Chapter 20: Problem 114
The decay of \(\mathrm{Rb}-87\left(t_{1 / 2}=4.8 \times 10^{10} \mathrm{y}\right)\) to \(\mathrm{Sr}-87\) has been used to determine the age of ancient rocks and minerals. a. Write the balanced nuclear equation for this decay. b. If a sample of rock is found to be \(0.100 \%\) by mass \(\mathrm{Rb}-87\) and \(0.00250 \% \mathrm{Sr}-87\), what is the age of the rock? Assume that there was no Sr-87 present when the rock formed.
Short Answer
Step by step solution
Write Nuclear Equation
Understand Given Values
Calculate Parent-to-Daughter Ratio
Use Age Equation for Radioactive Dating
Perform Calculation
Conclusion
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Nuclear Decay Equation
When Rubidium-87 (Rb-87) decays, it undergoes beta decay to form Strontium-87 (Sr-87). For this transformation, we write a balanced nuclear equation which is \[ ^{87}_{37}\text{Rb} \rightarrow ^{87}_{38}\text{Sr} + \beta^{-} + u_e \]Here, a beta particle \(\beta^{-}\) is an electron emitted during the process, and \(u_e\) is an antineutrino, a particle that carries away a bit of energy to conserve conservation laws.
- Mass number, 87, remains unchanged as a neutron is converted into a proton.
- The atomic number increases by one, from 37 to 38, as a new proton is formed in the process.
Beta Decay
During this process, a neutron in the nucleus transforms into a proton, which increases the atomic number of the element by one.
In the case of Rubidium-87 (Rb-87), this beta decay process is crucial as it helps to convert Rb-87 into Strontium-87 (Sr-87):- The symbol \(\beta^{-}\) represents the emitted electron.- The resulting transformation changes the identity of the element from rubidium (Rb) to strontium (Sr).This process:
- Changes the element into a different one, increasing the atomic number by one.
- Does not change the mass number, allowing for precise calculations in dating processes.
Half-life Calculation
For Rubidium-87, the half-life is an astonishingly long 4.8 billion years, which makes it very suitable for dating old rocks.
Calculating half-life involves understanding specific terms:
- The half-life, denoted as \(t_{1/2}\), is the period required for half of the radioactive atoms to decay.
- This decay follows an exponential decay model, which can be mathematically described using logarithmic functions.
- Knowledge of half-life helps us estimate the age of rocks by calculating how many half-lives have passed based on current and original amounts of the isotope.
Radioactive Dating
This dating method is fundamental in understanding the Earth's history.
Using the decay of Rb-87 to Sr-87 is a popular method for dating ancient geological samples because of the long half-life involved.
- The method measures the ratio of parent isotope \(^{87}_{37}\text{Rb}\) to daughter isotope \(^{87}_{38}\text{Sr}\).
- By calculating this ratio and using the known half-life, one can determine the time that has elapsed since the rock or mineral solidified.
- It requires assuming that there was no daughter isotope present at formation, which is valid if isotopes like Sr-87 do not form independently after initial formation.
Rock Age Determination
The Rubidium-Strontium method is particularly useful for dating ancient geological samples.To determine the age of a rock, one would:1. Measure the concentrations of Rb-87 and Sr-87 in a sample.2. Calculate the ratio of daughter isotope to parent isotope. 3. Apply the formula: \[ t = \frac{t_{1/2}}{\ln(2)} \ln \left( 1 + \frac{N_{\text{Sr}}}{N_{\text{Rb}}} \right) \]Where:
- \(t\) is the age of the rock.
- \(t_{1/2}\) is the isotope's half-life.
- \(\ln(2)\) reflects the exponential nature of decay.