Chapter 20: Problem 63
Carbon- 14 has been used to study the mechanisms of reactions that involve organic compounds. The half-life of carbon-14 is \(5.73 \times 10^{3} \mathrm{y}\). What is the decay constant (in \(/ \mathrm{s}\) )?
Short Answer
Expert verified
The decay constant of Carbon-14 is approximately \(3.84 \times 10^{-12} \, /\mathrm{s}\).
Step by step solution
01
Understanding the Problem
We are given the half-life of Carbon-14, which is \( t_{1/2} = 5.73 \times 10^3 \) years, and are tasked with finding the decay constant \( \lambda \) in terms of \( / \mathrm{s} \). The decay constant is related to the half-life by the formula \( t_{1/2} = \frac{\ln(2)}{\lambda} \).
02
Converting Half-Life to Seconds
First, we need to convert the half-life from years to seconds. Using the conversion factors: 1 year = 365.25 days (accounting for leap years), 1 day = 24 hours, 1 hour = 3600 seconds, we find:\[t_{1/2} = 5.73 \times 10^3 \text{ years} \times 365.25 \text{ days/year} \times 24 \text{ hours/day} \times 3600 \text{ seconds/hour}\]Carrying out the multiplication results in:\[t_{1/2} \approx 1.807 \times 10^{11} \text{ seconds}\]
03
Finding Decay Constant
Using the relationship between half-life and the decay constant, we can solve for \( \lambda \):\[\lambda = \frac{\ln(2)}{t_{1/2}}\]Substitute \(t_{1/2} = 1.807 \times 10^{11}\) seconds:\[\lambda \approx \frac{0.693}{1.807 \times 10^{11}} \approx 3.84 \times 10^{-12} \, /\mathrm{s}\]
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Decay Constant
The decay constant, represented by the Greek letter \( \lambda \), is a fundamental concept in radiochemistry and nuclear physics. It describes the rate at which a particular isotope will decay over time. The decay constant is like a probability rate that indicates how likely an atom of a radioactive material is to decay within a given time period. To understand decay constant, consider that each radioactive isotope has its unique decay constant value, suited to its specific half-life characteristics. In mathematical terms, the decay constant is linked to the half-life \( (t_{1/2}) \) by the equation: \[\lambda = \frac{\ln(2)}{t_{1/2}}\]Where \( \ln(2) \) is the natural logarithm of 2, approximately 0.693. Because the unit of half-life can vary, the decay constant is usually expressed per second \( (/\mathrm{s}) \), making it easier to apply across different time-related scenarios. Understanding decay constants is crucial in fields like archaeology and geology, where radiocarbon dating relies on determining the decay constant of carbon-14 to estimate the age of organic artifacts.
Half-Life
The concept of half-life is essential in understanding radioactive decay. Half-life refers to the amount of time it takes for half of the radioactive atoms in a sample to decay. During each half-life period, exactly half of the unstable nuclei will have undergone radioactive decay, turning into a different atom or isotope. This is a logarithmic process, meaning that in each successive half-life period, the remaining number of undecayed atoms continues to halve. Mathematically, the half-life \( (t_{1/2}) \) is found using the equation:\[t_{1/2} = \frac{\ln(2)}{\lambda}\]Where \( \lambda \) is the decay constant. In the context of carbon-14, its half-life is approximately 5730 years. This long half-life makes carbon-14 suitable for dating artifacts and fossils up to about 50,000 years old, a range well-suited for human historical research. Understanding half-lives helps scientists calculate the age of geological and archaeological samples by measuring how much carbon-14 remains in a once-living organism.
Carbon-14 Decay
Carbon-14 decay is a natural process by which carbon-14, a radioactive isotope, transforms into nitrogen-14 over time. This process is fundamental to radiocarbon dating, where scientists measure the remaining carbon-14 in organic materials to determine their age.
Carbon-14 is present in the atmosphere and absorbed by living organisms during their life. When an organism dies, it stops absorbing carbon-14, and the isotope begins to decay. By measuring how much carbon-14 has decayed, and knowing its half-life, scientists can estimate the time since the organism's death.
Key points about carbon-14 decay:
- Carbon-14 has a half-life of about 5730 years, a timespan useful for dating artifacts up to 50,000 years old.
- The decay happens via beta decay, where a neutron in the carbon-14 nucleus is transformed into a proton, releasing an electron (beta particle).
- This process is reliable because the decay rate is consistent and unaffected by external conditions like temperature or pressure.