Chapter 2: Problem 121
Give the formulas for the following compounds. a. mercury(I) sulfide b. cobalt(III) sulfite C. ammonium dichromate d. aluminum nitride
Short Answer
Expert verified
a. Hg鈧係; b. Co鈧(SO鈧)鈧; c. (NH鈧)鈧侰r鈧侽鈧; d. AlN.
Step by step solution
01
Understand the Compound Nomenclature
For each compound, identify the elements and any prefixes or Roman numerals. The Roman numeral indicates the charge of the cation (positive ion). For example, "cobalt(III)" means cobalt with a +3 charge, and "mercury(I)" refers to mercury with a +1 charge, forming a diatomic ion Hg鈧偮测伜.
02
Mercury(I) Sulfide
Mercury(I) sulfide involves Mercury in the +1 oxidation state. Mercury(I) forms the diatomic ion Hg鈧偮测伜 and sulfide is S虏鈦. To balance the charges, one formula unit of mercury(I) requires one sulfide ion to become neutral, resulting in Hg鈧係.
03
Cobalt(III) Sulfite
Cobalt(III) means cobalt has a +3 charge, Co鲁鈦. The sulfite ion is SO鈧兟测伝. To balance the charges, two cobalt ions and three sulfite ions are needed: \[\text{Co}_2(\text{SO}_3)_3\]
04
Ammonium Dichromate
Ammonium is NH鈧勨伜 and dichromate is Cr鈧侽鈧嚶测伝. To balance the charges, two ammonium ions pair with one dichromate ion, resulting in \[((\text{NH}_4)_2\text{Cr}_2\text{O}_7)\].
05
Aluminum Nitride
Aluminum has a charge of +3, represented as Al鲁鈦, and nitride (N鲁鈦) has a charge of -3. One aluminum ion and one nitride ion balance each other, resulting in the formula AlN.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Compound Nomenclature
In chemistry, compound nomenclature is the naming process for chemical compounds. The name provides valuable information about the types and quantities of atoms present in the compound.
For compounds, like mercury(I) sulfide or cobalt(III) sulfite, Roman numerals indicate the oxidation state (charge) of cations鈥攑ositively charged ions. Mercury(I) suggests that mercury acts with a +1 charge, while cobalt(III) indicates a +3 charge for the cobalt ion. These numerals help distinguish between different ions of the same element.
Understanding these conventions is crucial for both naming compounds accurately and writing their correct chemical formulas.
For compounds, like mercury(I) sulfide or cobalt(III) sulfite, Roman numerals indicate the oxidation state (charge) of cations鈥攑ositively charged ions. Mercury(I) suggests that mercury acts with a +1 charge, while cobalt(III) indicates a +3 charge for the cobalt ion. These numerals help distinguish between different ions of the same element.
Understanding these conventions is crucial for both naming compounds accurately and writing their correct chemical formulas.
Oxidation States
Oxidation states, also known as oxidation numbers, tell us about the charge of an atom in a compound, which is vital for determining how atoms combine. This concept helps us identify how many electrons an atom has gained or lost. In a compound, the sum of the oxidation states must equal the total charge.
For example, in mercury(I) sulfide, mercury appears in an unusual diatomic form as Hg鈧偮测伜, meaning it effectively carries a +1 charge. Similarly, in cobalt(III) sulfite, cobalt has a +3 charge: Co鲁鈦. Recognizing these states helps us predict compound structures and reactivity.
For example, in mercury(I) sulfide, mercury appears in an unusual diatomic form as Hg鈧偮测伜, meaning it effectively carries a +1 charge. Similarly, in cobalt(III) sulfite, cobalt has a +3 charge: Co鲁鈦. Recognizing these states helps us predict compound structures and reactivity.
Ion Charges
Ions play a significant role in the formation of compounds. An ion is an atom with an unequal number of protons and electrons, resulting in a charge. Cations are positive ions, while anions are negative ions.
In the compounds given in the exercise, mercury forms a diatomic ion (Hg鈧偮测伜), balancing with sulfide ions (S虏鈦) to form Hg鈧係. Cobalt ions (Co鲁鈦) must pair with sulfite ions (SO鈧兟测伝), requiring two cobalts for every three sulfites to create the neutral compound, Co鈧(SO鈧)鈧. Understanding ion charges is crucial for writing chemical formulas correctly.
In the compounds given in the exercise, mercury forms a diatomic ion (Hg鈧偮测伜), balancing with sulfide ions (S虏鈦) to form Hg鈧係. Cobalt ions (Co鲁鈦) must pair with sulfite ions (SO鈧兟测伝), requiring two cobalts for every three sulfites to create the neutral compound, Co鈧(SO鈧)鈧. Understanding ion charges is crucial for writing chemical formulas correctly.
Balancing Chemical Formulas
Balancing chemical formulas ensures that the chemical compound is electrically neutral, meaning it has no overall charge. This process involves ensuring that the total charges from cations equal the charges from anions.
For ammonium dichromate, the ammonium ion (NH鈧勨伜) must balance with the dichromate ion (Cr鈧侽鈧嚶测伝). To do this, two ammonium ions are required per dichromate to achieve neutrality, resulting in the formula \((\text{NH}_4)_2\text{Cr}_2\text{O}_7\). Similarly, aluminum nitride is straightforward; aluminum (Al鲁鈦) and nitride (N鲁鈦) are already balanced as a 1:1 ratio, yielding the simple formula AlN.
Balancing is essential for accurately representing the makeup of chemical substances.
For ammonium dichromate, the ammonium ion (NH鈧勨伜) must balance with the dichromate ion (Cr鈧侽鈧嚶测伝). To do this, two ammonium ions are required per dichromate to achieve neutrality, resulting in the formula \((\text{NH}_4)_2\text{Cr}_2\text{O}_7\). Similarly, aluminum nitride is straightforward; aluminum (Al鲁鈦) and nitride (N鲁鈦) are already balanced as a 1:1 ratio, yielding the simple formula AlN.
Balancing is essential for accurately representing the makeup of chemical substances.