Chapter 6: Problem 13
Define the heat capacity of a substance. Define the specific heat of a substance.
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Chapter 6: Problem 13
Define the heat capacity of a substance. Define the specific heat of a substance.
These are the key concepts you need to understand to accurately answer the question.
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Ammonia will burn in the presence of a platinum catalyst to produce nitric oxide, NO. $$4 \mathrm{NH}_{3}(g)+5 \mathrm{O}_{2}(g) \longrightarrow 4 \mathrm{NO}(g)+6 \mathrm{H}_{2} \mathrm{O}(g)$$ What is the heat of reaction at constant pressure? Use the following thermochemical equations: $$\begin{aligned}\mathrm{N}_{2}(g)+\mathrm{O}_{2}(g) & \longrightarrow 2 \mathrm{NO}(g) ; \Delta H=180.6 \mathrm{~kJ} \\ \mathrm{~N}_{2}(g)+3 \mathrm{H}_{2}(g) & \longrightarrow 2 \mathrm{NH}_{3}(g) ; \Delta H=-91.8 \mathrm{~kJ} \\ 2 \mathrm{H}_{2}(g)+\mathrm{O}_{2}(g) & \longrightarrow 2 \mathrm{H}_{2} \mathrm{O}(g) ; \Delta H=-483.7\mathrm{~kJ}\end{aligned}$$
When ice at \(0^{\circ} \mathrm{C}\) melts to liquid water at \(0^{\circ} \mathrm{C}\), it absorbs \(0.334 \mathrm{~kJ}\) of heat per gram. Suppose the heat needed to melt \(38.0 \mathrm{~g}\) of ice is absorbed from the water contained in a glass. If this water has a mass of \(0.210 \mathrm{~kg}\) and a temperature of \(21.0^{\circ} \mathrm{C}\), what is the final temperature of the water? (Note that you will also have \(38.0 \mathrm{~g}\) of water at \(0^{\circ} \mathrm{C}\) from the ice.)
Hydrazine, \(\mathrm{N}_{2} \mathrm{H}_{4}\), is a colorless liquid used as a rocket fuel. What is the enthalpy change for the process in which hydrazine is formed from its elements? $$\mathrm{N}_{2}(\mathrm{~g})+2 \mathrm{H}_{2}(\mathrm{~g}) \longrightarrow \mathrm{N}_{2} \mathrm{H}_{4}(l)$$ Use the following reactions and enthalpy changes: $$\begin{aligned}&\mathrm{N}_{2} \mathrm{H}_{4}(l)+\mathrm{O}_{2}(g) \longrightarrow \mathrm{N}_{2}(g)+2 \mathrm{H}_{2} \mathrm{O}(l) ; \Delta H=-622.2 \mathrm{~kJ} \\ &\mathrm{H}_{2}(g)+\frac{1}{2} \mathrm{O}_{2}(g) \longrightarrow \mathrm{H}_{2} \mathrm{O}(l) ; \Delta H=-285.8 \mathrm{~kJ}\end{aligned}$$
Tetraphosphorus trisulfide, \(\mathrm{P}_{4} \mathrm{~S}_{3}\), burns in excess oxygen to give tetraphosphorus decoxide, \(\mathrm{P}_{4} \mathrm{O}_{10}\), and sulfur dioxide, \(\mathrm{SO}_{2}\). Suppose you have measured the enthalpy change for this reaction. How could you use it to obtain the enthalpy of formation of \(\mathrm{P}_{4} \mathrm{~S}_{3}\) ? What other data do you need?
The cooling effect of alcohol on the skin is due to its evaporation. Calculate the heat of vaporization of ethanol (ethyl alcohol), \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}\). $$\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}(l) \longrightarrow \mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}(g) ; \Delta H^{\circ}=?$$ The standard enthalpy of formation of \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}(I)\) is \(-277.7\) \(\mathrm{kJ} / \mathrm{mol}\) and that of \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}(\mathrm{g})\) is \(-235.4 \mathrm{~kJ} / \mathrm{mol}\).
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