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Write a reaction for each of the following in which the species acts as a Br酶nsted acid. The equilibrium should favor the product side. a. \(\mathrm{H}_{2} \mathrm{O}_{2}\) b. \(\mathrm{HCO}_{3}^{-}\) C. \(\mathrm{NH}_{4}^{+}\) d. \(\mathrm{H}_{2} \mathrm{PO}_{4}^{-}\)

Short Answer

Expert verified
Each species donates a proton in the reactions, favoring the formation of hydronium ions and more stable conjugate bases.

Step by step solution

01

Identify the Br酶nsted Acid

A Br酶nsted acid is a species that donates a proton (H鈦) to another species. For each of the given species, we'll find a suitable conjugate base that can accept a proton, favoring a reaction equilibrium towards the products.
02

Formulate Reaction for H鈧侽鈧

In the reaction, \[\mathrm{H}_2\mathrm{O}_2 + \mathrm{H}_2\mathrm{O} \rightleftharpoons \mathrm{HO}_2^- + \mathrm{H}_3\mathrm{O}^+\]Hydrogen peroxide, \(\mathrm{H}_2\mathrm{O}_2\), donates a proton to water, forming \(\mathrm{HO}_2^-\) and \(\mathrm{H}_3\mathrm{O}^+\). This equilibrium is likely to favor the products due to the formation of the hydronium ion.
03

Formulate Reaction for HCO鈧冣伝

Consider the reaction: \[\mathrm{HCO}_3^- + \mathrm{H}_2\mathrm{O} \rightleftharpoons \mathrm{CO}_3^{2-} + \mathrm{H}_3\mathrm{O}^+\]The bicarbonate ion, \(\mathrm{HCO}_3^-\), donates a proton to water, forming carbonate ion \(\mathrm{CO}_3^{2-}\) and \(\mathrm{H}_3\mathrm{O}^+\). This reaction creates a strong base (carbonate ion), favoring product side equilibrium.
04

Formulate Reaction for NH鈧勨伜

Write the reaction: \[\mathrm{NH}_4^+ + \mathrm{H}_2\mathrm{O} \rightleftharpoons \mathrm{NH}_3 + \mathrm{H}_3\mathrm{O}^+\]The ammonium ion, \(\mathrm{NH}_4^+\), donates a proton to water, forming ammonia \(\mathrm{NH}_3\) and \(\mathrm{H}_3\mathrm{O}^+\). This equilibrium reaction is favored because ammonia is relatively stable and hydronium forms.
05

Formulate Reaction for H鈧侾O鈧勨伝

Consider the reaction: \[\mathrm{H}_2\mathrm{PO}_4^- + \mathrm{H}_2\mathrm{O} \rightleftharpoons \mathrm{HPO}_4^{2-} + \mathrm{H}_3\mathrm{O}^+\]The dihydrogen phosphate ion, \(\mathrm{H}_2\mathrm{PO}_4^-\), donates a proton to water, forming hydrogen phosphate \(\mathrm{HPO}_4^{2-}\) and \(\mathrm{H}_3\mathrm{O}^+\). This equilibrium favors products due to the stability of \(\mathrm{HPO}_4^{2-}\) and \(\mathrm{H}_3\mathrm{O}^+\).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Proton Donation
In the context of Br酶nsted acid reactions, proton donation is a key focus. A Br酶nsted acid is defined as a species that donates a proton, specifically a hydrogen ion (\(\mathrm{H}^+\)), to another species. This exchange typically involves an acid giving up a proton, transforming itself into its conjugate base.
For instance, when hydrogen peroxide (\(\mathrm{H}_2\mathrm{O}_2\)) acts as a Br酶nsted acid in a reaction with water, it donates a proton to form the hydroperoxide ion (\(\mathrm{HO}_2^-\)). Similarly, this process can be seen when bicarbonate (\(\mathrm{HCO}_3^-\)) donates a proton to water, resulting in the carbonate ion (\(\mathrm{CO}_3^{2-}\)).
To understand a substance's ability to donate protons, it's important to consider the stability of both the resulting conjugate base and how easily the proton can be removed.
Equilibrium Favorability
Equilibrium favorability pertains to the direction in which a chemical reaction naturally proceeds. For Br酶nsted acid reactions, an equilibrium might shift toward the product side if it results in more stable ions or molecules. Factors influencing this favorability include the energy states of reactants and products, as well as the relative stability of the ions or molecules formed.
Take the reaction of ammonium ion (\(\mathrm{NH}_4^+\)) acting as an acid by donating a proton to water. This forms ammonia (\(\mathrm{NH}_3\)) and the hydronium ion (\(\mathrm{H}_3\mathrm{O}^+\)). Since ammonia is relatively stable and the creation of hydronium ions is favorable in the reaction's context, the equilibrium tends to favor the formation of products.
Thus, reactions are thermodynamically driven to favor products where stability and lower energy configurations are achieved.
Conjugate Acid-Base Pairs
Conjugate acid-base pairs are fundamental in understanding Br酶nsted acid-based reactions. When a Br酶nsted acid donates a proton, it converts into its conjugate base, and the acceptor molecule becomes its conjugate acid. This pair represents the two forms related by the loss or gain of a proton.
For instance:
  • Hydrogen peroxide (\(\mathrm{H}_2\mathrm{O}_2\)) donates a proton to become hydroperoxide (\(\mathrm{HO}_2^-\)), forming a conjugate pair.
  • Bicarbonate (\(\mathrm{HCO}_3^-\)) donates a proton to form carbonate (\(\mathrm{CO}_3^{2-}\)).
  • The dihydrogen phosphate ion (\(\mathrm{H}_2\mathrm{PO}_4^-\)) loses a proton to form the hydrogen phosphate ion (\(\mathrm{HPO}_4^{2-}\)).
Understanding these pairs helps you predict the products of acidic reactions and grasp how these substances interact to maintain chemical equilibrium.
Chemical Equilibrium
Chemical equilibrium in reactions involving Br酶nsted acids is a dynamic state where the forward and reverse reactions occur at the same rate. With no net change in concentrations of reactants and products, the system is stable in terms of composition.
In equations like:
  • \(\mathrm{H}_2\mathrm{O}_2 + \mathrm{H}_2\mathrm{O} \rightleftharpoons \mathrm{HO}_2^- + \mathrm{H}_3\mathrm{O}^+\)
  • \(\mathrm{H}_2\mathrm{PO}_4^- + \mathrm{H}_2\mathrm{O} \rightleftharpoons \mathrm{HPO}_4^{2-} + \mathrm{H}_3\mathrm{O}^+\)
Chemical equilibrium establishes itself when the rates of proton transfer in both directions balance, resulting in a consistent mixture of reactants and products.
The principle of Le Chatelier's can further illustrate this by showing that any change in conditions (e.g., concentration, temperature) can shift the equilibrium, attempting to counteract the imposed change. Through understanding equilibrium and its variables, we can predict and explain how reactions naturally progress under different scenarios.

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Most popular questions from this chapter

Pure liquid hydrogen fluoride ionizes in a way similar to that of water. a. Write the equilibrium reaction for the self-ionization of liquid hydrogen fluoride. b. Will sodium fluoride be an acid or a base in liquid hydrogen fluoride? Why? c. Perchloric acid is a strong acid in liquid hydrogen fluoride. Write the chemical equation for the ionization reaction. What is the conjugate acid in this medium?

Blood contains several substances that minimize changes in its acidity by reacting with either an acid or a base. One of these is the hydrogen phosphate ion, \(\mathrm{HPO}_{4}^{2-} .\) Write one equation showing this species acting as a Br酶nsted-Lowry acid and another in which the species acts as a Br酶nsted- Lowry base.

Ethanol (ethyl alcohol), \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}\), can act as a Br酶nsted-Lowry acid. Write the chemical equation for the reaction of ethanol as an acid with hydroxide ion, \(\mathrm{OH}^{-}\). Ethanol can also react as a Br酶nsted-Lowry base. Write the chemical equation for the reaction of ethanol as a base with hydronium ion, \(\mathrm{H}_{3} \mathrm{O}^{+} .\) Explain how you arrived at these chemical equations. Both of these reactions can also be considered Lewis acid-base reactions. Explain this.

Two \(0.10\) -mol samples of the hypothetical monoprotic acids \(\mathrm{HA}(a q)\) and \(\mathrm{HB}(a q)\) are used to prepare \(1.0\) -L stock solutions of each acid. a. Write the chemical reactions for these acids in water. What are the concentrations of the two acid solutions? b. One of these acids is a strong acid, and one is weak. What could you measure that would tell you which acid was strong and which was weak? c. Say that the \(\mathrm{HA}(a q)\) solution has a \(\mathrm{pH}\) of \(3.7 .\) Is this the stronger of the two acids? How did you arrive at your answer? d. What is the concentration of \(\mathrm{A}^{-}(a q)\) in the HA solution described in part c? e. If \(\mathrm{HB}(a q)\) is a strong acid, what is the hydronium-ion concentration? f. In the solution of \(\mathrm{HB}(a q)\), which of the following would you expect to be in the greatest concentration: \(\mathrm{H}_{3} \mathrm{O}^{+}(a q)\), \(\mathrm{B}^{-}(a q), \mathrm{HB}(a q)\), or \(\mathrm{OH}^{-}(a q) ?\) How did you decide? g. In the solution of \(\mathrm{HA}(a q)\), which of the following would you expect to be in the greatest concentration: \(\mathrm{H}_{3} \mathrm{O}^{+}(a q)\), \(\mathrm{A}^{-}(a q), \mathrm{HA}(a q)\), or \(\mathrm{OH}^{-}(a q) ?\) How did you decide? h. Say you add \(1.0 \mathrm{~L}\) of pure water to a solution of \(\mathrm{HB}\). Would this water addition make the solution more acidic, make it less acidic, or not change the acidity of the original solution? Be sure to fully justify your answer. i. You prepare a \(1.0\) -L solution of \(\mathrm{HA}\). You then take a 200 mL sample of this solution and place it into a separate container. Would this \(200 \mathrm{~mL}\) sample be more acidic, be less acidic, or have the same acidity as the original \(1.0-\mathrm{L}\) solution of HA \((a q)\) ? Be sure to support your answer.

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