/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 20 How does a catalyst speed up a r... [FREE SOLUTION] | 91Ó°ÊÓ

91Ó°ÊÓ

How does a catalyst speed up a reaction? How can a catalyst be involved in a reaction without being consumed by it?

Short Answer

Expert verified
Catalysts provide a lower-energy pathway for reactions, speeding them up without being consumed.

Step by step solution

01

Understanding Catalysts

A catalyst is a substance that speeds up a chemical reaction without being consumed by it. To understand how this works, we need to first comprehend the energy changes that occur during a chemical reaction.
02

Reaction Energy Barrier

In a typical chemical reaction, reactants need to overcome an energy barrier known as activation energy to transform into products. This barrier can be visualized as a hill that reactants must climb before descending into the valley of the products.
03

Role of a Catalyst

A catalyst functions by providing an alternative pathway for the reaction with a lower activation energy. This means reactants can convert into products more easily and quickly, without needing as much energy to initiate the reaction.
04

Mechanism of Catalysis

Catalysts work by temporarily binding to reactants, forming a transitional complex that helps break old bonds and form new ones more easily. Once the products are formed, the catalyst is released unchanged and can facilitate the reaction in a repeated cycle.
05

Catalyst Recovery

Because the catalyst is not consumed in the process, it remains available to assist in transforming additional reactant molecules into products. This is why catalysts can be used over and over again without being used up.

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with 91Ó°ÊÓ!

Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Activation Energy
Activation energy is the minimum energy required for a chemical reaction to occur. Imagine reactants having to climb up a hill before they can roll down to become products. This hill represents the activation energy. Catalysts help by lowering this hill.

When activation energy is high, fewer reactant molecules will have sufficient energy to reach the peak of the hill. As a result, the reaction will proceed slowly. By using a catalyst, the activation energy is lowered.
  • Lower activation energy means more reactant molecules can quickly convert into products.
  • Less energy is required to start the reaction.
By understanding activation energy, you can better appreciate how catalysts accelerate reactions by reducing the energy hurdle reactants must overcome.
Reaction Mechanism
The reaction mechanism describes the step-by-step process through which reactants are transformed into products. It’s like a detailed roadmap showing every turn and stop. Catalysts influence this mechanism by creating alternative processes.

When a catalyst is involved, it forms temporary bonds with reactants. This results in a transition state that makes it easier to break existing bonds and form new ones.
  • This transitional complex is less stable than reactants or products, which is why it quickly proceeds to form the products.
  • Once the products form, the catalyst detaches and remains unchanged.
Understanding reaction mechanisms provides insight into how catalysts work. By changing the path of the reaction, catalysts make it easier for reactions to proceed faster and with more efficiency.
Energy Barrier
In chemical reactions, an energy barrier, or activation barrier, is a conceptual "wall" that reactants must overcome to react and form products. Think of it as an obstacle that needs an extra push to get over.

In the absence of a catalyst, reactants use more energy to surpass this barrier. It delays the reaction because only a few molecules have the necessary energy to overcome it. Envision this energy barrier as a gatekeeper of the reaction process.
  • Catalysts lower this barrier, enabling more molecules to react at a faster rate.
  • The lowered barrier means less energy is needed for the molecules to transform.
With catalysts lowering energy barriers, reactions proceed more readily and swiftly.
Chemical Kinetics
Chemical kinetics is the study of how reactions occur and the rate at which they proceed. It focuses on understanding the factors that influence reaction speed. Among these factors is catalysis, which significantly impacts reaction rates through its action on activation energy.

The presence of a catalyst generally increases the rate of reaction by altering the kinetic profile. It makes the process more efficient by changing the conditions under which molecules interact.
  • Chemical kinetics explores how reaction rates can be accelerated by lowering activation energy through catalysis.
  • It also examines how different conditions such as temperature and concentration affect these rates in the presence of catalysts.
Understanding chemical kinetics provides a scientific basis for controlling and optimizing reactions in both industrial and laboratory settings.

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

Nitrogen dioxide decomposes when heated. $$2 \mathrm{NO}_{2}(g) \longrightarrow 2 \mathrm{NO}(g)+\mathrm{O}_{2}(g)$$ During an experiment, the concentration of \(\mathrm{NO}_{2}\) varied with time in the following way: \(\begin{array}{ll}\text { Time } & {\left[\mathrm{NO}_{2}\right]} \\ 0.0 \mathrm{~min} & 0.1103 M \\ 1.0 \mathrm{~min} & 0.1076 M \\ 2.0 \mathrm{~min} & 0.1050 M \\ 3.0 \mathrm{~min} & 0.1026 M\end{array}\) Obtain the average rate of decomposition of \(\mathrm{NO}_{2}\) in units of \(M / \mathrm{s}\) for each time interval.

To obtain the rate of the reaction $$5 \mathrm{Br}^{-}(a q)+\mathrm{BrO}_{3}^{-}(a q)+6 \mathrm{H}^{+}(a q) \longrightarrow 3 \mathrm{Br}_{2}(a q)+3 \mathrm{H}_{2} \mathrm{O}(l)$$ you might follow the \(\mathrm{Br}^{-}\) concentration or the \(\mathrm{BrO}_{3}^{-}\) concentration. How are the rates in terms of these species related?

A compound decomposes by a first-order reaction. The concentration of compound decreases from \(0.1180 \mathrm{M}\) to \(0.0950 M\) in \(5.2 \mathrm{~min} .\) What fraction of the compound remains after \(7.1\) min?

In the presence of excess thiocyanate ion, \(\mathrm{SCN}^{-}\), the following reaction is first order in chromium(III) ion, \(\mathrm{Cr}^{3+}\); the rate constant is \(2.0 \times 10^{-6} / \mathrm{s}\) $$\mathrm{Cr}^{3+}(a q)+\mathrm{SCN}^{-}(a q) \longrightarrow \operatorname{Cr}(\mathrm{SCN})^{2+}(a q)$$ What is the half-life in hours? How many hours would be required for the initial concentration of \(\mathrm{Cr}^{3+}\) to decrease to each of the following values: \(25.0 \%\) left, \(12.5 \%\) left, \(6.25 \%\) left, 3.125\% left?

Hydrogen sulfide is oxidized by chlorine in aqueous solution. $$\mathrm{H}_{2} \mathrm{~S}(a q)+\mathrm{Cl}_{2}(a q) \longrightarrow \mathrm{S}(s)+2 \mathrm{HCl}(a q)$$ The experimental rate law is $$\text { Rate }=k\left[\mathrm{H}_{2} \mathrm{~S}\right]\left[\mathrm{Cl}_{2}\right]$$ What is the reaction order with respect to \(\mathrm{H}_{2} \mathrm{~S}\) ? with respect to \(\mathrm{Cl}_{2}\) ? What is the overall order?

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.