/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 32 An ideal gas is cooled isotherma... [FREE SOLUTION] | 91Ó°ÊÓ

91Ó°ÊÓ

An ideal gas is cooled isothermally (at constant temperature). The internal energy of an ideal gas remains constant during an isothermal change. If \(q\) is \(-76 \mathrm{~J}\), what are \(\Delta U\) and \(w\) ?

Short Answer

Expert verified
\(\Delta U = 0, w = 76 \, \mathrm{J}\).

Step by step solution

01

Understanding the Concept

For an isothermal process involving an ideal gas, the change in internal energy (\(\Delta U\)) is zero because the temperature remains constant. This is based on the fact that for ideal gases, internal energy depends only on temperature.
02

Applying the First Law of Thermodynamics

The first law of thermodynamics states that \(\Delta U = q + w\), where \(\Delta U\) is the change in internal energy, \(q\) is the heat exchanged, and \(w\) is the work done by the system. Since \(\Delta U = 0\), this simplifies to \(0 = q + w\). Thus, \(w = -q\).
03

Substitute the Given Values

Given \(q = -76 \, \mathrm{J}\), substituting into the equation \(w = -q\), we find that \(w = -(-76 \, \mathrm{J}) = 76 \, \mathrm{J}\).

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with 91Ó°ÊÓ!

Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Understanding an Ideal Gas
Ideal gases are a simplified model used to understand the behavior of gases under various conditions. They follow the ideal gas law, which is given by the formula \[ PV = nRT \] where:
  • \( P \) is the pressure,
  • \( V \) is the volume,
  • \( n \) is the number of moles of gas,
  • \( R \) is the ideal gas constant,
  • \( T \) is the temperature in Kelvin.
An ideal gas assumes no intermolecular forces and that the volume occupied by the gas molecules themselves is negligible. This model helps us predict how gases will react to changes in pressure, volume, and temperature. Notice that in an isothermal process, where temperature remains constant, the internal energy of an ideal gas does not change.
Exploring Internal Energy
Internal energy refers to the total energy contained within a system due to the kinetic energy of its particles. In the case of an ideal gas, the internal energy is entirely dependent on the temperature of the gas. This is because, for an ideal gas, internal energy is a function of the translational motion of particles, which is directly related to temperature.

During an isothermal process, where the temperature stays constant, the internal energy of an ideal gas does not change. Therefore, the change in internal energy, denoted as \( \Delta U \), is zero. Understanding this concept is crucial when analyzing processes involving heat and work in thermodynamic systems.
Examining the First Law of Thermodynamics
The first law of thermodynamics is all about the conservation of energy. It states that the change in internal energy \( \Delta U \) of a system is equal to the heat added to the system \( q \) plus the work done on the system or by the system \( w \). This can be expressed with the equation:\[ \Delta U = q + w \]
Since, in an isothermal process for ideal gases, the internal energy change \( \Delta U \) is zero, this equation simplifies to:\[ 0 = q + w \]With this simplification, it can be derived that the work done \( w \) is equal in magnitude but opposite in sign to the heat exchanged \( q \), specifically \( w = -q \). In the given problem where \( q = -76 \mathrm{~J} \), the work done would be \( w = 76 \mathrm{~J} \), as the system does work equal to the heat lost.

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

The free energy of formation of one mole of compound refers to a particular chemical equation. For each of the following, write that equation. a. \(\operatorname{KBr}(s)\) b. \(\mathrm{CH}_{3} \mathrm{Cl}(l)\) c. \(\mathrm{H}_{2} \mathrm{~S}(g)\) d. \(\mathrm{AsH}_{3}(g)\)

For each of the following statements, indicate whether it is true or false. a. A spontaneous reaction always releases heat. b. A spontaneous reaction is always a fast reaction. c. The entropy of a system always increases for a spontaneous change. d. The entropy of a system and its surroundings always increases for a spontaneous change. e. The energy of a system always increases for a spontaneous change.

Explain how the free energy changes as a spontaneous reaction occurs. Show by means of a diagram how \(G\) changes with the extent of reaction.

The following equation shows how nitrogen dioxide reacts with water to produce nitric acid: $$ 3 \mathrm{NO}_{2}(g)+\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow 2 \mathrm{HNO}_{3}(l)+\mathrm{NO}(g) $$ Predict the sign of \(\Delta S^{\circ}\) for this reaction.

You run a reaction that has a negative entropy change and is exothermic. Assuming that the entropy and enthalpy do not change with temperature, you could predict that as you increase the temperature: I. the equilibrium shifts to favor the reaction products. II. the reaction becomes more spontaneous. III. \(\Delta G\) for the reaction increases (becomes more positive). a. I only b. II only c. III only d. I and III only e. II and III only

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.