg}\) of barium sulfate, what is the empirical formula of thiophene? Its molecular mass is 84 amu. What is its molecular formula?

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