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You want to make up \(3.00 \mathrm{~L}\) of aqueous hydrochloric acid, \(\mathrm{HCl}(a q)\), that has a \(\mathrm{pH}\) of \(2.00 .\) How many grams of concentrated hydrochloric acid will you need? Concentrated hydrochloric acid contains \(37.2\) mass percent of \(\mathrm{HCl}\).

Short Answer

Expert verified
You need approximately 2.94 g of concentrated hydrochloric acid.

Step by step solution

01

Calculate the Concentration of Hydronium Ions

To find the concentration of hydronium ions \([\text{H}_3\text{O}^+]\) in a solution with a pH of 2.00, use the formula \( \text{pH} = -\log_{10} ([\text{H}_3\text{O}^+]) \). Since pH is given as 2.00, we can calculate the concentration by rearranging the formula: \([\text{H}_3\text{O}^+] = 10^{-2} = 0.01 \text{ M}\).
02

Calculate Moles of HCl needed for the Solution

To find the amount of \( \text{HCl} \) needed, use the formula \( \text{concentration} = \frac{\text{moles of solute}}{\text{volume of solution in liters}} \). We need \(0.01 \text{ M} \times 3.00 \text{ L} = 0.03 \text{ moles of HCl}\).
03

Calculate the Mass of HCl Needed

Using the molar mass of \( \text{HCl} \), which is approximately \(36.46 \text{ g/mol}\), calculate the mass: \(0.03 \text{ moles} \times 36.46 \text{ g/mol} = 1.094 \text{ g of HCl}\).
04

Calculate the Mass of Concentrated Hydrochloric Acid

Since concentrated hydrochloric acid contains \(37.2\)% \( \text{HCl} \), use the formula for percentage by mass to find the total mass of the concentrated solution needed: \(\text{mass of concentrated solution} = \frac{1.094 \text{ g}}{0.372} \approx 2.94 \text{ g}\).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

pH Calculation
Understanding how to calculate the pH of a solution is crucial for those working with acids or bases. pH measures the acidity or alkalinity of a solution. The formula to calculate pH is: \[ \text{pH} = -\log_{10} ([\text{H}_3\text{O}^+]) \]where \([\text{H}_3\text{O}^+]\) represents the hydronium ion concentration. For example, if you have a solution with a pH of 2.00, you want to find the concentration of hydronium ions. To do this, rearrange the formula to solve for \([\text{H}_3\text{O}^+]\):\[ [\text{H}_3\text{O}^+] = 10^{-\text{pH}} \]This tells us that a pH of 2.00 corresponds to a hydronium ion concentration of \(0.01 \text{ M}\). It's like deciphering a score; a pH of 7 is neutral, below 7 is acidic, and above 7 is basic.
Molarity Calculation
Molarity is the measure of the concentration of a solute in a solution. It is expressed in moles of solute per liter of solution and is symbolized with "M". It's a vital concept when preparing solutions. To determine molarity, use the formula: \[ \text{Molarity (M)} = \frac{\text{moles of solute}}{\text{volume of solution in liters}} \]For instance, if you need 0.01 M solution of hydrochloric acid \(\text{HCl}\) and you have a 3.00 L solution, you calculate moles needed: \[ 0.01 \text{ M} \times 3.00 \text{ L} = 0.03 \text{ moles of HCl} \]This approach is helpful for creating precise concentrations in laboratory settings, ensuring the right chemical reactions occur.
Mass Percent Calculation
Mass percent is an expression of the concentration of a particular component in a mixture. It tells you how much of one substance is present in a given amount of the total mixture. For instance, concentrated hydrochloric acid often contains about 37.2% HCl by mass. To calculate mass percent, the formula is: \[ \text{Mass percent} = \frac{\text{mass of component}}{\text{total mass of mixture}} \times 100 \]If you know the mass of HCl you need, you can calculate the total mass of the solution required. For example, if 1.094 g is the mass of pure HCl needed, and you have a solution which is 37.2% HCl:\[ \text{mass of solution} = \frac{1.094 \text{ g}}{0.372} \approx 2.94 \text{ g} \]This simple calculation helps determine how much concentrated acid is necessary for your desired solution.
Solution Concentration
Solution concentration indicates how much solute is present in a given volume of solvent, influencing the strength of the solution. When making solutions, understanding concentration ensures accuracy in experiments or product formulations. The concentration can be expressed in different ways:
  • Molarity (M): moles of solute per liter of solution
  • Mass Percent: weight percent of solute in a mixture
To prepare a specific solution, you adjust these terms based on what amount of solute is available and the final volume required. Knowing the concentration helps you safely manage chemical reactions and achieve desired outcomes, particularly in chemical laboratories or industries.

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Most popular questions from this chapter

In the following reaction of trichloroacetic acid, \(\mathrm{HC}_{2} \mathrm{Cl}_{3} \mathrm{O}_{2}\), with formate ion, \(\mathrm{CHO}_{2}^{-}\), the formation of trichloroacetate ion, \(\mathrm{C}_{2} \mathrm{Cl}_{3} \mathrm{O}_{2}^{-}\), and formic acid, \(\mathrm{HCHO}_{2}\) is favored. $$ \mathrm{HC}_{2} \mathrm{Cl}_{3} \mathrm{O}_{2}+\mathrm{CHO}_{2}^{-} \longrightarrow \mathrm{C}_{2} \mathrm{Cl}_{3} \mathrm{O}_{2}^{-}+\mathrm{HCHO}_{2} $$ Which is the stronger acid, trichloroacetic acid or formic acid? Explain.

What is meant by the self-ionization of water? Write the expression for \(K_{w} .\) What is its value at \(25^{\circ} \mathrm{C} ?\)

For each of the following, state whether the solution at \(25^{\circ} \mathrm{C}\) is acidic, neutral, or basic: (a) A beverage solution has a pH of 3.5. (b) A \(0.50 M\) solution of potassium bromide, KBr, has a pH of \(7.0 .\) (c) A \(0.050 M\) solution of pyridine, \(\mathrm{C}_{5} \mathrm{H}_{5} \mathrm{~N}\), has a pH of \(9.0\). (d) A solution of iron(III) chloride has a pH of \(5.5\).

The dihydrogen phosphate ion has the ability to act as an acid in the presence of a base and as a base in the presence of an acid. What is this property called? Illustrate this behavior with water by writing Brønsted-Lowry acid- base reactions. Also illustrate this property by selecting a common acid and base to react with the dihydrogen phosphate ion.

Write the balanced reaction of hypochlorous acid, HOCl, with water to form hydronium ion and the conjugate base of HOCl. Identify each species as either an acid or a base.

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