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Self-contained environments, such as that of a space station, require that the carbon dioxide exhaled by people be continuously removed. This can be done by passing the air over solid alkali hydroxide, in which carbon dioxide reacts with hydroxide ion. What ion is produced by the addition of \(\mathrm{OH}^{-}\) ion to \(\mathrm{CO}_{2}\) ? Use the Lewis concept to explain this.

Short Answer

Expert verified
The reaction produces the bicarbonate ion \([\text{HCO}_3^-]\).

Step by step solution

01

Understand the Reaction Components

The problem involves the reaction between carbon dioxide (\(\text{CO}_2\)) and hydroxide ion (\(\text{OH}^-\)). The task is to identify the ion produced when these two substances interact.
02

Analyze Lewis Structures

Carbon dioxide (\(\text{CO}_2\)) has a linear structure with the central carbon atom double-bonded to two oxygen atoms. The hydroxide ion (\(\text{OH}^-\)) consists of an oxygen atom single-bonded to a hydrogen atom with an extra electron giving it a negative charge. These manage electron sharing and can readily form new bonds.
03

Predicting Reaction Outcome Using Lewis Concept

When \(\text{OH}^-\) reacts with \(\text{CO}_2\), the hydroxide ion donates an electron pair forming a new molecule. The central carbon in \(\text{CO}_2\) can accept a pair of electrons from \(\text{OH}^-\) as it has empty orbitals that are suitable for bonding, leading to the formation of bicarbonate ion \([\text{HCO}_3^-]\).
04

Identify Produced Ion

The interaction of \(\text{CO}_2\) with \(\text{OH}^-\) ion results in the formation of the bicarbonate ion \([\text{HCO}_3^-]\). This results from the attachment of the \(\text{OH}^-\) ion to the \(\text{CO}_2\) and a rearrangement of electrons forming \(\text{HCO}_3^-\).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Carbon Dioxide Removal
In environments where human life must be sustained outside of Earth, such as space stations, controlling carbon dioxide levels is crucial. Humans naturally exhale carbon dioxide (CO鈧), which can accumulate and reach harmful concentrations if not managed. The removal of CO鈧 in space stations is achieved through chemical reactions involving solid alkali hydroxides. This chemical method hinges on the reaction between the carbon dioxide and hydroxide ions (OH鈦). The hydroxide ions effectively capture and convert CO鈧 into a more stable form, thereby reducing the CO鈧 concentration in the environment. This process not only ensures the atmosphere remains safe for astronauts but also maintains a balanced and controlled environment in closed, self-contained spaces.
Space Station Environment
Space stations operate as closed-loop systems where atmospheric control is essential. In a confined environment like this, it's crucial to recycle air effectively, ensuring the safety and well-being of the crew. A major component of this system is the removal of excess carbon dioxide. The process of air revitalization in space stations involves several critical steps:
  • Collection of CO鈧 from the exhaled air.
  • Reacting CO鈧 with compounds that can lock the carbon in a different form, such as solid alkali hydroxides.
  • Releasing oxygen in manageable amounts to keep the air breathable.
By employing chemical reactions that transform CO鈧 into bicarbonate ions, space stations efficiently manage air quality, allowing for sustained human occupancy.
Lewis Concept
The Lewis concept, named after Gilbert N. Lewis, is a fundamental theory in chemistry that describes how atoms and molecules bond by sharing electron pairs. In the context of carbon dioxide removal in space stations, this concept helps explain the interaction between carbon dioxide (CO鈧) and hydroxide ions (OH鈦). Carbon dioxide, with its linear and symmetrical molecular structure, has a central carbon atom double-bonded to oxygen atoms. Hydroxide ions are composed of an oxygen and hydrogen atom, with a negative charge due to an extra electron. When OH鈦 ions encounter CO鈧 molecules:
  • The hydroxide ion donates an electron pair to the carbon atom.
  • This electron donation allows for the formation of a new bond, resulting in the creation of bicarbonate ions (HCO鈧冣伝).
The Lewis concept highlights the flexibility of electron sharing and the ability of molecules to form new bonds, making it a crucial theory for understanding chemical reactions.
Bicarbonate Ion Formation
The interaction between carbon dioxide and hydroxide ions culminates in the formation of bicarbonate ions (HCO鈧冣伝). This process is crucial for the chemical removal of carbon dioxide in space station environments, allowing for effective air revitalization. Let鈥檚 break down the formation of bicarbonate ions:
  • The hydroxide ion (OH鈦) approaches the CO鈧 molecule.
  • An electron pair from the OH鈦 is shared with the carbon atom of CO鈧, forming a new bond.
  • This bond formation alters the structure, leading to the creation of bicarbonate ions.
Bicarbonate ions are stable and do not readily revert to their gaseous form, making them an optimal solution for CO鈧 capture in controlled environments such as space stations. The conversion of CO鈧 to HCO鈧冣伝 not only aids in managing air quality but also provides insights into the application of chemistry in life-support systems.

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Most popular questions from this chapter

The nitride ion and the amide ion, \(\mathrm{NH}_{2}^{-}\), have greater attractions for the hydronium ion than the hydroxide ion does. Write the equations for the reactions that occur when calcium nitride and sodium amide are added to water (each gives \(\mathrm{NH}_{3}\) ). Which is the stronger base, the nitride ion or the amide ion? Why? What is the meaning of the statement that the hydroxide ion is the strongest base that can exist in water?

Natural gas frequently contains hydrogen sulfide, \(\mathrm{H}_{2} \mathrm{~S}\). \(\mathrm{H}_{2} \mathrm{~S}\) is removed from natural gas by passing it through aqueous ethanolamine, \(\mathrm{HOCH}_{2} \mathrm{CH}_{2} \mathrm{NH}_{2}\) (an ammonia derivative), which reacts with the hydrogen sulfide. Write the equation for the reaction. Identify each reactant as either a Lewis acid or a Lewis base. Explain how you arrived at your answer.

A sample of lemon juice has a hydronium-ion concentration equal to \(2.5 \times 10^{-2} M\). What is the \(\mathrm{pH}\) of this sample?

A saturated solution of magnesium hydroxide is \(3.2 \times\) \(10^{-4} M \mathrm{Mg}(\mathrm{OH})_{2}\). What are the hydronium-ion and hydroxideion concentrations in the solution at \(25^{\circ} \mathrm{C}\) ?

What are the concentrations of \(\mathrm{H}_{3} \mathrm{O}^{+}\) and \(\mathrm{OH}^{-}\) in each of the following? a. \(1.65 \mathrm{M} \mathrm{NaOH}\) b. \(0.35 \mathrm{M} \mathrm{Sr}(\mathrm{OH})_{2}\) c. \(0.045 \mathrm{M} \mathrm{HClO}_{4}\) d. \(0.58 \mathrm{M} \mathrm{HCl}\)

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